Heavy metal complexes of azo compounds containing a halogeno-2,3-dihydroxy pyridine coupling component

Claim 1

A 1:1 or 1:2 chromium, cobalt, copper or nickel complex of a dyestuff of the formula ##SPC7## herein X is fluoro, chloro or bromo, D is phenyl or napthyl that contains, in the position ortho to the azo bridge; hydroxyl, amino or carboxyl, or if D is phenyl, also methoxy, and where said phenyl is further unsubstituted or substituted by chloro, methoxy, acetylamino, nitro, methyl, acetyl, carbonamido, sulfonamido, methylsulfonyl, sulfo, N-β-hydroxyethylsulfonamido, N-methylsulfonamido, N,N-dimethylsulfonamido, ethylsulfonyl, benzoylamino, β-hydroxyethylsulfonyl, (3'-methoxy, 4'-amino-)-phenyl-, mono- or di-sulfophenylazo, carboxysulfophenylazo, disulfonapthylazo, phenylazo, or an acylamino fiber reactive group wherein acyl is chloroacetyl, bromoacetyl, β-chloropropionyl, β-bromopropionyl, α,β-dichloropropionyl, α,β-dibromopropionyl, chloromaleyl, acrylyl, β-chloroacrylyl, β-bromoacrylyl, α-chlorocryly, α-bromoacrylyl, α,β-dibromoacrylyl, trichloroacylyl, chlorocrotonyl or propionyl, and where said napthyl is further unsubstituted or substituted by sulfo, sulfonamido, nitro, acetylamino or sulfophenylazo.