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US4157893A
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Uniformly dyed water-swellable cellulosic fibers
Assignee: BASF SE
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Filing: 1978-04-07
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Granted: 1979-06-12
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Expires: 1998-04-07
Abstract
Abstract Uniformly dyed water-swellable cellulosic fibers obtained by dyeing cellulosic fibers in the swollen state with a dye of the formula <IMAGE> in which one R is R1, OR1, SR1 or <IMAGE> the other R is <IMAGE> R1 and R2 independently of one another are hydrogen or an aliphatic, cycloaliphatic, araliphatic or aromatic radical, <IMAGE> may also be a saturated heterocyclic radical, and D is the radical of a diazo component. The dyed fibers exhibit very good fastness properties.
Inventors
- 👤 Johannes Dehnert
- 👤 Guenter Dunkelmann
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 23:48
CPC Classifications
D; D06; D06P; D06P3/00; D06P3/58; D06P3/60; D06P3/6033; D06P3/6041; C; C09; C09B; C09B29/00; C09B29/34; C09B29/36; C09B29/3604; C09B29/3665; C09B29/3669; C09B31/00; C09B31/02; C09B31/12; C09B31/14
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
238 words
Uniformly dyed water-swellable cellulosic fibers, said fibers being fast to washing, dry cleaning, sublimation and light, and having been produced by contacting water-swellable cellulose fibers sequentially or concomitantly with water, ethylene glycol or a derivative thereof and, while the fibers are still swollen with an essentially water-insoluble dye of the formula ##STR222## in which one R is R 1 , or ##STR223## the other R is ##STR224## D is phenyl which is substituted by cyano, trifluoromethyl, ##STR225## or D is anthraquinonyl which is unsubstituted or substituted by methyl; R 1 is hydrogen, alkyl or 1 to 8 carbon atoms, alkyl of 2 to 8 carbon atoms which is substituted by hydroxyl, alkoxy of 1 to 8 carbon atoms, benzyloxy or β-phenylethoxy; phenylakyl (where alkyl is of 1 to 4 carbon atoms), tolylalkyl (where alkyl is of 1 to 4 carbon atoms), phenyl, which is unsubstituted or substituted by methyl, ethyl or R 1 is (CH 2 ) 3 OC 2 H 4 C 6 H 5 ; R 2 is hydrogen, alkyl of 1 to 8 carbon atoms, or alkyl of 2 to 9 carbon atoms substituted by hydroxyl or alkoxy of 1 to 8 carbon atoms, T 1 is hydrogen, chlorine, bromine, methyl, methoxy or ethoxy, T 2 is hydrogen, methyl, methoxy or ethoxy, T 3 is hydrogen, methyl, chlorine, bromine, nitro, T 4 is hydrogen, chlorine or bromine and T 5 is hydrogen, methyl or ethyl.
Claim 2
Dependent Claim
238 words
Uniformly dyed water-swellable cellulosic fibers, said fibers being fast to washing, dry cleaning, sublimation and light, and having been produced by contacting water-swellable cellulose fibers sequentially or concomitantly with water, ethylene glycol or a derivative thereof and, while the fibers are still swollen with an essentially water-insoluble dye of the formula ##STR222## in which one R is R 1 , or ##STR223## the other R is ##STR224## D is phenyl which is substituted by cyano, trifluoromethyl, ##STR225## or D is anthraquinonyl which is unsubstituted or substituted by methyl; R 1 is hydrogen, alkyl or 1 to 8 carbon atoms, alkyl of 2 to 8 carbon atoms which is substituted by hydroxyl, alkoxy of 1 to 8 carbon atoms, benzyloxy or β-phenylethoxy; phenylakyl (where alkyl is of 1 to 4 carbon atoms), tolylalkyl (where alkyl is of 1 to 4 carbon atoms), phenyl, which is unsubstituted or substituted by methyl, ethyl or R 1 is (CH 2 ) 3 OC 2 H 4 C 6 H 5 ; R 2 is hydrogen, alkyl of 1 to 8 carbon atoms, or alkyl of 2 to 9 carbon atoms substituted by hydroxyl or alkoxy of 1 to 8 carbon atoms, T 1 is hydrogen, chlorine, bromine, methyl, methoxy or ethoxy, T 2 is hydrogen, methyl, methoxy or ethoxy, T 3 is hydrogen, methyl, chlorine, bromine, nitro, T 4 is hydrogen, chlorine or bromine and T 5 is hydrogen, methyl or ethyl.
Claim 3
Dependent Claim
143 words
The dyed fibers according to claim 1, wherein D is phenyl substituted by cyano, trifluoromethyl, ##STR226## or anthraquinonyl, R 1 is hydrogen, C 1 to C 8 alkyl, C 2 to C 8 alkyl substituted by hydroxy, C 1 to C 4 alkoxy, benzyloxy, β-phenylethoxy; phenyl-C 1 to C 4 -alkyl; phenyl, phenyl substituted by methyl or R 1 is (CH 2 ) 3 (OC 2 H 4 )OC 6 H 5 , R 2 is hydrogen, alkyl of 1 to 8 carbon atoms, alkyl of 2 to 9 carbon atoms substituted by hydroxyl or alkoxy of 1 to 8 carbon atoms, T 1 is hydrogen, chlorine, bromine, methyl, methoxy or ethoxy, T 2 is hydrogen, methyl, methoxy or ethoxy, T 3 is hydrogen, methyl, chlorine, bromine, nitro, T 4 is hydrogen, chlorine or bromine and T 5 is hydrogen, methyl or ethyl.
Claim 4
Dependent Claim
20 words
The fibers according to claim 1 dyed with a dye of the formula ##STR227## where p is 0 or 1.
Claim 5
Dependent Claim
24 words
The fibers according to claim 1 dyed with a dye of the formula ##STR228## where p is 0 or 1 and D is ##STR229##
Claim 6
Dependent Claim
14 words
The fibers according to claim 1 dyed with a dye of the formula ##STR230##
Claim 7
Dependent Claim
13 words
The fibers according to claim 1, wherein said fibers consist essentially of cotton.
Claim 8
Dependent Claim
16 words
The fibers according to claim 1, wherein said fibers comprise a mixture of cotton and polyester.
Claim 9
Dependent Claim
6 words
Printed fibers according to claim 1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-06-11 | 1982-12-11 | 1983-06-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-06-11 | 1986-12-11 | 1987-06-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-06-11 | 1990-12-11 | 1991-06-12 | $7700.00 | Window Closed / Lapsed |