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Liquefaction of solid carbonaceous materials

Assignee: Mobil Oil AS
•
Filing: 1976-12-01
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Granted: 1978-05-16
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Expires: 1996-12-01
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Abstract

Abstract This invention provides an improved process for solubilizing coal and other solid carbonaceous materials which involves heating a slurry of comminuted carbonaceous material and liquefaction solvent in contact with water, carbon monoxide, and a catalytic quantity of alkanol to produce a heavy oil or bitumen composition.

Inventors

  • 👤 Wilton F. Espenscheid

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 17:11
CPC Classifications
C; C10; C10G; C10G1/00; C10G1/04; C10G1/042

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 63 words
In a process for dissolution of solid carbonaceous material the improvement which consists essentially of heating at a temperature between about 400° and 1200° F and a pressure between about 200 and 6000 psi a slurry of comminuted carbonaceous material and a petroleum refinery highly aromatic residuum hydrogen-donor liquefaction solvent in contact with water, a catalytic quantity of primary alkanol, and carbon monoxide.
Claim 2
Dependent Claim 63 words
In a process for dissolution of solid carbonaceous material the improvement which consists essentially of heating at a temperature between about 400° and 1200° F and a pressure between about 200 and 6000 psi a slurry of comminuted carbonaceous material and a petroleum refinery highly aromatic residuum hydrogen-donor liquefaction solvent in contact with water, a catalytic quantity of primary alkanol, and carbon monoxide.
Claim 3
Dependent Claim 40 words
A process in accordance with claim 1 wherein the slurry of comminuted carbonaceous material and liquefaction solvent is pre-heated until the carbonaceous material is substantially solubilized before contacting the said slurry with the water, primary alkanol, and carbon monoxide components.
Claim 4
Dependent Claim 14 words
A process in accordance with claim 1 wherein the solid carbonaceous material is coal.
Claim 5
Dependent Claim 18 words
A process in accordance with claim 1 wherein the solid carbonaceous material is at least partly municipal refuse.
Claim 6
Dependent Claim 18 words
A process in accordance with claim 1 wherein the solid carbonaceous material is at least partly sewage sludge.
Claim 7
Dependent Claim 18 words
A process in accordance with claim 1 wherein the solid carbonaceous material is at least partly cellulosic waste.
Claim 8
Dependent Claim 24 words
A process in accordance with claim 1 wherein the liquefaction solvent has a boiling point in the range between about 450° and 950° F.
Claim 9
Dependent Claim 17 words
A process in accordance with claim 1 wherein the liquefaction solvent is a FCC main column bottoms.
Claim 10
Dependent Claim 17 words
A process in accordance with claim 1 wherein the liquefaction solvent is a FCC clarified slurry oil.
Claim 11
Dependent Claim 16 words
A process in accordance with claim 1 wherein the liquefaction solvent is a TCC syntower bottoms.
Claim 12
Dependent Claim 31 words
A process in accordance with claim 1 wherein the primary alkanol is present in a quantity between about 0.1 and 10 weight percent, based on the weight of solid carbonaceous material.
Claim 13
Dependent Claim 13 words
A process in accordance with claim 1 wherein the primary alkanol is methanol.
Claim 14
Dependent Claim 28 words
A process in accordance with claim 1 wherein the carbon monoxide partial pressure is maintained at a level of at least about 20 percent of the total pressure.

References Cited (Backward Citations)

US3617474A Cited
US3642607A Cited
US3765851A Cited
US3791957A Cited
US3983027A Cited
US4028220A Cited
US4030893A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-15 1981-11-14 1982-05-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-15 1985-11-14 1986-05-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-15 1989-11-14 1990-05-16 $7700.00 Window Closed / Lapsed

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