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US4066828A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the production of water-adsorbing cellulose ethers

Assignee: Hoechst AG
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Filing: 1976-05-06
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Granted: 1978-01-03
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Expires: 1996-05-06
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Abstract

Abstract This invention relates to an improvement in the process for the production of water-adsorbing, but at least partially water-insoluble, cellulose ethers in which cellulose is alkalized in a liquid reaction medium and etherified in a manner such that by etherification only an at least largely water-soluble carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, hydroxyethyl cellulose or methyl hydroxyethyl cellulose is produced, and in which the cellulose is reacted in an alkaline reaction medium before, during, or after the etherification with a cross-linking agent which is polyfunctional towards cellulose and selected from the group consisting of acrylamido methylene chloroacetamide, dichloroacetic acid, phosphorous oxychloride, or a compound in which at least two groups functional towards cellulose are ##STR1## the improvement comprising effecting alkalization, etherification, and cross-linking in a liquid reaction medium other than isopropyl alcohol.

Inventors

  • 👤 Arno Holst
  • 👤 Helmut Lask
  • 👤 Michael Kostrzewa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 06:35
CPC Classifications
C; C08; C08B; C08B15/00; C08B15/10; A; A61; A61L; A61L15/00; A61L15/16; A61L15/22; A61L15/28; C08B15/005

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 144 words
In the process for the production of water-adsorbing, but at least partially water-insoluble, cellulose ethers in which cellulose is alkalized in a liquid reaction medium and etherified in a manner such that by etherification only an at least largely water-soluble carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, hydroxyethyl cellulose or methyl hydroxyethyl cellulose is produced, and in which the cellulose is reacted in an alkaline reaction medium before, during or after the etherification with a cross-linking agent which is polyfunctional towards cellulose and selected from the group consisting of acrylamido methylene chloroacetamide, dichloroacetic acid, phosphorus oxychloride, or a compound in which at least two groups functional towards cellulose are ##STR3## the improvement comprising effecting alkalization, etherification, and cross-linking in a liquid reaction medium selected from the group consisting of the organic solvents, dioxane, methyl ethyl ketone, ethanol, acetone and tertiary butyl alcohol, and the solvent water.
Claim 2
Dependent Claim 144 words
In the process for the production of water-adsorbing, but at least partially water-insoluble, cellulose ethers in which cellulose is alkalized in a liquid reaction medium and etherified in a manner such that by etherification only an at least largely water-soluble carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, hydroxyethyl cellulose or methyl hydroxyethyl cellulose is produced, and in which the cellulose is reacted in an alkaline reaction medium before, during or after the etherification with a cross-linking agent which is polyfunctional towards cellulose and selected from the group consisting of acrylamido methylene chloroacetamide, dichloroacetic acid, phosphorus oxychloride, or a compound in which at least two groups functional towards cellulose are ##STR3## the improvement comprising effecting alkalization, etherification, and cross-linking in a liquid reaction medium selected from the group consisting of the organic solvents, dioxane, methyl ethyl ketone, ethanol, acetone and tertiary butyl alcohol, and the solvent water.
Claim 3
Dependent Claim 19 words
A process according to claim 1 including effecting alkalization, etherification, and cross-linking in a substantially pure aqueous reaction medium.
Claim 4
Dependent Claim 26 words
A process according to claim 1 including cross-linking the cellulose ether to form a cellulose ether which is more than 50 per cent by weight insoluble.

References Cited (Backward Citations)

US1884629A Cited
US2517577A Cited
US2667480A Cited
US3085087A Cited
US3069409A Cited
US3589364A Cited
US3936441A Cited
US3965091A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-01-02 1981-07-04 1982-01-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-01-02 1985-07-04 1986-01-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-01-02 1989-07-04 1990-01-03 $7700.00 Window Closed / Lapsed

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