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Rare earth or yttrium, transition metal oxide thermistors

Assignee: Ford Motor Co
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Filing: 1977-12-05
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Granted: 1979-07-31
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Expires: 1997-12-05
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Abstract

Abstract Thermistors comprising transition metal such as iron, rare earth of the lanthanide series or yttrium, and oxygen exhibit sufficient independence to variation in oxygen partial pressure over a range of exhaust gas conditions of internal combustion engines as to make them particularly suitable for temperature compensation of oxygen sensors such as those derived from titania as well as temperature sensing in other oxygen varying environments.

Inventors

  • 👤 Eleftherios M. Logothetis
  • 👤 Kamlakar R. Laud
  • 👤 John K. Park

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 13:41
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/50; G; G01; G01N; G01N27/00; G01N27/02; G01N27/04; G01N27/12; H; H01; H01C; H01C7/00; H01C7/04; H01C7/042; H01C7/043

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 61 words
A method of sensing temperature in an oxygen varying environment that contains combustion engine exhaust gas which comprises exposing to the environment a thermistor composition comprising (a) transition metal comprising iron, (b) one or more rare earth of the lanthanide series or yttrium and (c) oxygen in a respective molar ratio of the ions of about 1:1:3 and detecting its resistance.
Claim 2
Independent Claim 61 words
A method of sensing temperature in an oxygen varying environment that contains combustion engine exhaust gas which comprises exposing to the environment a thermistor composition comprising (a) transition metal comprising iron, (b) one or more rare earth of the lanthanide series or yttrium and (c) oxygen in a respective molar ratio of the ions of about 1:1:3 and detecting its resistance.
Claim 3
Dependent Claim 13 words
A method in accordance with claim 1, wherein the rare earth comprises praseodymium.
Claim 4
Dependent Claim 32 words
A method in accordance with claim 1, wherein the thermistor composition comprises a compound having a formula corresponding to RFeO 3 wherein R is rare earth of the lanthanide series or yttrium.
Claim 5
Dependent Claim 23 words
A method in accordance with claim 3, wherein the compound comprises a single phase having a density higher than about 60% of theoretical.
Claim 6
Dependent Claim 13 words
A method in accordance with claim 4, wherein the rare earth comprises praseodymium.
Claim 7
Dependent Claim 45 words
In an automotive feedback fuel control system that utilizes an oxygen sensor comprising titania and a thermistor in series electrical connection therewith for temperature compensation of the oxygen sensor, the improvement wherein the thermistor comprises a compound having a formula corresponding to PrFeO 3 .
Claim 8
Dependent Claim 45 words
In an automotive feedback fuel control system that utilizes an oxygen sensor comprising titania and a thermistor in series electrical connection therewith for temperature compensation of the oxygen sensor, the improvement wherein the thermistor comprises a compound having a formula corresponding to PrFeO 3 .
Claim 9
Independent Claim 61 words
A method of sensing temperature in an oxygen varying environment which comprises exposing to the environment a thermistor composition comprising a compound having a formula corresponding to RFeO 3 wherein R is a rare earth of the lanthanide series or yttrium, the thermistor composition being in electrical communication with an oxygen sensor comprising titania, and detecting resistance of the thermistor composition.
Claim 10
Independent Claim 61 words
A method of sensing temperature in an oxygen varying environment which comprises exposing to the environment a thermistor composition comprising a compound having a formula corresponding to RFeO 3 wherein R is a rare earth of the lanthanide series or yttrium, the thermistor composition being in electrical communication with an oxygen sensor comprising titania, and detecting resistance of the thermistor composition.
Claim 11
Dependent Claim 22 words
A method in accordance with claim 7 wherein the thermistor composition comprises a compound having a formula corresponding to PrFeO 3 .
Claim 12
Dependent Claim 22 words
A method in accordance with claim 7 wherein the thermistor composition comprises a compound having a formula corresponding to PrFeO 3 .
Claim 13
Independent Claim 65 words
A method of sensing temperature in an oxygen varying environment that contains combustion engine exhaust gas which comprises exposing to the environment a thermistor composition comprising a compound having a formula corresponding to RFeO 3 wherein R is a rare earth of the lanthanide series or yttrium, the thermistor composition being used in combination with an oxygen sensor and detecting resistance of the thermistor composition.
Claim 14
Independent Claim 65 words
A method of sensing temperature in an oxygen varying environment that contains combustion engine exhaust gas which comprises exposing to the environment a thermistor composition comprising a compound having a formula corresponding to RFeO 3 wherein R is a rare earth of the lanthanide series or yttrium, the thermistor composition being used in combination with an oxygen sensor and detecting resistance of the thermistor composition.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-07-30 1983-01-29 1983-07-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-07-30 1987-01-29 1987-07-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-07-30 1991-01-29 1991-07-31 $7700.00 Window Closed / Lapsed

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