Patent US4196233A successfully refreshed from Google Patents.
US4196233A
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US
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Process for coating inorganic substrates with carbides, nitrides and/or carbonitrides
Assignee: Novartis Corp
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Filing: 1977-07-06
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Granted: 1980-04-01
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Expires: 1997-07-06
Abstract
Abstract A process for coating inorganic substrates, especially metallic or metalloid substrates, sintered metal carbides and carbon materials with carbides, nitrides and/or carbonitrides, using certain nitriles as sources of carbon and nitrogen, is described. High deposition rates and smooth coatings of good to very good adhesion are achievable by this process.
Inventors
- 👤 Diethelm Bitzer
- 👤 Dieter Lohmann
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 17:15
CPC Classifications
C; C23; C23C; C23C16/00; C23C16/22; C23C16/30; C23C16/32
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
253 words
A process for producing on an inorganic substrate a coating of material selected from the group consisting of an element carbide, nitride and carbonitride, said element selected from the group consisting of iron, boron, silicon and the transition metals of sub-groups 4 to 6 of the periodic table, which comprises heating said substrate to a temperature of at least 500° C., and contacting said substrate with a gaseous or vaporous reactant stream comprising a mixture of hydrogen; a derivative of said element selected from the group consisting of its hydride, carbonyl, carbonyl-hydride, halide and organometallic compounds; and at least one carbon- and nitrogen-releasing compound of formula I or II ##STR17## wherein X represents ##STR18## an alkyl group with 1-6 carbon atoms; said alkyl group substituted by halogen atoms, ##STR19## an alkenyl group with 2-4 carbon atoms; said alkenyl group substituted by halogen atoms or ##STR20## a cycloalkyl group with 3-6 atoms or an aryl group with 6-10 carbon atoms; said cycloalkyl group or said aryl group substituted by halogen atoms, methyl groups or ##STR21## X 1 represents an alkylene group with 1-10 carbon atoms; an alkenylene group with 2-4 carbon atoms; a phenylene or cyclohexylene group; said phenylene or cyclohexylene group substituted by halogen atoms or ##STR22## or a group of the formula ##STR23## and R 1 and R 2 independently of one another denote hydrogen or an alkyl group with 1-4 carbon atoms, and m denotes an integer from 4 to 7; permitting reaction thereof to form said coating on said substrate.
Claim 2
Dependent Claim
253 words
A process for producing on an inorganic substrate a coating of material selected from the group consisting of an element carbide, nitride and carbonitride, said element selected from the group consisting of iron, boron, silicon and the transition metals of sub-groups 4 to 6 of the periodic table, which comprises heating said substrate to a temperature of at least 500° C., and contacting said substrate with a gaseous or vaporous reactant stream comprising a mixture of hydrogen; a derivative of said element selected from the group consisting of its hydride, carbonyl, carbonyl-hydride, halide and organometallic compounds; and at least one carbon- and nitrogen-releasing compound of formula I or II ##STR17## wherein X represents ##STR18## an alkyl group with 1-6 carbon atoms; said alkyl group substituted by halogen atoms, ##STR19## an alkenyl group with 2-4 carbon atoms; said alkenyl group substituted by halogen atoms or ##STR20## a cycloalkyl group with 3-6 atoms or an aryl group with 6-10 carbon atoms; said cycloalkyl group or said aryl group substituted by halogen atoms, methyl groups or ##STR21## X 1 represents an alkylene group with 1-10 carbon atoms; an alkenylene group with 2-4 carbon atoms; a phenylene or cyclohexylene group; said phenylene or cyclohexylene group substituted by halogen atoms or ##STR22## or a group of the formula ##STR23## and R 1 and R 2 independently of one another denote hydrogen or an alkyl group with 1-4 carbon atoms, and m denotes an integer from 4 to 7; permitting reaction thereof to form said coating on said substrate.
Claim 3
Dependent Claim
40 words
A process according to claim 1 using at least one compound of the formula II, wherein X 1 represents an unsubstituted alkylene group with 1-4 carbon atoms, an unsubstituted phenylene or cyclohexylene group or a group of the formula ##STR24##
Claim 4
Dependent Claim
19 words
A process as claimed in claim 1, characterized by the use of acetonitrile as the compound of formula I.
Claim 5
Dependent Claim
19 words
A process as claimed in claim 1, characterized by the use of acrylonitrile as the compound of formula I.
Claim 6
Dependent Claim
21 words
A process as claimed in claim 1, characterized by the use of adipic acid dinitrile as the compound of formula II.
Claim 7
Dependent Claim
21 words
A process as claimed in claim 1, characterized by the use of succinic acid dinitrile as the compound of formula II.
Claim 8
Dependent Claim
19 words
A process as claimed in claim 1, characterized by the use of tetracyanoethylene as the compound of formula II.
Claim 9
Dependent Claim
78 words
A process according to claim 1 using at least one compound of formula I wherein X represents an alkyl group with 1-4 carbon atoms; said alkyl group substituted by chlorine atoms or ##STR25## an alkenyl group with 2-4 carbon atoms; said alkenyl group substituted with chlorine atoms; phenyl; or said phenyl substituted by halogen atoms; methyl groups or ##STR26## where R 1 and R 2 independently of one another denote hydrogen or an alkyl with 1-2 carbon atoms.
Claim 10
Dependent Claim
16 words
A process according to claim 1 wherein the inorganic substrate is a metallic or metalloid material.
Claim 11
Dependent Claim
15 words
A process according to claim 1 wherein the inorganic substrate is a sintered metal carbide.
Claim 12
Dependent Claim
14 words
A process according to claim 1 wherein the inorganic substrate is a carbon material.
Claim 13
Dependent Claim
24 words
A process according to claim 1 which further comprises adding argon as a carrier gas to transport the starting materials into the reaction zone.
Claim 14
Dependent Claim
20 words
A process according to claim 1 wherein said substrate is heated to a temperature of 800° C. to 1500° C.
Claim 15
Dependent Claim
17 words
A process according to claim 1 wherein the reaction pressure is from 20 to 800 mm Hg.
Claim 16
Dependent Claim
28 words
A process according to claim 1 wherein said carbon and nitrogen-releasing compound is present in the gaseous reactant stream at a concentration of up to 10% by volume.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-04-01 | 1983-10-01 | 1984-04-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-04-01 | 1987-10-01 | 1988-04-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-04-01 | 1991-10-01 | 1992-04-01 | $7700.00 | Window Closed / Lapsed |