US4033929A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Plastic skin envelopes for glass bottles and the like
Assignee: Millennium Petrochemicals Inc
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Filing: 1974-01-14
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Granted: 1977-07-05
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Expires: 1994-01-14
Abstract
Abstract A method of producing a lightweight, strong, uniform, foamed layer containing tubular film with good opacity which can be heat-shrunk onto an annular substrate such as a glass bottle rapidly and uniformly is accomplished by co-extruding a low density polyethylene and a mixture of an ethylene polymer and a blowing agent under particular conditions and causing the blowing agent to decompose thereby foaming the ethylene polymer.
Inventors
- 👤 Claude J. Stiles
- 👤 Daniel Tomo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 17:41
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/065; B29; B29C; B29C44/00; B29C44/20; B29C44/22; B29C61/00; B29C61/06; B29C61/0608; B29C61/0616; B29C61/08; B32B27/32; B65; B65D; B65D23/00; B65D23/08; B65D23/0842; B65D23/0878; B29C48/00; B29C48/03; B29C48/09; B29C48/10; B29K; B29K2023/00; B29K2105/00; B29K2105/04; B29K2995/00; B29K2995/0018; B29K2995/0025; B32B2266/00; B32B2266/02; B32B2266/0214; B32B2266/025; B32B2307/00; B32B2307/40; B32B2307/41; B32B2307/70; B32B2307/718; B32B2323/00; B32B2323/04; B32B2323/046; Y; Y10; Y10S; Y10S264/00; Y10S264/05; Y10S264/71; Y10S428/00; Y10S428/91; Y10S428/913; Y10T; Y10T428/00; Y10T428/13; Y10T428/1328; Y10T428/249921; Y10T428/249953; Y10T428/249987; Y10T428/249988
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
181 words
A method of producing a seamless lightweight, strong, uniform, multi-ply, oriented foamed layer tubular laminate preform with good opacity adapted to be heat-shrunk onto a tubular substrate rapidly and uniformly, which comprises co-extruding through coaxial annular dies a first and second plastic material, said first plastic material comprising a low density polyethylene and said second plastic comprising an intimate mixture of an ethylene polymer and 0.1%-2% of a blowing agent having a decomposition range above the softening point of the ethylene polymer and below the decomposition temperature of the ethylene polymer, drawing down the resultant tubular foamed laminate at a speed of about 10-25 feet/minute; inflating said tubular foamed laminate wherein the blow-up ratio is about 1:1 to 3:1 such that shrinkage in the machine direction upon application of heat to the resulting laminate will be about 70%-90% and shrinkage in the transverse direction will be about 5%-15%; cooling said foamed tubular laminate and cutting said laminate to length to form said tubular preform and wherein the non-foamed ply of said final laminated preform is about 10%-20% of the thickness thereof.
Claim 2
Independent Claim
181 words
A method of producing a seamless lightweight, strong, uniform, multi-ply, oriented foamed layer tubular laminate preform with good opacity adapted to be heat-shrunk onto a tubular substrate rapidly and uniformly, which comprises co-extruding through coaxial annular dies a first and second plastic material, said first plastic material comprising a low density polyethylene and said second plastic comprising an intimate mixture of an ethylene polymer and 0.1%-2% of a blowing agent having a decomposition range above the softening point of the ethylene polymer and below the decomposition temperature of the ethylene polymer, drawing down the resultant tubular foamed laminate at a speed of about 10-25 feet/minute; inflating said tubular foamed laminate wherein the blow-up ratio is about 1:1 to 3:1 such that shrinkage in the machine direction upon application of heat to the resulting laminate will be about 70%-90% and shrinkage in the transverse direction will be about 5%-15%; cooling said foamed tubular laminate and cutting said laminate to length to form said tubular preform and wherein the non-foamed ply of said final laminated preform is about 10%-20% of the thickness thereof.
Claim 3
Dependent Claim
15 words
The method of claim 1 wherein the amount of blowing agent is between about 0.5%-1%.
Claim 4
Dependent Claim
16 words
The method of claim 1 wherein the ethylene polymer is polyethylene or an ethylene-vinyl acetate copolymer.
Claim 5
Dependent Claim
11 words
The method of claim 1 wherein the blowing agent is azodicarbonamide.
Claim 6
Dependent Claim
33 words
The method of claim 1 wherein the shrinkage in the machine direction is about 80% and the shrinkage in the transverse direction is about 10% as a predominant result of the blow-up ratio.
Claim 7
Dependent Claim
56 words
The method of claim 1 wherein the blowing agent is azodicarbonamide, the amount of blowing agent is between about 0.5%-1%, the extrusion temperature is from about 180°-230° C., and the shrinkage in the machine direction is about 80% and the shrinkage in the transverse direction is about 10% as a predominant result of the blow-up ratio.
Claim 8
Dependent Claim
35 words
The method of claim 1 further comprising positioning a container in the annular space within said preform and shrinking said preform to adherently coat the container by heating to a temperature of about 180°-260° C.
Claim 9
Dependent Claim
23 words
The method of claim 7 wherein the temperature is about 200°-220° C. and the heat is applied for a maximum of 30 seconds.
Claim 10
Dependent Claim
12 words
The method of claim 7 wherein the container is constructed of glass.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-07-04 | 1981-01-03 | 1981-07-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-07-04 | 1985-01-03 | 1985-07-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-07-04 | 1989-01-03 | 1989-07-05 | $7700.00 | Window Closed / Lapsed |