Patent US4053324A successfully refreshed from Google Patents.
US4053324A
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Production of reduced charge montmorillonite pigment
Assignee: BASF Catalysts LLC
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Filing: 1976-09-22
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Granted: 1977-10-11
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Expires: 1996-09-22
Abstract
Abstract Preparation of so-called "reduced charge" montmorillonite or bentonite pigment from a naturally-occurring crude clay containing dioctahedral montmorillonite by ion-exchanging cations in the clay with hydrogen ions while the clay is in slurry form, filtering, pugging the filter cake with a preselected amount of a neutral or alkaline lithium salt, preferably the oxide, hydroxide or carbonate, and heat treating to collapse the mineral structure.
Inventors
- 👤 Walter L. Haden, Jr.
- 👤 Peter A. H. Isaac
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 21:42
CPC Classifications
C; C09; C09C; C09C1/00; C09C1/40; C09C1/42; B; B41; B41M; B41M5/00; B41M5/124; B41M5/132; B41M5/155; B41M5/1555; C01; C01P; C01P2006/00; C01P2006/60; C01P2006/80; C01P2006/82; Y; Y10; Y10T; Y10T428/00; Y10T428/25; Y10T428/259
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
147 words
A method for producing a coating pigment useful as a sensitizer for record material from clay material, a substantial amount of which is dioctahedral montmorillonite having its ion-exchanged sites occupied by alkali metal or alkaline earth cations, which comprises forming said clay material into an aqueous slurry and incorporating therein a mineral acid the anion of which forms soluble salts with exchangeable cations in the clay, sufficient acid being used to exchange hydrogen ions for exchangeable cations in said clay, separating the clay thus ion-exchanged from the aqueous phase of the slurry by means of filtration or centrifugation, washing the remaining solids, pugging the solids with a preselected amount of a lithium salt to exchange lithium ions for hydrogen ions, without washing the pugged mixture, heating it mildly to collapse the structure of the dioctahedral montmorillonite, and grinding the material after heat treatment to produce pigment-sized particles.
Claim 2
Independent Claim
147 words
A method for producing a coating pigment useful as a sensitizer for record material from clay material, a substantial amount of which is dioctahedral montmorillonite having its ion-exchanged sites occupied by alkali metal or alkaline earth cations, which comprises forming said clay material into an aqueous slurry and incorporating therein a mineral acid the anion of which forms soluble salts with exchangeable cations in the clay, sufficient acid being used to exchange hydrogen ions for exchangeable cations in said clay, separating the clay thus ion-exchanged from the aqueous phase of the slurry by means of filtration or centrifugation, washing the remaining solids, pugging the solids with a preselected amount of a lithium salt to exchange lithium ions for hydrogen ions, without washing the pugged mixture, heating it mildly to collapse the structure of the dioctahedral montmorillonite, and grinding the material after heat treatment to produce pigment-sized particles.
Claim 3
Dependent Claim
28 words
The method of claim 1 wherein the lithium compound is lithium carbonate and sufficient of said compound is added to form a mixture having a pH above 7.
Claim 4
Dependent Claim
12 words
The method of claim 1 wherein said clay is a sodium bentonite.
Claim 5
Independent Claim
140 words
A method for producing a coating pigment useful as a sensitizer for record material from clay material, a substantial amount of which is dioctahedral montmorillonite having its ion-exchanged sites occupied by alkali metal or alkaline earth cations, which comprises forming said clay into an aqueous slurry having a solids content of at least 30% and adding hydrochloric acid therein sufficient to exchange exchangeable cations therein with hydrogen ions, filtering the slurry and recovering and washing the filter cake to remove free acid and soluble salts, adding lithium carbonate to the washed cake in amount to provide from about 60 to 120 meq. lithium ions per 100 grams of clay and pugging the mixture at a solids content of at least about 40% and, without washing solubles therefrom, heating the mixture to collapse the dioctahedral structure, and grinding to pigment-size particles.
Claim 6
Independent Claim
140 words
A method for producing a coating pigment useful as a sensitizer for record material from clay material, a substantial amount of which is dioctahedral montmorillonite having its ion-exchanged sites occupied by alkali metal or alkaline earth cations, which comprises forming said clay into an aqueous slurry having a solids content of at least 30% and adding hydrochloric acid therein sufficient to exchange exchangeable cations therein with hydrogen ions, filtering the slurry and recovering and washing the filter cake to remove free acid and soluble salts, adding lithium carbonate to the washed cake in amount to provide from about 60 to 120 meq. lithium ions per 100 grams of clay and pugging the mixture at a solids content of at least about 40% and, without washing solubles therefrom, heating the mixture to collapse the dioctahedral structure, and grinding to pigment-size particles.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-10-10 | 1981-04-11 | 1981-10-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-10-10 | 1985-04-11 | 1985-10-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-10-10 | 1989-04-11 | 1989-10-11 | $7700.00 | Window Closed / Lapsed |