Patent US4212919A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4212919A Expired / Lapsed US ⏱️ 0.0 years remaining

Strengthened polychromatic glasses

Assignee: Corning Glass Works
•
Filing: 1979-06-28
•
Granted: 1980-07-15
•
Expires: 1999-06-28
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract This invention is concerned with the production of chemically strengthened polychromatic glasses. In the preferred embodiment, the glasses are suitable for ophthalmic applications, i.e., the glasses have a refractive index of at least 1.523 and, after chemical strengthening, will exhibit a surface compression layer having a depth of at least 0.002", a maximum central tension of at least 0.7 kg/mm 2 , and a modulus of rupture of at least approximately 30,000 psi such as to pass the FDA strength requirements for glass ophthalmic lenses. For this preferred embodiment, the chemical strengthening reaction will be conducted for a period not exceeding about 24 hours and the glasses will have compositions consisting essentially, by weight on the oxide basis as calculated from the batch of about 11-18% Na 2 O, 60-70% SiO 2 , 3-12% ZrO 2 , 0-18% ZnO and/or 0-14% Al 2 O 3 , the total ZnO+Al 2 O 3 not exceeding about 20%, 0-5% BaO, 0.005-0.3% Ag, 0.01-0.2% CeO 2 , 1-4% F, and an amount of at least one halide selected from the group of Cl, Br, and I sufficient to react stoichiometrically with the Ag, but not more than about 3%.

Inventors

  • 👤 Syed N. Hoda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 01:49
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/04; C03C3/076; C03C3/11; C03C21/00; C03C3/112; C03C3/115; C03C3/118; Y; Y10; Y10T; Y10T428/00; Y10T428/31; Y10T428/315

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 101 words
Polychromatic glasses which, after chemical strengthening, exhibit a surface compression layer having a depth of at least 0.002", a maximum central tension of at least 0.7 kg/mm 2 , and a modulus of rupture of at least approximately 30,000 psi consisting essentially, by weight on the oxide basis as calculated from the batch, of about 11-18% Na 2 O, 60-70% SiO 2 , 2-12% ZrO 2 , 0.005-0.3% Ag, 1-4% F, and an amount of at least one halide selected from the group of Cl, Br, and I sufficient to react stoichiometrically with the Ag, but not more than about 3%.
Claim 2
Dependent Claim 101 words
Polychromatic glasses which, after chemical strengthening, exhibit a surface compression layer having a depth of at least 0.002", a maximum central tension of at least 0.7 kg/mm 2 , and a modulus of rupture of at least approximately 30,000 psi consisting essentially, by weight on the oxide basis as calculated from the batch, of about 11-18% Na 2 O, 60-70% SiO 2 , 2-12% ZrO 2 , 0.005-0.3% Ag, 1-4% F, and an amount of at least one halide selected from the group of Cl, Br, and I sufficient to react stoichiometrically with the Ag, but not more than about 3%.
Claim 3
Dependent Claim 12 words
Polychromatic glasses according to claim 1 also containing 0.01-0.2% CeO 2 .
Claim 4
Dependent Claim 31 words
Polychromatic glasses according to claim 1 also containing up to 14% Al 2 O 3 and/or up to 18% ZnO, the total Al 2 O 3 +ZnO not exceeding about 20%.
Claim 5
Dependent Claim 63 words
Polychromatic glasses according to claim 2 consisting essentially of 14-17% Na 2 O, 62-68% SiO 2 , 3-8% ZrO 2 , 2-12% Al 2 O 3 ; 5-13% ZnO, 0.005-0.3% Ag, 1-4% F, and an amount of at least one halide selected from the group of Cl, Br, and I sufficient to react stoichiometrically with the Ag, but not more than about 3%.
Claim 6
Dependent Claim 96 words
Polychromatic glasses according to claim 1 manifesting a refractive index of at least 1.523 consisting essentially, by weight on the oxide basis as calculated from the batch, of about 11-18% Na 2 O, 60-70% SiO 2 , 3-12% ZrO 2 , 0-18% ZnO and/or 0-14% Al 2 O 3 , the total ZnO+Al 2 O 3 not exceeding about 20%, 0-5% BaO, 0.005-0.3% Ag, 1-4% F, and an amount of at least one halide selected from the group of Cl, Br, and I sufficient to react stoichiometrically with the Ag, but not more than about 3%.

References Cited (Backward Citations)

US3790430A Cited
US3485702A Cited
US4017318A Cited
US4092139A Cited
US4118214A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-07-15 1984-01-14 1984-07-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-07-15 1988-01-14 1988-07-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-07-15 1992-01-14 1992-07-15 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag