Patent US4298903A successfully refreshed from Google Patents.
Patent US4151311A successfully refreshed from Google Patents.
US4151311A
Expired / Lapsed
US
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Post colloid addition of catalytic promoters to non noble metal principal catalytic compounds in electroless plating catalysts
Assignee: Individual
•
Filing: 1977-09-16
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Granted: 1979-04-24
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Expires: 1997-09-16
Abstract
Abstract A process and composition for catalyzing a substrate prior to electroless metal deposition. The catalyst formulation comprises the colloidal product resulting from the admixture of a principal catalytic agent and a catalytic promoting agent. The principle catalytic agent is selected from the metals of Period 4 of Groups 1B and VIII of the Periodic Table of the Elements while the catalytic promoting agent is selected from the metals of Period 4, 5, 6 and Groups IVB, VB, VIB and VIIB of the Periodic Table of the Elements, and further the catalytic promoter agent is admixed subsequent to the colloid nucleation process.
Inventors
- 👤 Nathan Feldstein
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 10:33
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/16; C23C18/18; C23C18/20; C23C18/28
Claims Analysis
Total Claims: 29
Claim 1
Independent Claim
181 words
A process for the catalytically rendering of a non-conductor surface receptive to electroless metal deposition comprising contacting said surface with a colloidal catalytic composition comprising the admixture of a principal catalytic agent wherein said principal catalytic agent is a compound of a metal selected from the groups of metals consisting of copper, nickel, cobalt, and iron and mixtures thereof and a catalytic promoter agent wherein said catalytic promoter agent is a compound of a metal selected from the group of metals consisting of Mg, Ca, Sr, Sc, Y, La, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Tc and Re and mixtures thereof and further said catalytic promoter is added subsequent to the colloidal nucleation process in which the principal catalytic agent is allowed to react as to yield a colloid, and further wherein the concentrations for the principal catalytic agent and the catalytic promoter agent are so adjusted as to yield a catalytic composition having a greater catalytic activity for electroless metal deposition in comparison to the same catalytic composition in the absence of said catalytic promoter agent.
Claim 2
Dependent Claim
181 words
A process for the catalytically rendering of a non-conductor surface receptive to electroless metal deposition comprising contacting said surface with a colloidal catalytic composition comprising the admixture of a principal catalytic agent wherein said principal catalytic agent is a compound of a metal selected from the groups of metals consisting of copper, nickel, cobalt, and iron and mixtures thereof and a catalytic promoter agent wherein said catalytic promoter agent is a compound of a metal selected from the group of metals consisting of Mg, Ca, Sr, Sc, Y, La, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Tc and Re and mixtures thereof and further said catalytic promoter is added subsequent to the colloidal nucleation process in which the principal catalytic agent is allowed to react as to yield a colloid, and further wherein the concentrations for the principal catalytic agent and the catalytic promoter agent are so adjusted as to yield a catalytic composition having a greater catalytic activity for electroless metal deposition in comparison to the same catalytic composition in the absence of said catalytic promoter agent.
Claim 3
Dependent Claim
29 words
The process according to claim 1 wherein said catalytic promoter agent is selected from at least one member of the group consisting of chromium, vanadium, molybdenum, tungsten and zirconium.
Claim 4
Dependent Claim
14 words
The process according to claim 1 wherein said electroless metal deposition is electroless copper.
Claim 5
Dependent Claim
15 words
The process according to claim 1 wherein said electroless metal deposition yields an image intensification.
Claim 6
Dependent Claim
16 words
The process according to claim 1, wherein said principal catalytic agent is a compound containing copper.
Claim 7
Dependent Claim
22 words
The process according to claim 1 further containing the step of activation and wherein said activation step is devoid of precious metal(s).
Claim 8
Dependent Claim
13 words
The process according to claim 6 further containing the step of electroles deposition.
Claim 9
Dependent Claim
11 words
The process according to claim 1 wherein said non-conductor is ABS.
Claim 10
Dependent Claim
13 words
The process according to claim 1 wherein said electroless metal deposition is copper.
Claim 11
Dependent Claim
32 words
The process according to claim 1 wherein said catalytic promoter agent is a compound of a metal selected from the group of metals consisting of Zr, Hf, V, Cr, Mo W, Mn.
Claim 12
Dependent Claim
40 words
The process according to claim 1 wherein said catalytic promoter agent is a compound of the metal containing Mo +6 , Mn +2 , Cr +3 , W +6 , V +5 , and Mn +7 , and mixtures thereof.
Claim 13
Dependent Claim
13 words
The process according to claim 1 wherein said electroless metal deposition is nickel.
Claim 14
Dependent Claim
25 words
The process according to claim 1 wherein said colloidal catalytic composition is derived by the interreaction of a soluble copper compound with a soluble borohydride.
Claim 15
Dependent Claim
16 words
The process according to claim 1 wherein said colloidal catalytic composition is of a positive colloid.
Claim 16
Dependent Claim
16 words
The process according to claim 1 wherein said colloidal catalytic composition is of a negative colloid.
Claim 17
Dependent Claim
22 words
The process according to claim 1 wherein said principal catalytic agent is a compound of copper and further contains a nickel compound.
Claim 18
Dependent Claim
22 words
The process according to claim 1 wherein said principal catalytic agent is a copper compound and further contains a compound of cobalt.
Claim 19
Dependent Claim
24 words
The process according to claim 1 wherein the concentration of the principal catalytic agent is greater than the concentration of the catalytic promoter agent.
Claim 20
Dependent Claim
23 words
The process according to claim 1 further containing the step of activation whereby the induction time for the actual metal deposition is reduced.
Claim 21
Dependent Claim
31 words
The process according to claim 19 wherein said activation comprises a reduction step and wherein said reduction may be effected via chemical reducing agent or light or heat and combinations thereof.
Claim 22
Dependent Claim
23 words
The process according to claim 1 wherein the concentration of said catalytic promoter agent is from about 0.12 g/l. to about 1.2 g/l.
Claim 23
Dependent Claim
16 words
The process according to claim 1 wherein said colloidal catalytic composition is in an alkaline pH.
Claim 24
Dependent Claim
13 words
The process according to claim 1 further containing the step of water rinsing.
Claim 25
Dependent Claim
13 words
The process according to claim 1 wherein said non-conductor surface is selectively catalyzed.
Claim 26
Dependent Claim
18 words
The process according to claim 1 wherein said colloidal catalytic composition further contains at least one colloid stabilizer.
Claim 27
Dependent Claim
35 words
The process according to claim 1 further containing the step of activation and wherein said activation selectively removes colloid stabilizer present on the non-conductor surface after contacting said non-conductor surface with said colloidal catalytic composition.
Claim 28
Dependent Claim
12 words
The process according to claim 1 further containing the step of drying.
Claim 29
Dependent Claim
19 words
The process according to claim 1 wherein said non-conductor is preconditioned prior to contacting with said colloidal catalytic composition.
References Cited (Backward Citations)
US3310430A
Cited
US3657003A
Cited
US3900614A
Cited
US3993491A
Cited
US3958048A
Cited
US3993799A
Cited
US3993801A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-04-23 | 1982-10-23 | 1983-04-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-04-23 | 1986-10-23 | 1987-04-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-04-23 | 1990-10-23 | 1991-04-24 | $7700.00 | Window Closed / Lapsed |