Patent US4150106A successfully refreshed from Google Patents.
US4150106A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Toothpaste permitting of controlling the tooth brushing time
Assignee: Cooper SA
•
Filing: 1978-04-12
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Granted: 1979-04-17
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Expires: 1998-04-12
Abstract
Abstract This toothpaste contains reagents for controlling the tooth brushing time by the change in color occurring after a predetermined brushing time. It contains essentially a citrate/citric acid buffer having a molarity of 0.07 to 0.35 M and a pH of 4 to 5.5 in the proportion of 10 to 50%, and chlorophenol red in the proportion of 0.02 to 0.1%.
Inventors
- 👤 Jacques Assal
- 👤 Bernard Blanc
- 👤 Bernard Monnerat
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 10:00
CPC Classifications
A; A61; A61Q; A61Q11/00; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/49; A61K2800/00; A61K2800/40; A61K2800/42; A61K2800/45
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
64 words
A toothpaste containing reagents for controlling the tooth brushing time by the change in color occurring after a predetermining brushing time, said reagents comprising essentially a citrate-citric acid buffer having a molarity within the range of 0.07 to 0.35 M with a pH of 4 to 5.5 in the proportion of 10 to 50% and chlorophenol red in the proportion of 0.02 to 0.1%.
Claim 2
Dependent Claim
64 words
A toothpaste containing reagents for controlling the tooth brushing time by the change in color occurring after a predetermining brushing time, said reagents comprising essentially a citrate-citric acid buffer having a molarity within the range of 0.07 to 0.35 M with a pH of 4 to 5.5 in the proportion of 10 to 50% and chlorophenol red in the proportion of 0.02 to 0.1%.
Claim 3
Dependent Claim
99 words
A toothpaste according to claim 1, having the following composition: a mixture, not in excess of 3.5% of synthetic polymers carboxypolymethylenes) and modified celluloses (sodium carragheenate); 8 to 25% silicic acid; 1 to 6% silica; 1.5 to 3% Sodium dodecylhydrogensulphate; 3 to 4 propandiol; 20 to 60% sorbitol; 0.1 to 0.5% p-hydroxybenzoic acid esters; 0.02 to 0.1% chlorophenol red; about 1.5% aromas; 0.01 to 0.04% foodstuff dyes; 10 to 50% of a citrate/citric acid buffer having a ionic strength and a pH value adapted to yield a final pH within the range of 4.0 to 5.5; water, q.s 100%.
Claim 4
Dependent Claim
17 words
Toothpaste according to claim 2, wherein the carboxypolymethylene and carragheenate consist of Carbopol 940 and Satiagum B.
Claim 5
Dependent Claim
21 words
A toothpaste according to claim 2, wherein said esters of p-hydroxybenzoic acid are a mixture of methyl p-hydroxybenzoate and popyl p-hydroxybenzoate.
Claim 6
Dependent Claim
29 words
A toothpaste according to claim 2, wherein said citrate buffer consists of 0.07 M citric acid and 0.07 M sodium citrate set at a pH of 4.2 to 4.6.
Claim 7
Dependent Claim
33 words
Toothpaste according to claim 2, wherein said foodstuff dye is a moderately concentrated corn-poppy red (0.01 to 0.04%) in order not to interfere with the turning of the chlorophenol red to purple red.
Claim 8
Dependent Claim
64 words
Toothpaste according to claim 1, of which the preferred composition is: ______________________________________
Carbopol 940 1.5%
Satiagum B 1.5%
Silicic acid 10.0%
Titanium dioxide 4.0%
Sodium laurylsulphate 2.1%
70% Sorbitol 33.0%
Methyl p-hydroxybenzoate
0.15%
Propyl p-hydroxybenzoate
0.15%
Chlorophenol red 0.05%
Aromas 1.3%
Sodium Saccharin 0.5%
Sodium monofluorophosphate
0.75%
Bromochlorophene 0.15%
Buffer : 0.07 M citric acid/
sodium citrate, pH = 4.5
q.s. 100.00 grams.
______________________________________
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-04-16 | 1982-10-16 | 1983-04-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-04-16 | 1986-10-16 | 1987-04-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-04-16 | 1990-10-16 | 1991-04-17 | $7700.00 | Window Closed / Lapsed |