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US4110488A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for making schottky barrier diodes

Assignee: RCA Corp
•
Filing: 1976-04-09
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Granted: 1978-08-29
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Expires: 1996-04-09
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Abstract

Abstract A plurality of Schottky barrier devices are produced by a method which uses a relationship between barrier height, surface concentration of impurities, and alloying time valid when a thin layer of oxide is present on a device substrate and includes the steps of preselecting an impurity concentration for the principal surface of a plurality of silicon substrates and using a predetermined alloying time for each substrate to achieve a preselected barrier height.

Inventors

  • 👤 John J. Risko

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 19:21
CPC Classifications
H; H10; H10D; H10D64/00; H10D64/01; H10D64/012; H10D64/0124; H10D64/0121; H10D64/60; H10D64/64

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 91 words
A method for making a Schottky barrier device comprising the steps of: forming a thin layer of a natural oxide of silicon adjacent the principal surface of a substrate of silicon; forming a layer of a Schottky metal adjacent said oxide layer; and heating the Schottky metal layer and the substrate at a selected temperature, the temperature being sufficient to form a metal silicide whereby a metal silicide layer is formed between said substrate and said oxide layer, and thereafter removing said oxide layer whereby said metal silicide layer is exposed.
Claim 2
Independent Claim 91 words
A method for making a Schottky barrier device comprising the steps of: forming a thin layer of a natural oxide of silicon adjacent the principal surface of a substrate of silicon; forming a layer of a Schottky metal adjacent said oxide layer; and heating the Schottky metal layer and the substrate at a selected temperature, the temperature being sufficient to form a metal silicide whereby a metal silicide layer is formed between said substrate and said oxide layer, and thereafter removing said oxide layer whereby said metal silicide layer is exposed.
Claim 3
Dependent Claim 48 words
The method as recited in claim 1 wherein prior to forming the layer of the Schottky metal adjacent the oxide layer a conductivity type imparting impurity concentration for the principal surface of the substrate is selected by ion implanting a known amount of impurities into the principal surface.
Claim 4
Dependent Claim 47 words
The method as recited in claim 1 wherein prior to forming the layer of Schottky metal adjacent the oxide layer a conductivity type imparting impurity concentration for the principal surface of the substrate is selected by diffusing a known amount of the impurities into the principal surface.
Claim 5
Dependent Claim 20 words
The method as recited in claim 3 wherein the impurities are diffused from a doped oxide adjacent the principal surface.
Claim 6
Dependent Claim 13 words
The method as recited in claim 1 wherein the Schottky metal is platinum.
Claim 7
Dependent Claim 287 words
In a method for making a plurality of Schottky barrier diodes comprising the steps of: preselecting a Schottky barrier height, φ b ; selecting a first amount of a Schottky metal; placing the first selected amount of the Schottky metal above a principal surface of a first silicon substrate; alloying the Schottky metal to the first substrate wherein a first Schottky metal silicide layer is formed adjacent the first substrate having a first barrier height; selecting a second amount of a Schottky metal; placing the second selected amount of the Schottky metal above a principal surface of a second silicon substrate having a second barrier height; the improvement comprising the additional steps of: forming conductivity type imparting impurity atoms of a selected free carrier concentration equally on the principal surfaces of the first and second substrates; forming similar thin layers of a natural oxide of silicon adjacent the principal surfaces of the first and second silicon substrates prior to the placement of the Schottky metal above said principal surfaces; selecting and using a first time duration for alloying the Schottky metal to the first substrate; determining the actual barrier height of the first Schottky metal silicide layer; and selecting and using a second time duration for alloying the Schottky metal to the ground substrate determined by an equation t' = kφ b n /N o where t' is the second time duration, N o is the concentration of the impurity atoms at the principal surfaces, n is equal to 4 for platinum as the Schottky metal, and k is a constant determined by the above equation wherein the actual barrier height for the first metal silicon layer is substituted for the preselected barrier height, φ b .
Claim 8
Dependent Claim 287 words
In a method for making a plurality of Schottky barrier diodes comprising the steps of: preselecting a Schottky barrier height, φ b ; selecting a first amount of a Schottky metal; placing the first selected amount of the Schottky metal above a principal surface of a first silicon substrate; alloying the Schottky metal to the first substrate wherein a first Schottky metal silicide layer is formed adjacent the first substrate having a first barrier height; selecting a second amount of a Schottky metal; placing the second selected amount of the Schottky metal above a principal surface of a second silicon substrate having a second barrier height; the improvement comprising the additional steps of: forming conductivity type imparting impurity atoms of a selected free carrier concentration equally on the principal surfaces of the first and second substrates; forming similar thin layers of a natural oxide of silicon adjacent the principal surfaces of the first and second silicon substrates prior to the placement of the Schottky metal above said principal surfaces; selecting and using a first time duration for alloying the Schottky metal to the first substrate; determining the actual barrier height of the first Schottky metal silicide layer; and selecting and using a second time duration for alloying the Schottky metal to the ground substrate determined by an equation t' = kφ b n /N o where t' is the second time duration, N o is the concentration of the impurity atoms at the principal surfaces, n is equal to 4 for platinum as the Schottky metal, and k is a constant determined by the above equation wherein the actual barrier height for the first metal silicon layer is substituted for the preselected barrier height, φ b .
Claim 9
Dependent Claim 11 words
The method of claim 6 wherein the Schottky metal is platinum.
Claim 10
Dependent Claim 31 words
The method of claim 6 wherein the impurity atoms of a selected concentration are formed by disposing a doped oxide of a known impurity concentration adjacent the principal surfaces and heating.
Claim 11
Dependent Claim 29 words
The method of claim 6 wherein the impurity atoms of a selected concentration are formed by ion implanting like ions of a known flux density into the principal surfaces.

References Cited (Backward Citations)

US3290127A Cited
US3496631A Cited
US3579278A Cited
US3849789A Cited
US3841904A Cited
US3900344A Cited
US4056642A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-08-28 1982-02-27 1982-08-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-08-28 1986-02-27 1986-08-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-08-28 1990-02-27 1990-08-29 $7700.00 Window Closed / Lapsed

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