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Process for improving the color yield and fastness properties of dyeings produced with anionic dyes on cellulose fibre material and fluorine-containing cationic compounds

Assignee: BASF Corp
•
Filing: 1977-06-09
•
Granted: 1979-10-23
•
Expires: 1997-06-09
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Abstract

Abstract A process for improving the color yield and the wet-fastness properties of dyeings produced on cellulose fibrous material with anionic dyes which process comprises treating the cellulose material before, during or after dyeing, with a fluorine-containing cationic compound of the formula ##STR1## WHEREIN B represents a triazine or pyrimidine radical, W represents a reactive fluorine atom, Z represents halogen, lower alkyl, phenyl, lower alkoxy, lower alkylthio, phenoxy, phenylthio, --NH 2 , or the group of the formula ##STR2## EACH OF Ar 1 and Ar 2 independently represents an aromatic radical, Each of R 1 and R 2 independently represents hydrogen, lower alkyl or hydroxy-lower alkyl, Each of X, x 1 , x 2 , y 1 , y 2 , v 1 and V 2 independently represents lower alkyl, benzyl, or lower alkyl which is substituted by halogen, hydroxyl or cyano, and X also represents phenyl or methylphenyl, or Each of the pair of substituents X 1 and X 2 and Y 1 and Y 2 , together with the nitrogen atom to which it is attached, represents a 5- or 6-membered heterocyclic radical, An.sup.⊖ represents the anion of an organic or inorganic acid, and N is 1 or 2.

Inventors

  • 👤 Pierre Perrin
  • 👤 Gert Hegar
  • 👤 Gerald Siegrist
  • 👤 Herbert Seiler
  • 👤 Ulrich Horn

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 19:51
CPC Classifications
D; D06; D06P; D06P3/00; D06P3/58; D06P3/60; C; C07; C07D; C07D251/00; C07D251/02; C07D251/12; C07D251/26; C07D251/40; C07D251/42; C07D251/44; C07D251/46; C07D251/48; C07D251/50; C09; C09B; C09B62/00; C09B62/02; D06P1/00; D06P1/44; D06P1/655; D06P1/66; D06P5/00; D06P5/02; D06P5/04; D06P5/06

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 200 words
A process for improving the colour yield and the wetfastness properties of dyeings produced on cellulose fiber material with anionic dyes which process comprises treating the cellulose material before, during or after dyeing, with a fluorine-containing cationic compound of the formula ##STR21## wherein B represents a triazinyl or pyrimidyl radical, W represents a reactive fluorine atom, Z represents halogen, lower alkyl, phenyl, lower alkoxy, lower alkylthio, phenoxy, phenylthio, --NH 2 , or the group of the formula ##STR22## each of Ar 1 and Ar 2 independently represents an aromatic radical, each of R 1 and R 2 independently represents hydrogen, lower alkyl or hydroxy-lower alkyl, each of X, x 1 , x 2 , y 1 , y 2 , v 1 and V 2 independently represents lower alkyl, benzyl, or lower alkyl which is substituted by halogen, hydroxyl or cyano, and X also represents phenyl or methylphenyl, or each of the pair of substituents X 1 and X 2 and Y 1 and Y 2 , together with the nitrogen atom to which it is attached, represents a 5- or 6-membered heterocyclic radical, An.sup.⊖ represents the anion of an organic or inorganic acid, and n is 1 or 2.
Claim 2
Dependent Claim 200 words
A process for improving the colour yield and the wetfastness properties of dyeings produced on cellulose fiber material with anionic dyes which process comprises treating the cellulose material before, during or after dyeing, with a fluorine-containing cationic compound of the formula ##STR21## wherein B represents a triazinyl or pyrimidyl radical, W represents a reactive fluorine atom, Z represents halogen, lower alkyl, phenyl, lower alkoxy, lower alkylthio, phenoxy, phenylthio, --NH 2 , or the group of the formula ##STR22## each of Ar 1 and Ar 2 independently represents an aromatic radical, each of R 1 and R 2 independently represents hydrogen, lower alkyl or hydroxy-lower alkyl, each of X, x 1 , x 2 , y 1 , y 2 , v 1 and V 2 independently represents lower alkyl, benzyl, or lower alkyl which is substituted by halogen, hydroxyl or cyano, and X also represents phenyl or methylphenyl, or each of the pair of substituents X 1 and X 2 and Y 1 and Y 2 , together with the nitrogen atom to which it is attached, represents a 5- or 6-membered heterocyclic radical, An.sup.⊖ represents the anion of an organic or inorganic acid, and n is 1 or 2.
Claim 3
Dependent Claim 23 words
A process according to claim 1 which comprises the use of a compound of the formula (1), wherein B represents a 1,3,5-triazinyl radical.
Claim 4
Dependent Claim 26 words
A process according to claim 1, which comprises the use of a compound of the formula (1), wherein Z represents a group of the formula (1b).
Claim 5
Dependent Claim 27 words
A process according to claim 1 which comprises the use of a compound of the formula (1), wherein each of Ar 1 and Ar 2 represents phenylene.
Claim 6
Dependent Claim 73 words
A process according to claim 1 which comprises the use of a fluorine-containing compound of the formula ##STR23## wherein An.sup.⊖, Ar 1 and Ar 2 are as defined in claim 1, each of R 3 and R 4 independently represents hydrogen, methyl or ethyl, each of X 3 , x 4 , y 3 and Y 4 represents lower alkyl, and each of V 3 and V 4 represents lower alkyl or benzyl.
Claim 7
Dependent Claim 27 words
A process according to claim 5 which comprises the use of a compound of the formula (2), wherein each of Ar 1 and Ar 2 represents phenylene.
Claim 8
Dependent Claim 41 words
A process according to claim 1 which comprises the use of a fluorine-containing triazinyl compound of the formula ##STR24## wherein X 5 represents methyl or ethyl, V 5 represents methyl, ethyl or benzyl, and An.sup.⊖ is as defined in claim 1.
Claim 9
Dependent Claim 36 words
A process according to claim 7 which comprises the use of a fluorine-containing triazinyl-containing compound of the formula (3), in which each of X 5 and V 5 represents methyl and An.sup.⊖ represents a chloride ion.
Claim 10
Dependent Claim 46 words
A process according to claim 1 which comprises the use of a fluorine-containing pyrimidyl compound of the formula ##STR25## wherein X 5 represents methyl or ethyl, V 5 represents methyl, ethyl or benzyl, T represents hydrogen or chlorine, and An.sup.⊖ is as defined in claim 1.
Claim 11
Dependent Claim 51 words
A process according to claim 9 which comprises the use of a fluorine-containing pyrimidyl compound of the formula (4), in which each of X 5 and V 5 represents methyl, T represents chlorine and An.sup.⊖ represents a chloride ion and the trimethylammonium group is in the meta-position to the --NH-- group.
Claim 12
Dependent Claim 26 words
A process according to claim 1 wherein the treatment of the cellulose material with the fluorine-containing cationic compound is carried out before or after the dyeing.
Claim 13
Dependent Claim 19 words
A process according to claim 11 wherein the treatment of the cellulose material is carried out after the dyeing.
Claim 14
Dependent Claim 22 words
A process according to claim 11 wherein the pre- or aftertreatment of the cellulose material is carried out by an exhaustion process.
Claim 15
Dependent Claim 23 words
A process according to claim 11 wherein the pre- or aftertreatment of the cellulose material is carried out by a cold pad-batch process.

References Cited (Backward Citations)

US2415554A Cited
DE633691C Cited
DE1094699B Cited
US3122542A Cited
DE1134964B Cited
US3271147A Cited
US3310557A Cited
US3632294A Cited
US3679348A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-10-22 1983-04-23 1983-10-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-10-22 1987-04-23 1987-10-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-10-22 1991-04-23 1991-10-23 $7700.00 Window Closed / Lapsed

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