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US3976606A Expired / Lapsed US ⏱️ 0.0 years remaining

Adhesives tackified with low molecular weight terpene-phenolic resins

Assignee: 3M Co
•
Filing: 1973-10-23
•
Granted: 1976-08-24
•
Expires: 1993-10-23
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Abstract

Abstract Adhesive compositions having a high degree of adhesive tack are provided by certain rubbery materials which contain terpene-phenolic resins. The terpene phenolic resins are prepared by alkylating phenols with terpene hydrocarbons.

Inventors

  • 👤 Ramsis Gobran

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 15:09
CPC Classifications
C; C08; C08G; C08G61/00; C08G61/02; C09; C09J; C09J109/00; C08L; C08L2666/00; C08L2666/02; C08L2666/14; Y; Y10; Y10S; Y10S525/00; Y10S525/94; Y10T; Y10T442/00; Y10T442/20; Y10T442/2738; Y10T442/2754

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 164 words
A tacky adhesive composition suited for use as the adhesive for pressure-sensitive adhesive tape comprising 1. 5 to 200 parts by weight terpene-phenolic resin having a number average molecular weight between about 400 and about 3500, said resin being produced by reacting, in an inert atmosphere, in the presence of a Friedel-Crafts catalyst and at a temperature in the range of about 20°C - 130°C, 2 to 4 moles of terpene with one mole of a compound containing at least two phenolic groups, each of said groups having at least one ortho or para position free for alkylation by said terpene, wherein said compound having at least two phenolic grops is selected from the group consisting of bisphenol A, bisphenol B, 4,4'-dihydroxydiphenyl ether, and compounds produced by reacting about 2 moles of a phenol with about 1 mole of a diene or triene and; 2. about 100 parts by weight of a rubbery material selected from the group consisting of natural rubber and cis-polybutadiene.
Claim 2
Dependent Claim 164 words
A tacky adhesive composition suited for use as the adhesive for pressure-sensitive adhesive tape comprising 1. 5 to 200 parts by weight terpene-phenolic resin having a number average molecular weight between about 400 and about 3500, said resin being produced by reacting, in an inert atmosphere, in the presence of a Friedel-Crafts catalyst and at a temperature in the range of about 20°C - 130°C, 2 to 4 moles of terpene with one mole of a compound containing at least two phenolic groups, each of said groups having at least one ortho or para position free for alkylation by said terpene, wherein said compound having at least two phenolic grops is selected from the group consisting of bisphenol A, bisphenol B, 4,4'-dihydroxydiphenyl ether, and compounds produced by reacting about 2 moles of a phenol with about 1 mole of a diene or triene and; 2. about 100 parts by weight of a rubbery material selected from the group consisting of natural rubber and cis-polybutadiene.
Claim 3
Dependent Claim 25 words
An article comprising a flexible self-supporting strip bearing a thin layer of the tacky adhesive composition of claim 1 on at least one surface thereof.
Claim 4
Dependent Claim 27 words
The tacky adhesive composition of claim 1 wherein at least half of the olefinic carbon atoms and carbon atom bearing hydroxy groups of said resin are hydrogenated.
Claim 5
Dependent Claim 24 words
An article comprising a flexible self-supporting strip bearing a thin layer of the tacky adhesive composition of claim 3 on one major surface thereof.
Claim 6
Dependent Claim 19 words
The tacky adhesive composition of claim 1 wherein said resin is the reaction product of phenol, dicyclopentadiene, and camphene.
Claim 7
Dependent Claim 15 words
The adhesive composition of claim 5 wherein said reaction product is at least partially hydrogenated.

References Cited (Backward Citations)

US2558812A Cited
US3015638A Cited
US3251808A Cited
US3347935A Cited
US3197326A Cited
US3383362A Cited
US3408253A Cited
US3491167A Cited
US3586738A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-08-24 1980-02-23 1980-08-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-08-24 1984-02-23 1984-08-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-08-24 1988-02-23 1988-08-24 $7700.00 Window Closed / Lapsed

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