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US4193916A Expired / Lapsed US ⏱️ 0.0 years remaining

Sulfo- or carboxy-aryl amino sulfonyl phenyl azo hydroxpyridine heavy metal complex dyes

Assignee: BASF Corp
•
Filing: 1977-09-28
•
Granted: 1980-03-18
•
Expires: 1997-09-28
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Abstract

Abstract A heavy metal complex of an azo compound of the formula ##STR1## in which A is a substituted or unsubstituted carboxy- or sulpho-phenyl radical or a carboxy- or sulpho- naphthyl radical, p is 1 or 2, R 1 is hydrogen, chlorine, bromine, nitro, alkyl, alkoxy, aryloxy or acylamino, R 2 is hydrogen or alkyl, R 3 is hydroxyl or amino, R 4 is hydrogen, chlorine, bromine, cyano, amino, amino substituted by 1 or 2 alkyl radicals, arylamino, morpholino, pyrrolidino, piperidino, mercapto, alkylthio, arylthio, sulpho or arylsulphonyl and R 5 is hydrogen, chlorine or bromine and one of the radicals R 1 and --SO 2 --NR 2 --A is bonded to the benzene ring in the 4-position and the other is bonded to the benzene ring in the 5-position or 6-position, and 1 or 2 molecules of the azo compound of the formula (1) are bonded to one atom of copper, nickel, chromium or cobalt; such dyes being suitable for dyeing and printing polyamide materials, such as wool, silk, leather and synthetic polyamides.

Inventors

  • 👤 Gerhard Back
  • 👤 Alfred Fasciati

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 14:34
CPC Classifications
C; C09; C09B; C09B45/00; D; D06; D06P; D06P1/00; D06P1/02; D06P1/10

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 121 words
A 1:1 or 1:2 copper, nickel, chromium or cobalt metal complex dye of an azo compound of the formula ##STR103## wherein A is carboxyphenyl or sulfophenyl which are unsubstituted or substituted by chloro, methyl, methoxy or acetylamino; p is 1 or 2; R 1 is hydrogen; chloro; bromo; nitro; C 1 -C 4 alkyl; C 1 -C 4 -alkoxy; C 1 -C 4 alkanoylamino; C 1 -C 4 alkoxycarbonylamino; or phenoxy which is unsubstituted or substituted by chloro, bromo, methyl, methoxy or nitro; R 2 is hydrogen or C 1 -C 4 alkyl; and with the proviso that one of --R 1 and --SO 2 NR 2 --A is in the 4-position and the other is in the 5- or 6-position.
Claim 2
Dependent Claim 121 words
A 1:1 or 1:2 copper, nickel, chromium or cobalt metal complex dye of an azo compound of the formula ##STR103## wherein A is carboxyphenyl or sulfophenyl which are unsubstituted or substituted by chloro, methyl, methoxy or acetylamino; p is 1 or 2; R 1 is hydrogen; chloro; bromo; nitro; C 1 -C 4 alkyl; C 1 -C 4 -alkoxy; C 1 -C 4 alkanoylamino; C 1 -C 4 alkoxycarbonylamino; or phenoxy which is unsubstituted or substituted by chloro, bromo, methyl, methoxy or nitro; R 2 is hydrogen or C 1 -C 4 alkyl; and with the proviso that one of --R 1 and --SO 2 NR 2 --A is in the 4-position and the other is in the 5- or 6-position.
Claim 3
Dependent Claim 18 words
A metal complex dye according to claim 1, which is a 1:1 copper or nickel metal complex dye.
Claim 4
Dependent Claim 18 words
A metal complex dye according to claim 1, which is a 1:2 nickel or cobalt metal complex dye.
Claim 5
Dependent Claim 15 words
A metal complex dye according to claim 1, which is a 1:1 chromium complex dye.
Claim 6
Dependent Claim 12 words
A metal complex dye according to claim 1, wherein p is 1.
Claim 7
Dependent Claim 29 words
A 1:1 copper complex dye according to claim 1, of an azo compound of the formula ##STR104## wherein R 1 ' is hydrogen, chloro, bromo, methyl, methoxy or nitro.

References Cited (Backward Citations)

US3971738A Cited
US3869440A Cited
US3870695A Cited
GB1476807A Cited
GB1479948A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-03-18 1983-09-17 1984-03-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-03-18 1987-09-17 1988-03-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-03-18 1991-09-17 1992-03-18 $7700.00 Window Closed / Lapsed

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