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US4150106A Expired / Lapsed US ⏱️ 0.0 years remaining

Toothpaste permitting of controlling the tooth brushing time

Assignee: Cooper SA
•
Filing: 1978-04-12
•
Granted: 1979-04-17
•
Expires: 1998-04-12
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Abstract

Abstract This toothpaste contains reagents for controlling the tooth brushing time by the change in color occurring after a predetermined brushing time. It contains essentially a citrate/citric acid buffer having a molarity of 0.07 to 0.35 M and a pH of 4 to 5.5 in the proportion of 10 to 50%, and chlorophenol red in the proportion of 0.02 to 0.1%.

Inventors

  • 👤 Jacques Assal
  • 👤 Bernard Blanc
  • 👤 Bernard Monnerat

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 10:00
CPC Classifications
A; A61; A61Q; A61Q11/00; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/49; A61K2800/00; A61K2800/40; A61K2800/42; A61K2800/45

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 64 words
A toothpaste containing reagents for controlling the tooth brushing time by the change in color occurring after a predetermining brushing time, said reagents comprising essentially a citrate-citric acid buffer having a molarity within the range of 0.07 to 0.35 M with a pH of 4 to 5.5 in the proportion of 10 to 50% and chlorophenol red in the proportion of 0.02 to 0.1%.
Claim 2
Dependent Claim 64 words
A toothpaste containing reagents for controlling the tooth brushing time by the change in color occurring after a predetermining brushing time, said reagents comprising essentially a citrate-citric acid buffer having a molarity within the range of 0.07 to 0.35 M with a pH of 4 to 5.5 in the proportion of 10 to 50% and chlorophenol red in the proportion of 0.02 to 0.1%.
Claim 3
Dependent Claim 99 words
A toothpaste according to claim 1, having the following composition: a mixture, not in excess of 3.5% of synthetic polymers carboxypolymethylenes) and modified celluloses (sodium carragheenate); 8 to 25% silicic acid; 1 to 6% silica; 1.5 to 3% Sodium dodecylhydrogensulphate; 3 to 4 propandiol; 20 to 60% sorbitol; 0.1 to 0.5% p-hydroxybenzoic acid esters; 0.02 to 0.1% chlorophenol red; about 1.5% aromas; 0.01 to 0.04% foodstuff dyes; 10 to 50% of a citrate/citric acid buffer having a ionic strength and a pH value adapted to yield a final pH within the range of 4.0 to 5.5; water, q.s 100%.
Claim 4
Dependent Claim 17 words
Toothpaste according to claim 2, wherein the carboxypolymethylene and carragheenate consist of Carbopol 940 and Satiagum B.
Claim 5
Dependent Claim 21 words
A toothpaste according to claim 2, wherein said esters of p-hydroxybenzoic acid are a mixture of methyl p-hydroxybenzoate and popyl p-hydroxybenzoate.
Claim 6
Dependent Claim 29 words
A toothpaste according to claim 2, wherein said citrate buffer consists of 0.07 M citric acid and 0.07 M sodium citrate set at a pH of 4.2 to 4.6.
Claim 7
Dependent Claim 33 words
Toothpaste according to claim 2, wherein said foodstuff dye is a moderately concentrated corn-poppy red (0.01 to 0.04%) in order not to interfere with the turning of the chlorophenol red to purple red.
Claim 8
Dependent Claim 64 words
Toothpaste according to claim 1, of which the preferred composition is: ______________________________________ Carbopol 940 1.5% Satiagum B 1.5% Silicic acid 10.0% Titanium dioxide 4.0% Sodium laurylsulphate 2.1% 70% Sorbitol 33.0% Methyl p-hydroxybenzoate 0.15% Propyl p-hydroxybenzoate 0.15% Chlorophenol red 0.05% Aromas 1.3% Sodium Saccharin 0.5% Sodium monofluorophosphate 0.75% Bromochlorophene 0.15% Buffer : 0.07 M citric acid/ sodium citrate, pH = 4.5 q.s. 100.00 grams. ______________________________________

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-04-16 1982-10-16 1983-04-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-04-16 1986-10-16 1987-04-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-04-16 1990-10-16 1991-04-17 $7700.00 Window Closed / Lapsed

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