Patent US4212759A successfully refreshed from Google Patents.
US4212759A
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US
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Acidic hydrocarbon-in-water emulsions
Assignee: Individual
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Filing: 1979-01-22
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Granted: 1980-07-15
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Expires: 1999-01-22
Abstract
Abstract An acidic cleaning composition which is especially useful in cleaning glass-ceramic range surfaces comprises an acid-stable, hydrocarbon-in-water emulsion. The composition contains liquid hydrocarbon, solid, porous absorbent, and a minor amount of an acid to provide an acidic emulsion. The composition may also contain a soap or detergent, a minor amount of polysilicone or a thickening agent.
Inventors
- 👤 David W. Young
- 👤 Donald G. Cherry
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 15:57
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/20; C11D3/2075; C11D3/26; C11D3/30; C11D3/43; C11D7/00; C11D7/02; C11D7/04; C11D7/08; Y; Y10; Y10S; Y10S516/00; Y10S516/01; Y10S516/02; Y10S516/905; Y10S516/914
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
122 words
An acidic cleaning composition in the form of a stable hydrocarbon-in-water emulsion for cleaning surfaces comprising about 3 to 20 weight percent liquid hydrocarbon having a boiling range of about 130° C. to 350° C., about 15 to 35 weight percent porous silica absorbent, said absorbent having a surface area of at least about 100 square meters per gram and a particle size in the range of about 10 to 200 microns in diameter; about 0.5 to 7 weight percent moderately strong acid; about 0.5 to 10 weight percent aliphatic monocarboxylic acid having about 10 to 24 carbon atoms; about 0.5 to 5 of secondary or tertiary lower alkanol amine; and water; said composition having a pH of about 1 to 3.
Claim 2
Dependent Claim
122 words
An acidic cleaning composition in the form of a stable hydrocarbon-in-water emulsion for cleaning surfaces comprising about 3 to 20 weight percent liquid hydrocarbon having a boiling range of about 130° C. to 350° C., about 15 to 35 weight percent porous silica absorbent, said absorbent having a surface area of at least about 100 square meters per gram and a particle size in the range of about 10 to 200 microns in diameter; about 0.5 to 7 weight percent moderately strong acid; about 0.5 to 10 weight percent aliphatic monocarboxylic acid having about 10 to 24 carbon atoms; about 0.5 to 5 of secondary or tertiary lower alkanol amine; and water; said composition having a pH of about 1 to 3.
Claim 3
Dependent Claim
15 words
The acidic cleaning composition of claim 1 wherein the moderately strong acid is oxalic acid.
Claim 4
Dependent Claim
15 words
The acidic cleaning composition of claim 1 wherein the moderately strong acid is sulfamic acid.
Claim 5
Dependent Claim
22 words
The acidic cleaning composition of claim 3 wherein the emulsion contains sufficient thickening agent to provide a gel-like consistency to the emulsion.
Claim 6
Dependent Claim
29 words
The acidic cleaning composition of claim 4 wherein the thickening agent is sodium carboxymethylcellulose and is in an amount of about 0.5 to 5 weight percent of the composition.
Claim 7
Dependent Claim
22 words
The acidic cleaning composition of claim 1 wherein the cleaning composition contains about 1 to 7 weight percent of a straight-chain polysilicone.
Claim 8
Dependent Claim
65 words
An acidic, acid-stable, hydrocarbon-in-water emulsion comprising an emulsion-providing combination consisting essentially of a liquid hydrocarbon, water in an amount to provide a weight ratio of water to liquid hydrocarbon greater than about 2:1, a minor amount of a porous absorbent silica sufficient to stabilize the emulsion, and a minor amount of a moderately strong acid sufficient to provide a pH of about 0.5 to 3.5.
Claim 9
Dependent Claim
65 words
An acidic, acid-stable, hydrocarbon-in-water emulsion comprising an emulsion-providing combination consisting essentially of a liquid hydrocarbon, water in an amount to provide a weight ratio of water to liquid hydrocarbon greater than about 2:1, a minor amount of a porous absorbent silica sufficient to stabilize the emulsion, and a minor amount of a moderately strong acid sufficient to provide a pH of about 0.5 to 3.5.
Claim 10
Dependent Claim
16 words
The emulsion of claim 7 wherein the water to hydrocarbon ratio is about 14:1 to 3:1.
Claim 11
Dependent Claim
23 words
The emulsion of claim 7 wherein the amount of absorbent is about 1 to 4 times by weight of the amount of hydrocarbon.
Claim 12
Dependent Claim
13 words
The emulsion of claim 7 wherein the moderately strong acid is oxalic acid.
Claim 13
Dependent Claim
13 words
The emulsion of claim 7 wherein the moderately strong acid is sulfamic acid.
Claim 14
Dependent Claim
20 words
The emulsion of claim 11 wherein the emulsion contains sufficient thickening agent to provide a gel-like consistency to the emulsion.
Claim 15
Dependent Claim
137 words
An acidic cleaning composition in the form of a stable hydrocarbon-in-water emulsion for cleaning surfaces consisting essentially of a liquid hydrocarbon; water, wherein the weight ratio of water to liquid hydrocarbon is greater than about 2:1; a minor amount of a porous silica absorbent, said absorbent having a surface area of at least about 100 square meters per gram and a particle size in the range of about 10 to 200 microns in diameter sufficient to stabilize the composition; and a minor amount of a moderately strong acid sufficient to provide a pH of about 0.5 to 3.5, said emulsion further containing a minor amount of an amine soap of an aliphatic carboxylic acid having about 10 to 24 carbon atoms and a secondary or tertiary lower alkanol amine, to enhance the cleaning activity of the composition.
Claim 16
Dependent Claim
137 words
An acidic cleaning composition in the form of a stable hydrocarbon-in-water emulsion for cleaning surfaces consisting essentially of a liquid hydrocarbon; water, wherein the weight ratio of water to liquid hydrocarbon is greater than about 2:1; a minor amount of a porous silica absorbent, said absorbent having a surface area of at least about 100 square meters per gram and a particle size in the range of about 10 to 200 microns in diameter sufficient to stabilize the composition; and a minor amount of a moderately strong acid sufficient to provide a pH of about 0.5 to 3.5, said emulsion further containing a minor amount of an amine soap of an aliphatic carboxylic acid having about 10 to 24 carbon atoms and a secondary or tertiary lower alkanol amine, to enhance the cleaning activity of the composition.
Claim 17
Dependent Claim
28 words
The cleaning composition of claim 7 or 13 wherein the cleaning composition contains a minor amount of a straight-chain polysilicone to provide a smooth-feeling surface which resists soiling.
Claim 18
Dependent Claim
21 words
The cleaning composition of claim 14 wherein the emulsion contains sufficient thickening agent to provide a gel-like consistency to the emulsion.
Claim 19
Dependent Claim
14 words
The cleaning composition of claim 13 wherein the moderately strong acid is oxalic acid.
Claim 20
Dependent Claim
14 words
The cleaning composition of claim 13 wherein the moderately strong acid is sulfamic acid.
Claim 21
Dependent Claim
81 words
An acidic, acid-stable, hydrocarbon-in-water emulsion comprising about 3 to 20 weight percent liquid hydrocarbon having a boiling range of about 130° C. to 350° C.; about 15 to 35 weight percent porous silica absorbent, said absorbent having a surface area of at least about 100 square meters per gram; a minor amount of a moderately strong acid sufficient to provide a pH of about 0.5 to 3.5; and water in a weight ratio to said liquid hydrocarbon greater than about 2:1.
Claim 22
Dependent Claim
81 words
An acidic, acid-stable, hydrocarbon-in-water emulsion comprising about 3 to 20 weight percent liquid hydrocarbon having a boiling range of about 130° C. to 350° C.; about 15 to 35 weight percent porous silica absorbent, said absorbent having a surface area of at least about 100 square meters per gram; a minor amount of a moderately strong acid sufficient to provide a pH of about 0.5 to 3.5; and water in a weight ratio to said liquid hydrocarbon greater than about 2:1.
References Cited (Backward Citations)
US2261700A
Cited
US3271319A
Cited
US3325415A
Cited
US3681122A
Cited
US3794523A
Cited
US3806460A
Cited
US3799266A
Cited
US3997460A
Cited
US4010105A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-07-15 | 1984-01-14 | 1984-07-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-07-15 | 1988-01-14 | 1988-07-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-07-15 | 1992-01-14 | 1992-07-15 | $7700.00 | Window Closed / Lapsed |