US4199552A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the production of synthetic rutile
Assignee: Kerr McGee Corp
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Filing: 1978-05-26
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Granted: 1980-04-22
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Expires: 1998-05-26
Abstract
Abstract An improved process for the production of synthetic rutile from ore containing titanium and iron, such as ilmenite ore, by a multi-step procedure employing controlled reduction, controlled oxidation and acid leaching. More specifically, the ilmenite ore first is reduced thermally such that substantially all of the iron (III) present has been converted to iron (II) and some metallic iron. The reduced ore then is oxidized with an oxidizing gas substantially free of elemental oxygen to convert the metallic iron to iron (II) without the substantial formation of iron (III). The oxidized ore then is leached to remove the iron (II) and calcined to produce synthetic rutile. The synthetic rutile so produced contains in excess of 92 percent titanium dioxide and less than 2 percent iron (III), by weight. Often, the synthetic rutile contains less than 1 percent total iron by weight.
Inventors
- 👤 Theodore A. Rado
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 16:25
CPC Classifications
C; C22; C22B; C22B34/00; C22B34/10; C22B34/12; C22B34/1218; C22B34/1227; C22B34/1204; Y; Y02; Y02P; Y02P10/00; Y02P10/20
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
252 words
A process of improved thermal efficiency for the production of synthetic rutile from an ore containing titanium and iron, comprising: introducing said ore into a rotary kiln having a reduction region and an oxidation region; reducing said ore containing titanium and iron in said reduction region by heating said ore to a temperature in the range of from about 700 degrees C. to about 1100 degrees C. in the presence of a reducing agent such that the iron (III) present in the ore is substantially reduced to iron (II) and some metallic iron and a reduction flue gas is produced; recovering at least a portion of said reduction flue gas from said reduction region of said rotary kiln; introducing said recovered reduction flue gas into said oxidation region of said rotary kiln in such a manner that said reduction flue gas passes countercurrently to said reduced ore within said rotary kiln to cool said reduced ore by heat exchange and oxidize said reduced ore to convert metallic iron to iron (II) without the formation of significant amounts of iron (III); withdrawing the oxidized ore from the rotary kiln; leaching said oxidized ore with a hydrochloric acid solution to substantially remove the iron (II) and any remaining iron (III) present in the ore; and calcining the acid leached ore to produce synthetic rutile, the thermal efficiency of said rotary kiln having been increased by having passed said reduction flue gas countercurrently to said reduced ore in said oxidation region of said rotary kiln.
Claim 2
Dependent Claim
252 words
A process of improved thermal efficiency for the production of synthetic rutile from an ore containing titanium and iron, comprising: introducing said ore into a rotary kiln having a reduction region and an oxidation region; reducing said ore containing titanium and iron in said reduction region by heating said ore to a temperature in the range of from about 700 degrees C. to about 1100 degrees C. in the presence of a reducing agent such that the iron (III) present in the ore is substantially reduced to iron (II) and some metallic iron and a reduction flue gas is produced; recovering at least a portion of said reduction flue gas from said reduction region of said rotary kiln; introducing said recovered reduction flue gas into said oxidation region of said rotary kiln in such a manner that said reduction flue gas passes countercurrently to said reduced ore within said rotary kiln to cool said reduced ore by heat exchange and oxidize said reduced ore to convert metallic iron to iron (II) without the formation of significant amounts of iron (III); withdrawing the oxidized ore from the rotary kiln; leaching said oxidized ore with a hydrochloric acid solution to substantially remove the iron (II) and any remaining iron (III) present in the ore; and calcining the acid leached ore to produce synthetic rutile, the thermal efficiency of said rotary kiln having been increased by having passed said reduction flue gas countercurrently to said reduced ore in said oxidation region of said rotary kiln.
Claim 3
Dependent Claim
50 words
The process of claim 1 wherein the iron (III) in the ore is substantially reduced to iron (II) and some metallic iron defined further as: reducing the iron (III) in the ore such that less than 0.5 percent iron (III), by weight, remains in the ore after reduction is completed.
Claim 4
Dependent Claim
48 words
The process of claim 1 wherein metallic iron is formed by reduction of iron (III) defined further as reducing the iron (III) in the ore such that metallic iron now is present in the range of from about 0.25 to about 4.0 percent of the ore, by weight.
Claim 5
Dependent Claim
28 words
The process of claim 1 wherein the leaching is performed with a hydrochloric acid solution having a 17 percent to about 22 percent hydrochloric acid content, by weight.
Claim 6
Dependent Claim
34 words
The process of claim 1 wherein the leaching is performed with a hydrochloric acid solution having a hydrochloric acid content in the range of from about 18 percent to about 20 percent, by weight.
Claim 7
Dependent Claim
13 words
The process of claim 1 wherein ore containing titanium and iron is ilmenite.
Claim 8
Dependent Claim
30 words
The process of claim 1 wherein the synthetic rutile is defined further as containing in excess of 92 percent titanium dioxide and less than 2 percent iron (III), by weight.
Claim 9
Dependent Claim
18 words
The process, of claim 7 wherein the synthetic rutile contains less than 1 percent total iron, by weight.
Claim 10
Dependent Claim
26 words
The process of claim 1 wherein the calcining occurs at a temperature in the range of from about 600 degrees C. to about 1100 degrees C.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-04-22 | 1983-10-22 | 1984-04-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-04-22 | 1987-10-22 | 1988-04-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-04-22 | 1991-10-22 | 1992-04-22 | $7700.00 | Window Closed / Lapsed |