Soluble resinous products of polyepoxide-amine adducts and cyclic dicarboxylic acid anhydrides

Claim 2

A resinous composition comprising the acid-amide reaction product of (A) an adduct of (1) a polyepoxide resin derived from a dihydric phenol and an epihalohydrin, said polyepoxide resin having a 1,2-epoxide equivalent weight of about 450 to about 4000; and (2) an alkyl primary monoamine or a polyamine having at least 2 amine nitrogen atoms per molecule and at least 3 amine hydrogen atoms per molecule, said amines having no other groups reactive with epoxide groups; and (B) maleic or succinic anhydride wherein about one mol of (2) is reacted with each epoxide equivalent of (1) and wherein about 0.5 to 1 mol of (B) is reacted per each amine nitrogen atom in said adduct.

Claim 3

The composition of claim 1 wherein the polyepoxide resin is derived from p,p'-dihydroxydiphenyl propane and epichlorohydrin and has a 1,2-epoxide equivalent weight of about 800 to about 2000.

Claim 4

The composition of claim 1 wherein the alkyl group of the primary monoamine contains 3 to 18 carbon atoms.

Claim 5

The composition of claim 1 wherein the polyamine is an alkylene polyamine having the formula ##STR2## wherein n is an integer of 0 to 4 and R is an alkylene group containing 2 to 4 carbon atoms.

Claim 6

The composition of claim 4 wherein the alkylene polyamine is an ethylene polyamine.

Claim 7

The composition of claim 5 wherein the ethylene polyamine is ethylene diamine.

Claim 8

The composition of claim 1 wherein about 0.7 to about 1 mol of anhydride is reacted per each amine nitrogen atom.

Claim 9

A resinous composition comprising the acid-amide reaction product of (A) an adduct of (1) a polyepoxide resin derived from a dihydric phenol and an epihalohydrin, said polyepoxide resin having a 1,2-epoxide equivalent weight of about 450 to about 4000; (2) a polyamine having at least 2 amine nitrogen atoms per molecule and at least 3 amine hydrogen atoms per molecule, said amine having no other groups reactive with epoxide groups; and (3) a monoepoxide which contains one 1,2-epoxide group and no other groups reactive with amine groups, said monoepoxide having about 8 to 24 carbon atoms per molecule; and (B) maleic or succinic anhydride, wherein about one mol of (2) is reacted with each epoxide equivalent of (1), wherein 0 to about (x-2) mols of (3) are reacted per mol of polyamine wherein x represents the number of amine hydrogens originally present, and wherein about 0.5 to about 1 mol of B is reacted per each primary and secondary amine group in said adduct.

Claim 10

A resinous composition comprising the acid-amide reaction product of (A) an adduct of (1) a polyepoxide resin derived from a dihydric phenol and an epihalohydrin, said polyepoxide resin having a 1,2-epoxide equivalent weight of about 450 to about 4000; (2) a polyamine having at least 2 amine nitrogen atoms per molecule and at least 3 amine hydrogen atoms per molecule, said amine having no other groups reactive with epoxide groups; and (3) a monoepoxide which contains one 1,2-epoxide group and no other groups reactive with amine groups, said monoepoxide having about 8 to 24 carbon atoms per molecule; and (B) maleic or succinic anhydride, wherein about one mol of (2) is reacted with each epoxide equivalent of (1), wherein 0 to about (x-2) mols of (3) are reacted per mol of polyamine wherein x represents the number of amine hydrogens originally present, and wherein about 0.5 to about 1 mol of B is reacted per each primary and secondary amine group in said adduct.

Claim 11

The composition of claim 8 wherein the polyepoxide resin is derived from p,p'-dihydroxydiphenyl propane and epichlorohydrin and has a 1,2-epoxide equivalent weight of about 800 to about 2000.

Claim 12

The composition of claim 8 wherein the polyamine is an alkylene polyamine having the formula ##STR3## wherein n is an integer of 0 to 4 and R is an alkylene group containing 2 to 4 carbon atoms.

Claim 13

The composition of claim 10 wherein the alkylene polyamine is an ethylene polyamine.

Claim 14

The composition of claim 11 wherein the ethylene polyamine is ethylene diamine.

Claim 15

The composition of claim 8 wherein the monoepoxide is a glycidyl ether of a fatty alcohol wherein the fatty alcohol contains 8 to 18 carbon atoms.

Claim 16

The composition of claim 8 wherein two to three mols of monoepoxide are reacted per mol of adduct and wherein 2.8 to 4 mols of anhydride are reacted per mol of adduct.