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US4151311A Expired / Lapsed US ⏱️ 0.0 years remaining

Post colloid addition of catalytic promoters to non noble metal principal catalytic compounds in electroless plating catalysts

Assignee: Individual
•
Filing: 1977-09-16
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Granted: 1979-04-24
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Expires: 1997-09-16
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Abstract

Abstract A process and composition for catalyzing a substrate prior to electroless metal deposition. The catalyst formulation comprises the colloidal product resulting from the admixture of a principal catalytic agent and a catalytic promoting agent. The principle catalytic agent is selected from the metals of Period 4 of Groups 1B and VIII of the Periodic Table of the Elements while the catalytic promoting agent is selected from the metals of Period 4, 5, 6 and Groups IVB, VB, VIB and VIIB of the Periodic Table of the Elements, and further the catalytic promoter agent is admixed subsequent to the colloid nucleation process.

Inventors

  • 👤 Nathan Feldstein

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 10:33
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/16; C23C18/18; C23C18/20; C23C18/28

Claims Analysis

Total Claims: 29
Claim 1
Independent Claim 181 words
A process for the catalytically rendering of a non-conductor surface receptive to electroless metal deposition comprising contacting said surface with a colloidal catalytic composition comprising the admixture of a principal catalytic agent wherein said principal catalytic agent is a compound of a metal selected from the groups of metals consisting of copper, nickel, cobalt, and iron and mixtures thereof and a catalytic promoter agent wherein said catalytic promoter agent is a compound of a metal selected from the group of metals consisting of Mg, Ca, Sr, Sc, Y, La, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Tc and Re and mixtures thereof and further said catalytic promoter is added subsequent to the colloidal nucleation process in which the principal catalytic agent is allowed to react as to yield a colloid, and further wherein the concentrations for the principal catalytic agent and the catalytic promoter agent are so adjusted as to yield a catalytic composition having a greater catalytic activity for electroless metal deposition in comparison to the same catalytic composition in the absence of said catalytic promoter agent.
Claim 2
Dependent Claim 181 words
A process for the catalytically rendering of a non-conductor surface receptive to electroless metal deposition comprising contacting said surface with a colloidal catalytic composition comprising the admixture of a principal catalytic agent wherein said principal catalytic agent is a compound of a metal selected from the groups of metals consisting of copper, nickel, cobalt, and iron and mixtures thereof and a catalytic promoter agent wherein said catalytic promoter agent is a compound of a metal selected from the group of metals consisting of Mg, Ca, Sr, Sc, Y, La, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Tc and Re and mixtures thereof and further said catalytic promoter is added subsequent to the colloidal nucleation process in which the principal catalytic agent is allowed to react as to yield a colloid, and further wherein the concentrations for the principal catalytic agent and the catalytic promoter agent are so adjusted as to yield a catalytic composition having a greater catalytic activity for electroless metal deposition in comparison to the same catalytic composition in the absence of said catalytic promoter agent.
Claim 3
Dependent Claim 29 words
The process according to claim 1 wherein said catalytic promoter agent is selected from at least one member of the group consisting of chromium, vanadium, molybdenum, tungsten and zirconium.
Claim 4
Dependent Claim 14 words
The process according to claim 1 wherein said electroless metal deposition is electroless copper.
Claim 5
Dependent Claim 15 words
The process according to claim 1 wherein said electroless metal deposition yields an image intensification.
Claim 6
Dependent Claim 16 words
The process according to claim 1, wherein said principal catalytic agent is a compound containing copper.
Claim 7
Dependent Claim 22 words
The process according to claim 1 further containing the step of activation and wherein said activation step is devoid of precious metal(s).
Claim 8
Dependent Claim 13 words
The process according to claim 6 further containing the step of electroles deposition.
Claim 9
Dependent Claim 11 words
The process according to claim 1 wherein said non-conductor is ABS.
Claim 10
Dependent Claim 13 words
The process according to claim 1 wherein said electroless metal deposition is copper.
Claim 11
Dependent Claim 32 words
The process according to claim 1 wherein said catalytic promoter agent is a compound of a metal selected from the group of metals consisting of Zr, Hf, V, Cr, Mo W, Mn.
Claim 12
Dependent Claim 40 words
The process according to claim 1 wherein said catalytic promoter agent is a compound of the metal containing Mo +6 , Mn +2 , Cr +3 , W +6 , V +5 , and Mn +7 , and mixtures thereof.
Claim 13
Dependent Claim 13 words
The process according to claim 1 wherein said electroless metal deposition is nickel.
Claim 14
Dependent Claim 25 words
The process according to claim 1 wherein said colloidal catalytic composition is derived by the interreaction of a soluble copper compound with a soluble borohydride.
Claim 15
Dependent Claim 16 words
The process according to claim 1 wherein said colloidal catalytic composition is of a positive colloid.
Claim 16
Dependent Claim 16 words
The process according to claim 1 wherein said colloidal catalytic composition is of a negative colloid.
Claim 17
Dependent Claim 22 words
The process according to claim 1 wherein said principal catalytic agent is a compound of copper and further contains a nickel compound.
Claim 18
Dependent Claim 22 words
The process according to claim 1 wherein said principal catalytic agent is a copper compound and further contains a compound of cobalt.
Claim 19
Dependent Claim 24 words
The process according to claim 1 wherein the concentration of the principal catalytic agent is greater than the concentration of the catalytic promoter agent.
Claim 20
Dependent Claim 23 words
The process according to claim 1 further containing the step of activation whereby the induction time for the actual metal deposition is reduced.
Claim 21
Dependent Claim 31 words
The process according to claim 19 wherein said activation comprises a reduction step and wherein said reduction may be effected via chemical reducing agent or light or heat and combinations thereof.
Claim 22
Dependent Claim 23 words
The process according to claim 1 wherein the concentration of said catalytic promoter agent is from about 0.12 g/l. to about 1.2 g/l.
Claim 23
Dependent Claim 16 words
The process according to claim 1 wherein said colloidal catalytic composition is in an alkaline pH.
Claim 24
Dependent Claim 13 words
The process according to claim 1 further containing the step of water rinsing.
Claim 25
Dependent Claim 13 words
The process according to claim 1 wherein said non-conductor surface is selectively catalyzed.
Claim 26
Dependent Claim 18 words
The process according to claim 1 wherein said colloidal catalytic composition further contains at least one colloid stabilizer.
Claim 27
Dependent Claim 35 words
The process according to claim 1 further containing the step of activation and wherein said activation selectively removes colloid stabilizer present on the non-conductor surface after contacting said non-conductor surface with said colloidal catalytic composition.
Claim 28
Dependent Claim 12 words
The process according to claim 1 further containing the step of drying.
Claim 29
Dependent Claim 19 words
The process according to claim 1 wherein said non-conductor is preconditioned prior to contacting with said colloidal catalytic composition.

References Cited (Backward Citations)

US3310430A Cited
US3657003A Cited
US3900614A Cited
US3993491A Cited
US3958048A Cited
US3993799A Cited
US3993801A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-04-23 1982-10-23 1983-04-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-04-23 1986-10-23 1987-04-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-04-23 1990-10-23 1991-04-24 $7700.00 Window Closed / Lapsed

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