Method for preparing straight chain primary alcohols from 1-bromoalkanes

Claim 2

In a process for preparing straight-chain, primary alcohols having 6-20 carbon atoms, the improvement comprising reacting at a temperature of about 150° to 300° C. straight-chain 1-bromoalkanes having 6 to 20 carbon atoms with alkali salts of alkanoic acids having 4 to 22 carbon atoms in the presence of 1 to 10 mole percent of alkanoic acids having 4 to 22 carbon atoms based on said alkali salts of the alkanoic acids to form esters, saponifying said esters in an alkaline medium to form straight-chain, primary alcohols having 6-20 carbon atoms and separating said straight-chain, primary alcohols.

Claim 3

The process of claim 1, wherein said alkali salts of alkanoic acids have 4 to 10 carbon atoms.

Claim 4

The process of claim 2, wherein said reacting temperature is about 200° to 250° C.

Claim 5

A process for preparing straight-chain, primary alcohols having 6-20 carbon atoms, comprising: (a) hydrobrominating α olefins having 6 to 20 carbon atoms in the presence of UV light or peroxides to form brominated α olefins; (b) fractionally distilling said brominated α olefins; (c) separating straight-chain 1-bromoalkanes having 6 to 20 carbon atoms as sump product; (d) reacting said straight-chain 1-bromoalkanes with alkali salts of alkanoic acids having 4 to 22 carbon atoms in the presence of 1 to 10 mole percent of alkanoic acids having 4 to 22 carbon atoms and at a temperature of about 150° to 300° C. to form esters; (e) saponifying said esters in an alkaline medium to form said straight-chain, primary alcohols having 6-20 carbon atoms; and (f) separating said straight chain, primary alcohols.

Claim 6

A process for preparing straight-chain, primary alcohols having 6-20 carbon atoms, comprising: (a) hydrobrominating α olefins having 6 to 20 carbon atoms in the presence of UV light or peroxides to form brominated α olefins; (b) fractionally distilling said brominated α olefins; (c) separating straight-chain 1-bromoalkanes having 6 to 20 carbon atoms as sump product; (d) reacting said straight-chain 1-bromoalkanes with alkali salts of alkanoic acids having 4 to 22 carbon atoms in the presence of 1 to 10 mole percent of alkanoic acids having 4 to 22 carbon atoms and at a temperature of about 150° to 300° C. to form esters; (e) saponifying said esters in an alkaline medium to form said straight-chain, primary alcohols having 6-20 carbon atoms; and (f) separating said straight chain, primary alcohols.

Claim 7

The process of claim 4, wherein step (d) is carried out at a temperature of about 200° to 250° C.

Claim 8

The process of claim 4, wherein step (d) is carried out for a period of about 10 minutes to 5 hours.

Claim 9

The process of claim 4, wherein step (d) is carried out for a period of about 1 to 2 hours.

Claim 10

The process of claim 4, wherein said 1-bromoalkanes have a bromine content of about 22 to 46 percent and are selected from the group consisting of 1-bromohexane 1-bromoheptane, 1-bromooctane, 1-bromononane, 1-bromodecane, 1-bromoundecane, 1-bromododecane, 1-bromotridecane, 1-bromotetradecane, 1-bromopentadecane, 1-hexadecane, 1-bromoheptadecane, 1-bromooctadecane, 1-bromononadecane, 1-bromoeicosane and mixtures thereof.