Adhesives tackified with phenol-diene-olefin adducts having number average molecular weight between about 600 to 6000

Claim 2

A tacky adhesive composition comprising (1) 5 to 200 parts by weight phenol-diene-olefin resin having a number average molecular weight between about 600 and about 6000, said resin being produced by first reacting about 2 moles of a phenol with about 1 mole of non-conjugated diene, and then reacting one to four moles of olefin with the reaction product, both reactions being carried out in an inert atmosphere, in the presence of a Friedel-Crafts catalyst, and at a temperature in the range of about 20° C. to 180° C., wherein said phenol has at least 2 ortho and/or para positions free for reaction, and wherein said olefin is selected from the group consisting of styrene, α-methylstyrene, chlorostyrene, vinyltoluene, t-butylstyrene, hexene-1, hexene-2, octene-1, 2-ethylhexene-1, indene, cylohexene, methyl vinyl ether, isobutyl vinyl ether, allyl propyl ether, methyl cinnamate, dimethyl fumarate, N-vinylpyridine, N-vinylpyrrolidone, and N-vinylcarbazole, and (2) about 100 parts by weight of a rubbery material selected from the group consisting of natural rubber and cis-polybutadiene.

Claim 3

A tacky adhesive composition comprising (1) 5 to 200 parts by weight phenol-diene-olefin resin having a number average molecular weight between about 600 and about 6000, said resin being produced by first reacting about 2 moles of a phenol with about 1 mole of non-conjugated diene, and then reacting one to four moles of olefin with the reaction product, both reactions being carried out in an inert atmosphere, in the presence of a Friedel-Crafts catalyst, and at a temperature in the range of about 20° C. to 130° C., wherein said phenol has at least 2 ortho and/or para positions free for reaction, wherein said olefin is selected from the group consisting of styrene, α-methylstyrene, chlorostyrene, vinyltoluene, t-butylstyrene, hexene-1, hexene-2, octene-1, 2-ethylhexene-1, indene, cyclohexene, methyl vinyl ether, isobutyl vinyl ether, allyl propyl ether, methyl cinnamate, dimethyl fumarate, N-vinylpyridine, N-vinylpyrrolidone, and N-vinylcarbazole, and wherein at least half of the olefin carbon atoms and carbon atoms having hydroxyl groups of said resin are hydrogenated, and (2) about 100 parts by weight of a polyurethane rubbery material.

Claim 4

A tacky adhesive composition comprising (1) 5 to 200 parts by weight phenol-diene-olefin resin having a number average molecular weight between about 600 and about 6000, said resin being produced by first reacting about 2 moles of a phenol with about 1 mole of non-conjugated diene, and then reacting one to four moles of olefin with the reaction product, both reactions being carried out in an inert atmosphere, in the presence of a Friedel-Crafts catalyst, and at a temperature in the range of about 20° C. to 130° C., wherein said phenol has at least 2 ortho and/or para positions free for reaction, wherein said olefin is selected from the group consisting of styrene, α-methylstyrene, chlorostyrene, vinyltoluene, t-butylstyrene, hexene-1, hexene-2, octene-1, 2-ethylhexene-1, indene, cyclohexene, methyl vinyl ether, isobutyl vinyl ether, allyl propyl ether, methyl cinnamate, dimethyl fumarate, N-vinylpyridine, N-vinylpyrrolidone, and N-vinylcarbazole, and wherein at least half of the olefin carbon atoms and carbon atoms having hydroxyl groups of said resin are hydrogenated, and (2) about 100 parts by weight of a polyurethane rubbery material.

Claim 5

A tacky adhesive composition comprising 5 to 200 parts by weight phenol-diene-olefin resin having a number average molecular weight between about 600 and about 6000, said resin being produced by first reacting about 2 moles of a phenol with about 1 mole of non-conjugated diene, and then reacting one to four moles of olefin with the reaction product, both reactions being carried out in an inert atmosphere, in the presence of a Friedel-Crafts catalyst, and at a temperature in the range of about 20° C. to 130° C., wherein said phenol has at least 2 ortho and/or para positions free for reaction, wherein said olefin is selected from the group consisting of styrene, α-methylstyrene, chlorostyrene, vinyl-toluene, t-butylstyrene, hexene-1, hexene-2, octene-1, 2-ethylhexene-1, indene, cyclohexene, methyl vinyl ether, isobutyl vinyl ether, allyl propyl ether, methyl cinnamate, dimethyl fumarate, N-vinylpyridine, N-vinylpyrrolidone, and N-vinylcarbazole, and wherein said resin is substantially completely hydrogenated, and (2) about 100 parts by weight of a rubbery material selected from the group consisting of natural rubber, cis-polybutadiene rubber, styrene-butadiene rubber, block copolymers of styrene with butadiene or isoprene and ethylene propylene rubbers.

Claim 6

A tacky adhesive composition comprising 5 to 200 parts by weight phenol-diene-olefin resin having a number average molecular weight between about 600 and about 6000, said resin being produced by first reacting about 2 moles of a phenol with about 1 mole of non-conjugated diene, and then reacting one to four moles of olefin with the reaction product, both reactions being carried out in an inert atmosphere, in the presence of a Friedel-Crafts catalyst, and at a temperature in the range of about 20° C. to 130° C., wherein said phenol has at least 2 ortho and/or para positions free for reaction, wherein said olefin is selected from the group consisting of styrene, α-methylstyrene, chlorostyrene, vinyl-toluene, t-butylstyrene, hexene-1, hexene-2, octene-1, 2-ethylhexene-1, indene, cyclohexene, methyl vinyl ether, isobutyl vinyl ether, allyl propyl ether, methyl cinnamate, dimethyl fumarate, N-vinylpyridine, N-vinylpyrrolidone, and N-vinylcarbazole, and wherein said resin is substantially completely hydrogenated, and (2) about 100 parts by weight of a rubbery material selected from the group consisting of natural rubber, cis-polybutadiene rubber, styrene-butadiene rubber, block copolymers of styrene with butadiene or isoprene and ethylene propylene rubbers.

Claim 7

The adhesive composition of claim 1 wherein said phenol is selected from the group consisting of phenol, anisol, cresol, naphthol, butylphenol, t-amylphenol, octylphenol, bisphenol A and bisphenol B.

Claim 8

The tacky adhesive composition of claim 1 wherein said diene is selected from the group consisting of dicyclopentadiene, 4-vinylcyclohexene-1, dipentene, and 1,5-cyclooctadiene.

Claim 9

An article comprising a flat self-supporting strip bearing a thin layer of the tacky adhesive composition of claim 1 on at least one surface thereof.

Claim 10

An article comprising a flexible self-supporting strip bearing a thin layer of the tacky adhesive composition of claim 3 on one major surface thereof.

Claim 11

The tacky adhesive composition of claim 1 wherein said resin is the reaction product of phenol, dicyclopentadiene, and tertiary butyl styrene.

Claim 12

Phenoldiene-olefin resin having a number average molecular weight between about 600 and about 6000, said resin being produced by first reacting about 2 moles of a phenol with about 1 mole of non-conjugated diene, and then reacting one to four moles of olefin with the reaction product, both reactions being carried out in an inert atmosphere, in the presence of a Friedel-Crafts catalyst, and at a temperature in the range of about 20° C. to 130° C., wherein said phenol has at least 2 ortho and/or para positions free for reaction and wherein said olefin is selected from the group consisting of styrene, α-methylstyrene, chlorostyrene, vinyltoluene, t-butylstyrene, hexene-1, hexene-2, octene-1, 2-ethylhexene-1, indene, cyclohexene, methyl vinyl ether, isobutyl vinyl ether, allyl propyl ether, methyl cinnamate dimethyl fumarate, N-vinyl-pyridine, N-vinylpyrrolidone, and N-vinylcarbazole.

Claim 13

Phenoldiene-olefin resin having a number average molecular weight between about 600 and about 6000, said resin being produced by first reacting about 2 moles of a phenol with about 1 mole of non-conjugated diene, and then reacting one to four moles of olefin with the reaction product, both reactions being carried out in an inert atmosphere, in the presence of a Friedel-Crafts catalyst, and at a temperature in the range of about 20° C. to 130° C., wherein said phenol has at least 2 ortho and/or para positions free for reaction and wherein said olefin is selected from the group consisting of styrene, α-methylstyrene, chlorostyrene, vinyltoluene, t-butylstyrene, hexene-1, hexene-2, octene-1, 2-ethylhexene-1, indene, cyclohexene, methyl vinyl ether, isobutyl vinyl ether, allyl propyl ether, methyl cinnamate dimethyl fumarate, N-vinyl-pyridine, N-vinylpyrrolidone, and N-vinylcarbazole.

Claim 14

The resin of claim 9 wherein said phenol is selected from the group consisting of phenol, anisol, cresol, naphthol, butylphenol, octylphenol, t-amylphenol, bisphenol A and bisphenol B.

Claim 15

The resin of claim 9 wherein said diene is selected from the group consisting of dicyclopentadiene, 4-vinylcyclohexene-1, dipentene, and 1,5-cyclooctadiene.

Claim 16

The resin of claim 9 wherein at least half of the olefin carbon atoms and carbon atoms bearing hydroxyl groups are hydrogenated.