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US4137399A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of preparing functionalized celluloses

Assignee: Dynamit Nobel AG
•
Filing: 1977-09-30
•
Granted: 1979-01-30
•
Expires: 1997-09-30
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Abstract

Abstract Production of cellulose derivatives substituted by groups having functional moieties by reaction of a hydroxyl group(s) of the cellulose with an at least bifunctional reagent. The reagent is reacted with cellulose dissolved in dimethylsulfoxide containing polyhydroxymethylene.

Inventors

  • 👤 Hans L. Hulsmann
  • 👤 Gustav Renckhoff

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 14:05
CPC Classifications
C; C08; C08B; C08B15/00; C08B15/05; C08B1/00; C08B1/003; C08B11/00; C08B11/02; C08B11/04; C08B11/10; C08B11/12

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 78 words
In the production of cellulose substituted by a group having a functional moiety or moieties capable of forming respectively a bond or bonds, wherein cellulose is contacted with an at least bifunctional reagent for reaction of a hydroxy group of the cellulose with the bifunctional reagent to form said substituted cellulose, the improvement which comprises contacting the reagent with cellulose dissolved in dimethylsulfoxide containing polyhydroxymethylene for said reaction of the cellulose and reagent to form said substituted cellulose.
Claim 2
Dependent Claim 78 words
In the production of cellulose substituted by a group having a functional moiety or moieties capable of forming respectively a bond or bonds, wherein cellulose is contacted with an at least bifunctional reagent for reaction of a hydroxy group of the cellulose with the bifunctional reagent to form said substituted cellulose, the improvement which comprises contacting the reagent with cellulose dissolved in dimethylsulfoxide containing polyhydroxymethylene for said reaction of the cellulose and reagent to form said substituted cellulose.
Claim 3
Dependent Claim 14 words
Process of claim 1, wherein the reagent has at least two different functional groups.
Claim 4
Dependent Claim 11 words
Process of claim 1, the reagent being p-chloromethylbenzoic acid methyl ester.
Claim 5
Dependent Claim 9 words
Process of claim 1, the reagent being p-nitrobenzoyl chloride.
Claim 6
Dependent Claim 8 words
Process of claim 1, the reagent being γ-aminopropyltriethoxysilane.
Claim 7
Dependent Claim 8 words
Process of claim 1, the reagent being γ-mercaptopropyltrimethoxysilane.
Claim 8
Dependent Claim 8 words
Process of claim 1, the reagent being γ-glycidyoxypropyltrimethoxysilane.
Claim 9
Dependent Claim 86 words
Process of claim 1, wherein said group is of the formula ##STR3## wherein: B is said functional moiety; n is 1-4; A is a group of the reagent bonded to the oxygen atom of the hydroxy group of the cellulose; A' is a group capable of reaction with cellulose; and R' is an aliphatic group of 2 to 4 aliphatic carbon atoms or of 1 carbon atom where B is a carboxyl moiety, a group containing a benzene, toluene, or xylene moiety, or an organosilane moiety.

References Cited (Backward Citations)

US2730427A Cited
US3023183A Cited
US3971743A Cited
US3936441A Cited
US4024335A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-01-29 1982-07-31 1983-01-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-01-29 1986-07-31 1987-01-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-01-29 1990-07-31 1991-01-30 $7700.00 Window Closed / Lapsed

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