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US4157893A Expired / Lapsed US ⏱️ 0.0 years remaining

Uniformly dyed water-swellable cellulosic fibers

Assignee: BASF SE
•
Filing: 1978-04-07
•
Granted: 1979-06-12
•
Expires: 1998-04-07
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Abstract

Abstract Uniformly dyed water-swellable cellulosic fibers obtained by dyeing cellulosic fibers in the swollen state with a dye of the formula <IMAGE> in which one R is R1, OR1, SR1 or <IMAGE> the other R is <IMAGE> R1 and R2 independently of one another are hydrogen or an aliphatic, cycloaliphatic, araliphatic or aromatic radical, <IMAGE> may also be a saturated heterocyclic radical, and D is the radical of a diazo component. The dyed fibers exhibit very good fastness properties.

Inventors

  • 👤 Johannes Dehnert
  • 👤 Guenter Dunkelmann

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 13:25
CPC Classifications
D; D06; D06P; D06P3/00; D06P3/58; D06P3/60; D06P3/6033; D06P3/6041; C; C09; C09B; C09B29/00; C09B29/34; C09B29/36; C09B29/3604; C09B29/3665; C09B29/3669; C09B31/00; C09B31/02; C09B31/12; C09B31/14

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 238 words
Uniformly dyed water-swellable cellulosic fibers, said fibers being fast to washing, dry cleaning, sublimation and light, and having been produced by contacting water-swellable cellulose fibers sequentially or concomitantly with water, ethylene glycol or a derivative thereof and, while the fibers are still swollen with an essentially water-insoluble dye of the formula ##STR222## in which one R is R 1 , or ##STR223## the other R is ##STR224## D is phenyl which is substituted by cyano, trifluoromethyl, ##STR225## or D is anthraquinonyl which is unsubstituted or substituted by methyl; R 1 is hydrogen, alkyl or 1 to 8 carbon atoms, alkyl of 2 to 8 carbon atoms which is substituted by hydroxyl, alkoxy of 1 to 8 carbon atoms, benzyloxy or β-phenylethoxy; phenylakyl (where alkyl is of 1 to 4 carbon atoms), tolylalkyl (where alkyl is of 1 to 4 carbon atoms), phenyl, which is unsubstituted or substituted by methyl, ethyl or R 1 is (CH 2 ) 3 OC 2 H 4 C 6 H 5 ; R 2 is hydrogen, alkyl of 1 to 8 carbon atoms, or alkyl of 2 to 9 carbon atoms substituted by hydroxyl or alkoxy of 1 to 8 carbon atoms, T 1 is hydrogen, chlorine, bromine, methyl, methoxy or ethoxy, T 2 is hydrogen, methyl, methoxy or ethoxy, T 3 is hydrogen, methyl, chlorine, bromine, nitro, T 4 is hydrogen, chlorine or bromine and T 5 is hydrogen, methyl or ethyl.
Claim 2
Dependent Claim 238 words
Uniformly dyed water-swellable cellulosic fibers, said fibers being fast to washing, dry cleaning, sublimation and light, and having been produced by contacting water-swellable cellulose fibers sequentially or concomitantly with water, ethylene glycol or a derivative thereof and, while the fibers are still swollen with an essentially water-insoluble dye of the formula ##STR222## in which one R is R 1 , or ##STR223## the other R is ##STR224## D is phenyl which is substituted by cyano, trifluoromethyl, ##STR225## or D is anthraquinonyl which is unsubstituted or substituted by methyl; R 1 is hydrogen, alkyl or 1 to 8 carbon atoms, alkyl of 2 to 8 carbon atoms which is substituted by hydroxyl, alkoxy of 1 to 8 carbon atoms, benzyloxy or β-phenylethoxy; phenylakyl (where alkyl is of 1 to 4 carbon atoms), tolylalkyl (where alkyl is of 1 to 4 carbon atoms), phenyl, which is unsubstituted or substituted by methyl, ethyl or R 1 is (CH 2 ) 3 OC 2 H 4 C 6 H 5 ; R 2 is hydrogen, alkyl of 1 to 8 carbon atoms, or alkyl of 2 to 9 carbon atoms substituted by hydroxyl or alkoxy of 1 to 8 carbon atoms, T 1 is hydrogen, chlorine, bromine, methyl, methoxy or ethoxy, T 2 is hydrogen, methyl, methoxy or ethoxy, T 3 is hydrogen, methyl, chlorine, bromine, nitro, T 4 is hydrogen, chlorine or bromine and T 5 is hydrogen, methyl or ethyl.
Claim 3
Dependent Claim 143 words
The dyed fibers according to claim 1, wherein D is phenyl substituted by cyano, trifluoromethyl, ##STR226## or anthraquinonyl, R 1 is hydrogen, C 1 to C 8 alkyl, C 2 to C 8 alkyl substituted by hydroxy, C 1 to C 4 alkoxy, benzyloxy, β-phenylethoxy; phenyl-C 1 to C 4 -alkyl; phenyl, phenyl substituted by methyl or R 1 is (CH 2 ) 3 (OC 2 H 4 )OC 6 H 5 , R 2 is hydrogen, alkyl of 1 to 8 carbon atoms, alkyl of 2 to 9 carbon atoms substituted by hydroxyl or alkoxy of 1 to 8 carbon atoms, T 1 is hydrogen, chlorine, bromine, methyl, methoxy or ethoxy, T 2 is hydrogen, methyl, methoxy or ethoxy, T 3 is hydrogen, methyl, chlorine, bromine, nitro, T 4 is hydrogen, chlorine or bromine and T 5 is hydrogen, methyl or ethyl.
Claim 4
Dependent Claim 20 words
The fibers according to claim 1 dyed with a dye of the formula ##STR227## where p is 0 or 1.
Claim 5
Dependent Claim 24 words
The fibers according to claim 1 dyed with a dye of the formula ##STR228## where p is 0 or 1 and D is ##STR229##
Claim 6
Dependent Claim 14 words
The fibers according to claim 1 dyed with a dye of the formula ##STR230##
Claim 7
Dependent Claim 13 words
The fibers according to claim 1, wherein said fibers consist essentially of cotton.
Claim 8
Dependent Claim 16 words
The fibers according to claim 1, wherein said fibers comprise a mixture of cotton and polyester.
Claim 9
Dependent Claim 6 words
Printed fibers according to claim 1.

References Cited (Backward Citations)

US3667897A Cited
US3711245A Cited
US3706525A Cited
US3752647A Cited
US3752645A Cited
US3752646A Cited
DE2524243A1 Cited
US4049377A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-06-11 1982-12-11 1983-06-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-06-11 1986-12-11 1987-06-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-06-11 1990-12-11 1991-06-12 $7700.00 Window Closed / Lapsed

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