Poly(ester-amide) hot melt adhesives containing spheroidal metal powders

Claim 2

An adhesive composition comprising: a. from about 60 to about 30 parts by weight of a poly-(ester-amide) block copolymer melting in the range of about 155° to about 225° C. having from about 30 to about 70 percent by weight of crystalline polyester segments derived from at least one aliphatic or alicyclic diol having from 2 to 10 carbon atoms and at least one alicyclic or aromatic dicarboxylic acid having from 8 to 20 carbon atoms, and from about 70 to about 30 percent by weight of amorphous polyamide segments derived from an aliphatic polycarboxylic acid containing at least 40 weight percent of a C 18 to C 54 polycarboxylic acid and an aliphatic or alicyclic primary diamine containing 2 to 10 carbon atoms; and b. from about 40 to about 60 parts by weight of finely divided spheroidal metal powder selected from the group consisting of aluminum, iron, mild steel, stainless steel and zinc of particle size in the range of about 0.2 to about 150 microns.

Claim 3

The adhesive composition of claim 1 wherein the polyester is selected from the group consisting of poly(ethylene-terephthalate), co-poly(butylene terephthalate)-(ethylene terephthalate), co-poly(ethylene-terephthalate)-(ethyleneisophthalate) and copoly(ethylene terephthalate)-(propylene terephthalate).

Claim 4

The adhesive composition of claim 1 wherein the diamine is hexamethylene diamine.

Claim 5

The adhesive composition of claim 1 having a melt viscosity at 232° C. of less than about 150,000 centipoise at a shear rate of 4 sec. -1 .

Claim 6

The adhesive composition of claim 1 wherein the polyester segment prior to incorporation in the polyesteramide has an inherent viscosity at 25° C. in the range of about 0.05 to about 0.70 measured as a 0.5 gram solution in 100 ml. of a solvent mixture of 60 parts by weight of phenol and 40 parts by weight of symm-tetrachloroethane and a melting point in the range of about 180° to about 270° C.

Claim 7

The adhesive composition of claim 1 wherein the poly(ester-amide) has an inherent viscosity at 25° C. in the range of from 0.35 to about 0.95 measured as a 0.5 gram solution in 100 ml. of a solvent mixture of 60 parts by weight of phenol and 40 parts by weight of symm-tetrachloroethane.

Claim 8

The adhesive composition of claim 1 wherein the spheroidal metal powder has a particle size in the range of about 4 to about 100 microns.

Claim 9

An adhesive composition comprising: a. from about 70 to about 30 parts by weight of a poly (ester-amide) block copolymer of inherent viscosity in the range of about 0.35 to about 0.95 and of melting point in the range of about 155° to about 225° C., having from about 30 to about 70 percent by weight of crystalline polyester segments selected from the group consisting of poly(ethylene-terephthalate), co-poly (butylene terephthalate)-(ethylene terephthalate), co-poly(ethylene-terephthalate)-(ethylene isophthalate) and co-poly(ethylene terephthalate)-(propylene terephthalate) which prior to incorporation in the poly(ester-amide), have an inherent viscosity in the range of about 0.05 to about 0.70 and a melting point in the range of about 180° to about 270° C., and from about 70 to about 30 percent by weight of amorphous polyamide segments derived from a C 36 dibasic acid and an aliphatic or alicyclic diamine containing from 2 to 10 carbon atoms, the inherent viscosities being determined at 25° C. with an 0.5 gram solution in 100 ml. of a solvent mixture of 60 parts by weight of phenol and 40 parts by weight of symm-tetrachloroethane; and b. from about 30 to about 70 parts by weight of spheroidal aluminum powder of particle size in the range of about 4 to about 100 microns.

Claim 10

An adhesive composition comprising: a. from about 70 to about 30 parts by weight of a poly (ester-amide) block copolymer of inherent viscosity in the range of about 0.35 to about 0.95 and of melting point in the range of about 155° to about 225° C., having from about 30 to about 70 percent by weight of crystalline polyester segments selected from the group consisting of poly(ethylene-terephthalate), co-poly (butylene terephthalate)-(ethylene terephthalate), co-poly(ethylene-terephthalate)-(ethylene isophthalate) and co-poly(ethylene terephthalate)-(propylene terephthalate) which prior to incorporation in the poly(ester-amide), have an inherent viscosity in the range of about 0.05 to about 0.70 and a melting point in the range of about 180° to about 270° C., and from about 70 to about 30 percent by weight of amorphous polyamide segments derived from a C 36 dibasic acid and an aliphatic or alicyclic diamine containing from 2 to 10 carbon atoms, the inherent viscosities being determined at 25° C. with an 0.5 gram solution in 100 ml. of a solvent mixture of 60 parts by weight of phenol and 40 parts by weight of symm-tetrachloroethane; and b. from about 30 to about 70 parts by weight of spheroidal aluminum powder of particle size in the range of about 4 to about 100 microns.

Claim 11

The adhesive composition of claim 8 wherein the diamine is hexamethylene diamine.

Claim 12

The adhesive composition of claim 8 having a melt viscosity at 232° C. of less than about 150,000 centipoise at a shear rate of 4 sec. -1 .

Claim 13

A substrate coated with an adhesive composition wherein the adhesive composition comprises: a. from about 60 to about 30 parts by weight of a poly (ester-amide) block copolymer melting in the range of about 155° to about 225° C. having from about 30 to about 70 percent by weight of crystalline polyester segments derived from at least one aliphatic or alicyclic diol having from 2 to 10 carbon atoms and at least one alicyclic or aromatic dicarboxylic acid having from 8 to 20 carbon atoms, and from about 70 to about 30 percent by weight of amorphous polyamide segments derived from an aliphatic polycarboxylic acid containing at least 40 weight percent of a C 18 to C 54 polycarboxylic acid and an aliphatic or alicyclic primary diamine containing 2 to 10 carbon atoms; and b. from about 40 to about 60 parts by weight of finely divided spheroidal metal powder selected from the group consisting of aluminum, iron, mild steel, stainless steel and zinc of particle size in the range of about 0.2 to about 150 microns.

Claim 14

A substrate coated with an adhesive composition wherein the adhesive composition comprises: a. from about 60 to about 30 parts by weight of a poly (ester-amide) block copolymer melting in the range of about 155° to about 225° C. having from about 30 to about 70 percent by weight of crystalline polyester segments derived from at least one aliphatic or alicyclic diol having from 2 to 10 carbon atoms and at least one alicyclic or aromatic dicarboxylic acid having from 8 to 20 carbon atoms, and from about 70 to about 30 percent by weight of amorphous polyamide segments derived from an aliphatic polycarboxylic acid containing at least 40 weight percent of a C 18 to C 54 polycarboxylic acid and an aliphatic or alicyclic primary diamine containing 2 to 10 carbon atoms; and b. from about 40 to about 60 parts by weight of finely divided spheroidal metal powder selected from the group consisting of aluminum, iron, mild steel, stainless steel and zinc of particle size in the range of about 0.2 to about 150 microns.

Claim 15

The substrate of claim 11 wherein the polyester block of the poly(ester-amide) is selected from the group consisting of poly(ethylene-terephthalate), co-poly(butylene terephthalate)-(ethylene terephthalate), co-poly(ethylene-terephthalate)-(ethylene isophthalate) and co-poly(ethylene terephthalate)-(propylene terephthalate).

Claim 16

The substrate of claim 11 wherein the diamine of the amide block of the poly(ester-amide) is hexamethylene diamine.

Claim 17

The substrate of claim 11 wherein the melt viscosity of the adhesive composition at 232° C. is less than about 150,000 centipoise at a shear rate of 4 sec. -1 .

Claim 18

The substrate of claim 11 wherein the polyester segment prior to incorporation in the poly(ester-amide) has an inherent viscosity at 25° C. in the range of about 0.05 to about 0.70 measured as an 0.5 gram solution in 100 ml. of a solvent mixture of 60 parts by weight of phenol and 40 parts by weight of symm-tetrachloroethane and a melting point in the range of about 180° to about 270° C.

Claim 19

The substrate of claim 11 wherein the poly(ester-amide) has an inherent viscosity at 25° C. in the range of from 0.35 to about 0.95 measured as an 0.5 gram solution in 100 ml. of a solvent mixture of 60 parts by weight of phenol and 40 parts by weight of symm-tetrachloroethane.

Claim 20

The substrate of claim 11 wherein the spheroidal metal powder has a particle size in the range of about 4 to about 100 microns.

Claim 21

A substrate coated with an adhesive composition wherein the adhesive composition comprises: a. from about 70 to about 30 parts by weight of a poly (ester-amide) block copolymer of inherent viscosity in the range of about 0.35 to about 0.95 and of melting point in the range of about 155° to about 225° C., having from about 30 to about 70 percent by weight of crystalline polyester segments selected from the group consisting of poly(ethylene-terephthalate), co-poly (butylene terephthalate)-(ethylene terephthalate, co-poly(ethylene-terephthalate)-(ethylene isophthalate) and co-poly(ethylene terephthalate)-(propylene terephthalate) which prior to incorporation in the poly(ester-amide), have an inherent viscosity in the range of about 0.05 to about 0.70 and a melting point in the range of about 180° to about 270° C., and from about 70 to about 30 percent by weight of amorphous polyamide segments derived from a C 36 dibasic acid and an aliphatic or alicyclic diamine containing from 2 to 10 carbon atoms, the inherent viscosities being determined at 25° C. with an 0.5 gram solution in 100 ml. of a solvent mixture of 60 parts by weight of phenol and 40 parts by weight of symm-tetrachloroethane; and b. from about 30 to about 70 parts by weight of spheroidal aluminum powder of particle size in the range of about 4 to about 100 microns.

Claim 22

A substrate coated with an adhesive composition wherein the adhesive composition comprises: a. from about 70 to about 30 parts by weight of a poly (ester-amide) block copolymer of inherent viscosity in the range of about 0.35 to about 0.95 and of melting point in the range of about 155° to about 225° C., having from about 30 to about 70 percent by weight of crystalline polyester segments selected from the group consisting of poly(ethylene-terephthalate), co-poly (butylene terephthalate)-(ethylene terephthalate, co-poly(ethylene-terephthalate)-(ethylene isophthalate) and co-poly(ethylene terephthalate)-(propylene terephthalate) which prior to incorporation in the poly(ester-amide), have an inherent viscosity in the range of about 0.05 to about 0.70 and a melting point in the range of about 180° to about 270° C., and from about 70 to about 30 percent by weight of amorphous polyamide segments derived from a C 36 dibasic acid and an aliphatic or alicyclic diamine containing from 2 to 10 carbon atoms, the inherent viscosities being determined at 25° C. with an 0.5 gram solution in 100 ml. of a solvent mixture of 60 parts by weight of phenol and 40 parts by weight of symm-tetrachloroethane; and b. from about 30 to about 70 parts by weight of spheroidal aluminum powder of particle size in the range of about 4 to about 100 microns.

Claim 23

The substrate of claim 18 wherein the diamine of the amide block of the poly(ester-amide) is hexamethylene diamine.

Claim 24

The substrate of claim 18 wherein the melt viscosity of the adhesive composition at 232° C. is less than about 150,000 centipoise at a shear rate of 4 sec. -1 .