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US4049448A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing an electrophotographic material in which a pinhole-filling dispersion is employed

Assignee: Fujifilm Holdings Corp
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Filing: 1975-07-08
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Granted: 1977-09-20
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Expires: 1995-07-08
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Abstract

Abstract In a process for producingan electrophotographic light-sensitive material having a porous support such as a paper support and at least one film forming resin layer directly coated on the support, the at least one resin layer is processed with a pinhole-filling dispersion comprising a liquid and a finely dispersed substance such as a pigment, a plastic particle or a pigment coated with a plastic therein, whereby the finely dispersed substance fills and seals pinholes in the film forming resin layer.

Inventors

  • 👤 Satoru Honjo
  • 👤 Masaaki Takimoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 20:54
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/10; G03G5/101

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 206 words
In a process for producing an electrophotographic light-sensitive material comprising coating a paper support with an electroconductive layer and a photoconductive layer on the opposite side of said electroconductive layer, and directly coating on said paper support at least one film-forming resin layer, wherein said film-forming resin layer can be said electroconductive layer, the improvement which comprises bringing at least one film-forming resin layer directly coated on the support into contact with a pinhole-filling dispersion comprising a volatile liquid and a finely dispersed substance selected from the group consisting of a white or black pigment, a plastic particle or a pigment coated with a plastic therein, said liquid easily penetrating into the interior of the paper support through pinholes in said film forming resin layer and carrying said finely dispersed substance into said pinholes, whereby said finely dispersed substance fills and seals said pinholes which permit the penetration of said liquid and which exist in the surface of said film-forming resin layer which is itself capable of substantially completely preventing penetration of said liquid into said paper support and wherein the rate of penetration of said pinhole-filling dispersion is from about 2 × 10 -4 mm 3 to about 60 × 10 -4 mm 3 /second.
Claim 2
Dependent Claim 206 words
In a process for producing an electrophotographic light-sensitive material comprising coating a paper support with an electroconductive layer and a photoconductive layer on the opposite side of said electroconductive layer, and directly coating on said paper support at least one film-forming resin layer, wherein said film-forming resin layer can be said electroconductive layer, the improvement which comprises bringing at least one film-forming resin layer directly coated on the support into contact with a pinhole-filling dispersion comprising a volatile liquid and a finely dispersed substance selected from the group consisting of a white or black pigment, a plastic particle or a pigment coated with a plastic therein, said liquid easily penetrating into the interior of the paper support through pinholes in said film forming resin layer and carrying said finely dispersed substance into said pinholes, whereby said finely dispersed substance fills and seals said pinholes which permit the penetration of said liquid and which exist in the surface of said film-forming resin layer which is itself capable of substantially completely preventing penetration of said liquid into said paper support and wherein the rate of penetration of said pinhole-filling dispersion is from about 2 × 10 -4 mm 3 to about 60 × 10 -4 mm 3 /second.
Claim 3
Dependent Claim 40 words
The method of claim 1 wherein prior to treatment with said pinhole-filling dispersion from 5 to 30 pinholes per cm 2 are present, and after said treatment with the pinhole-filling dispersion less than 5 pinholes per cm 2 are present.
Claim 4
Dependent Claim 34 words
The method of claim 2 where the pinholes have a diameter less than about 10 microns and the finely dispersed substance has a size equal to or less than the size of the pinholes.
Claim 5
Dependent Claim 22 words
The method of claim 3 wherein the size of the finely dispersed substance is from about 0.5 microns to about 5 microns.
Claim 6
Dependent Claim 54 words
The method of claim 1 wherein said film-forming resin is selected from the group consisting of a polyalkyl acrylate, a polymethacrylate, a copolymer of an alkylacrylate, a copolymer of an alkylmethacrylate, a linear polyester, an unsaturated polyester, an alkyd epoxy resin, a polyvinyl alcohol, polyvinylbenzyl trimethylammonium chloride or a copolymer of styrene and butadiene.
Claim 7
Dependent Claim 33 words
The method of claim 3 wherein said liquid carrying said finely dispersed substance therein is selected from the group consisting of one or more volatile petroleum hydrocarbons, esters, ketones, alcohols and halogenated hydrocarbons.
Claim 8
Dependent Claim 22 words
The method of claim 1 wherein said finely dispersed substance comprises from about 1 to 20% by volume of the said liquid.
Claim 9
Dependent Claim 34 words
The method of claim 1 wherein said liquid carrying said finely dispersed substance therein is contacted with said film-forming resin layer for about 2 seconds to about 40 seconds, after which drying is conducted.
Claim 10
Dependent Claim 16 words
The method of claim 8 wherein drying is at about 60° C. to about 120° C.
Claim 11
Dependent Claim 16 words
The method of claim 1 wherein the finely dispersed substance is said white or black pigment.
Claim 12
Dependent Claim 14 words
The method of claim 1 wherein the finely dispersed substance is said plastic particle.
Claim 13
Dependent Claim 17 words
The method of claim 1 wherein the finely dispersed substance is said pigment coated with a plastic.
Claim 14
Dependent Claim 12 words
The method of claim 1 wherein said liquid is an organic liquid.
Claim 15
Dependent Claim 28 words
The method of claim 1 wherein the rate of penetration of said pinhole-filling dispersion is from 4 × 10 -4 to 32 × 10 -4 mm 3 /sec.
Claim 16
Dependent Claim 15 words
In the process of claim 1, said film-forming resin layer is an electroconductive resin layer.
Claim 17
Dependent Claim 22 words
In the process of claim 1, said film-forming resin layer exists on the back side of the support bearing a photoconductive layer.
Claim 18
Dependent Claim 34 words
In the process of claim 1, said plastic is a thermoplastic resin and the resin layer after contacting with the dispersion is dried and passed between heated calender rolls thereby the plastic is fused.
Claim 19
Dependent Claim 24 words
In the process of claim 1, wherein excess pinhole-filling dispersion is removed after being brought into contact with said at least one film-forming layer.
Claim 20
Dependent Claim 201 words
In a process for producing an electrophotographic light-sensitive material having an electroconductive carbon black-containing paper support and at least one film-forming resin layer directly coated on the support comprising coating said support with a photoconductive layer, wherein said photoconductive layer can be said film-forming resin layer, the improvement which comprises bringing at least one film-forming resin layer directly coated on the carbon black-containing support into contact with a pinhole-filling dispersion comprising a volatile liquid and a finely dispersed substance selected from the group consisting of a white or black pigment, a plastic particle or a pigment coated with a plastic therein, said liquid easily penetrating into the interior of the porous paper support through pinholes in said film-forming resin layer and carrying said finely dispersed substance into said pinholes, whereby said finely dispersed substance fills and seals said pinholes which permit the penetration of said liquid and which exist in the surface of said film-forming resin layer which is itself capable of substantially completely preventine penetration of said liquid into said paper support and wherein the rate of penetration of said pinhole-filling dispersion is from about 2 × 10 -4 mm 3 to about 60 × 10 -4 mm 3 /second.
Claim 21
Dependent Claim 201 words
In a process for producing an electrophotographic light-sensitive material having an electroconductive carbon black-containing paper support and at least one film-forming resin layer directly coated on the support comprising coating said support with a photoconductive layer, wherein said photoconductive layer can be said film-forming resin layer, the improvement which comprises bringing at least one film-forming resin layer directly coated on the carbon black-containing support into contact with a pinhole-filling dispersion comprising a volatile liquid and a finely dispersed substance selected from the group consisting of a white or black pigment, a plastic particle or a pigment coated with a plastic therein, said liquid easily penetrating into the interior of the porous paper support through pinholes in said film-forming resin layer and carrying said finely dispersed substance into said pinholes, whereby said finely dispersed substance fills and seals said pinholes which permit the penetration of said liquid and which exist in the surface of said film-forming resin layer which is itself capable of substantially completely preventine penetration of said liquid into said paper support and wherein the rate of penetration of said pinhole-filling dispersion is from about 2 × 10 -4 mm 3 to about 60 × 10 -4 mm 3 /second.
Claim 22
Dependent Claim 18 words
In the process of claim 18, wherein the finely dispersed substance is said pigment coated with a plastic.
Claim 23
Dependent Claim 19 words
In the process of claim 19, wherein the film-forming resin layer is a vinyl methyl ether-maleic anhydride copolymer layer.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-09-19 1981-03-21 1981-09-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-09-19 1985-03-21 1985-09-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-09-19 1989-03-21 1989-09-20 $7700.00 Window Closed / Lapsed

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