Patent US4033929A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4033929A Expired / Lapsed US ⏱️ 0.0 years remaining

Plastic skin envelopes for glass bottles and the like

Assignee: Millennium Petrochemicals Inc
•
Filing: 1974-01-14
•
Granted: 1977-07-05
•
Expires: 1994-01-14
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A method of producing a lightweight, strong, uniform, foamed layer containing tubular film with good opacity which can be heat-shrunk onto an annular substrate such as a glass bottle rapidly and uniformly is accomplished by co-extruding a low density polyethylene and a mixture of an ethylene polymer and a blowing agent under particular conditions and causing the blowing agent to decompose thereby foaming the ethylene polymer.

Inventors

  • 👤 Claude J. Stiles
  • 👤 Daniel Tomo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 22:34
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/065; B29; B29C; B29C44/00; B29C44/20; B29C44/22; B29C61/00; B29C61/06; B29C61/0608; B29C61/0616; B29C61/08; B32B27/32; B65; B65D; B65D23/00; B65D23/08; B65D23/0842; B65D23/0878; B29C48/00; B29C48/03; B29C48/09; B29C48/10; B29K; B29K2023/00; B29K2105/00; B29K2105/04; B29K2995/00; B29K2995/0018; B29K2995/0025; B32B2266/00; B32B2266/02; B32B2266/0214; B32B2266/025; B32B2307/00; B32B2307/40; B32B2307/41; B32B2307/70; B32B2307/718; B32B2323/00; B32B2323/04; B32B2323/046; Y; Y10; Y10S; Y10S264/00; Y10S264/05; Y10S264/71; Y10S428/00; Y10S428/91; Y10S428/913; Y10T; Y10T428/00; Y10T428/13; Y10T428/1328; Y10T428/249921; Y10T428/249953; Y10T428/249987; Y10T428/249988

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 181 words
A method of producing a seamless lightweight, strong, uniform, multi-ply, oriented foamed layer tubular laminate preform with good opacity adapted to be heat-shrunk onto a tubular substrate rapidly and uniformly, which comprises co-extruding through coaxial annular dies a first and second plastic material, said first plastic material comprising a low density polyethylene and said second plastic comprising an intimate mixture of an ethylene polymer and 0.1%-2% of a blowing agent having a decomposition range above the softening point of the ethylene polymer and below the decomposition temperature of the ethylene polymer, drawing down the resultant tubular foamed laminate at a speed of about 10-25 feet/minute; inflating said tubular foamed laminate wherein the blow-up ratio is about 1:1 to 3:1 such that shrinkage in the machine direction upon application of heat to the resulting laminate will be about 70%-90% and shrinkage in the transverse direction will be about 5%-15%; cooling said foamed tubular laminate and cutting said laminate to length to form said tubular preform and wherein the non-foamed ply of said final laminated preform is about 10%-20% of the thickness thereof.
Claim 2
Independent Claim 181 words
A method of producing a seamless lightweight, strong, uniform, multi-ply, oriented foamed layer tubular laminate preform with good opacity adapted to be heat-shrunk onto a tubular substrate rapidly and uniformly, which comprises co-extruding through coaxial annular dies a first and second plastic material, said first plastic material comprising a low density polyethylene and said second plastic comprising an intimate mixture of an ethylene polymer and 0.1%-2% of a blowing agent having a decomposition range above the softening point of the ethylene polymer and below the decomposition temperature of the ethylene polymer, drawing down the resultant tubular foamed laminate at a speed of about 10-25 feet/minute; inflating said tubular foamed laminate wherein the blow-up ratio is about 1:1 to 3:1 such that shrinkage in the machine direction upon application of heat to the resulting laminate will be about 70%-90% and shrinkage in the transverse direction will be about 5%-15%; cooling said foamed tubular laminate and cutting said laminate to length to form said tubular preform and wherein the non-foamed ply of said final laminated preform is about 10%-20% of the thickness thereof.
Claim 3
Dependent Claim 15 words
The method of claim 1 wherein the amount of blowing agent is between about 0.5%-1%.
Claim 4
Dependent Claim 16 words
The method of claim 1 wherein the ethylene polymer is polyethylene or an ethylene-vinyl acetate copolymer.
Claim 5
Dependent Claim 11 words
The method of claim 1 wherein the blowing agent is azodicarbonamide.
Claim 6
Dependent Claim 33 words
The method of claim 1 wherein the shrinkage in the machine direction is about 80% and the shrinkage in the transverse direction is about 10% as a predominant result of the blow-up ratio.
Claim 7
Dependent Claim 56 words
The method of claim 1 wherein the blowing agent is azodicarbonamide, the amount of blowing agent is between about 0.5%-1%, the extrusion temperature is from about 180°-230° C., and the shrinkage in the machine direction is about 80% and the shrinkage in the transverse direction is about 10% as a predominant result of the blow-up ratio.
Claim 8
Dependent Claim 35 words
The method of claim 1 further comprising positioning a container in the annular space within said preform and shrinking said preform to adherently coat the container by heating to a temperature of about 180°-260° C.
Claim 9
Dependent Claim 23 words
The method of claim 7 wherein the temperature is about 200°-220° C. and the heat is applied for a maximum of 30 seconds.
Claim 10
Dependent Claim 12 words
The method of claim 7 wherein the container is constructed of glass.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-07-04 1981-01-03 1981-07-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-07-04 1985-01-03 1985-07-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-07-04 1989-01-03 1989-07-05 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag