Patent US4026931A successfully refreshed from Google Patents.
US4026931A
Expired / Lapsed
US
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Process for dyeing polyurethane plastics
Assignee: Bayer AG
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Filing: 1975-07-25
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Granted: 1977-05-31
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Expires: 1995-07-25
Abstract
Abstract A process for dyeing polyurethane plastics is disclosed in which an azo dyestuff derived from an indole or 5-aminopyrazole coupling component and containing at least one group having an active hydrogen atom, e.g. hydroxyl aor amino, is introduced during the reaction forming the polyurethane whereby the dyestuff is bonded to the polyurethane by a covalent bond resulting from reaction of the active hydrogen on the dyestuff with a polyurethane reaction component, e.g. polyisocyanate. The dyed polyurethanes produced by this process having a very high level of fastness, e.g. fastness to bleeding upon overcoating.
Inventors
- 👤 Manfred Wiesel
- 👤 Richard Sommer
- 👤 Georg Pape
- 👤 Michael Kressner
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 22:53
CPC Classifications
C; C09; C09B; C09B29/00; C09B29/34; C09B29/36; C09B29/3604; C09B29/3647; C09B29/3652; C09B29/3656; C08; C08K; C08K5/00; C08K5/0008; C08K5/0041; C09B29/3608; C09B29/3613
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
209 words
A process for dyeing polyurethane plastic by incorporating a dye in the reaction mixture used to prepare the polyurethane by polyaddition reaction or to one of the components of the polyaddition reaction mixture, before or during polyaddition; said dye being capable of forming covalent bonds with said polyurethane, said dye having the formula ##STR22## in which n' is 1, 2 or 4; R 1 " is cyano, chlorine, bromine or methyl; R 3 " is hydrogen, chlorine, bromine or methyl; R 5 ' is hydrogen; alkyl; cyclohexyl; benzyl; phenethyl; phenyl; tolyl; tolyl substituted by hydroxy, cyano, chlorine, bromine or C 1 -C 4 alkoxy; R 6 ' is hydrogen; C 1 -C 4 alkyl; benzyl; phenethyl; phenyl; tolyl; tolyl substituted by hydroxy, cyano, chlorine, bromine or C 1 -C 4 alkoxy; or R 6 ' together with R 5 ' and the nitrogen atom are pyrrolidinyl, piperdinyl or morpholinyl; R 7 " is methyl, ethyl, phenyl, p-biphenyl, or o-, m- or p-chlorophenyl; R 8 ' is hydrogen; C 1 -C 4 alkyl; or C 1 -C 4 -alkyl substituted by OH, CN, CONH 2 or COOH; R 9 " is hydrogen, chlorine, bromine, methyl, ethyl, methoxy or ethoxy; wherein the OH-groups are attached to the molecule through alkylene radicals.
Claim 2
Dependent Claim
209 words
A process for dyeing polyurethane plastic by incorporating a dye in the reaction mixture used to prepare the polyurethane by polyaddition reaction or to one of the components of the polyaddition reaction mixture, before or during polyaddition; said dye being capable of forming covalent bonds with said polyurethane, said dye having the formula ##STR22## in which n' is 1, 2 or 4; R 1 " is cyano, chlorine, bromine or methyl; R 3 " is hydrogen, chlorine, bromine or methyl; R 5 ' is hydrogen; alkyl; cyclohexyl; benzyl; phenethyl; phenyl; tolyl; tolyl substituted by hydroxy, cyano, chlorine, bromine or C 1 -C 4 alkoxy; R 6 ' is hydrogen; C 1 -C 4 alkyl; benzyl; phenethyl; phenyl; tolyl; tolyl substituted by hydroxy, cyano, chlorine, bromine or C 1 -C 4 alkoxy; or R 6 ' together with R 5 ' and the nitrogen atom are pyrrolidinyl, piperdinyl or morpholinyl; R 7 " is methyl, ethyl, phenyl, p-biphenyl, or o-, m- or p-chlorophenyl; R 8 ' is hydrogen; C 1 -C 4 alkyl; or C 1 -C 4 -alkyl substituted by OH, CN, CONH 2 or COOH; R 9 " is hydrogen, chlorine, bromine, methyl, ethyl, methoxy or ethoxy; wherein the OH-groups are attached to the molecule through alkylene radicals.
Claim 3
Dependent Claim
9 words
Polyurethane plastics dyed by the process of claim 1.
Claim 4
Dependent Claim
12 words
The process of claim 1 wherein a dyed polyurethane foam is produced.
Claim 5
Dependent Claim
183 words
A process for dyeing polyurethane plastic by incorporating a dye in the reaction mixture used to prepare the polyurethane by polyaddition reaction or to one of the components of the polyaddition reaction mixture, before or during polyaddition; said dye being capable of forming covalent bonds with said polyurethane, said dye having the formula ##STR23##in which R 1 " is cyano, chlorine, bromine or methyl; R 3 " is hydrogen, chlorine, bromine or methyl; R 5 ' is hydrogen; alkyl; cyclohexyl; benzyl; phenethyl; phenyl; tolyl; tolyl substituted by hydroxy, cyano, chlorine, bromine or C 1 -C 4 alkoxy; R 6 ' is hydrogen; C 1 -C 4 alkyl; benzyl; phenethyl; phenyl; tolyl; tolyl substituted by hydroxy, cyano, chlorine, bromine or C 1 -C 4 alkoxy; or n' is 1, 2 or 4; R 10 " is hydrogen; C 1 -C 4 alkyl; C 1 -C 4 -alkyl substituted by hydroxy; phenyl; or phenyl substituted by chlorine, methyl or sulphamoyl monosubstituted or disubstituted by C 1 -C 4 -alkyl; R 11 " is methyl; and the OH-groups are attached to the molecule through alkylene radicals.
Claim 6
Dependent Claim
183 words
A process for dyeing polyurethane plastic by incorporating a dye in the reaction mixture used to prepare the polyurethane by polyaddition reaction or to one of the components of the polyaddition reaction mixture, before or during polyaddition; said dye being capable of forming covalent bonds with said polyurethane, said dye having the formula ##STR23##in which R 1 " is cyano, chlorine, bromine or methyl; R 3 " is hydrogen, chlorine, bromine or methyl; R 5 ' is hydrogen; alkyl; cyclohexyl; benzyl; phenethyl; phenyl; tolyl; tolyl substituted by hydroxy, cyano, chlorine, bromine or C 1 -C 4 alkoxy; R 6 ' is hydrogen; C 1 -C 4 alkyl; benzyl; phenethyl; phenyl; tolyl; tolyl substituted by hydroxy, cyano, chlorine, bromine or C 1 -C 4 alkoxy; or n' is 1, 2 or 4; R 10 " is hydrogen; C 1 -C 4 alkyl; C 1 -C 4 -alkyl substituted by hydroxy; phenyl; or phenyl substituted by chlorine, methyl or sulphamoyl monosubstituted or disubstituted by C 1 -C 4 -alkyl; R 11 " is methyl; and the OH-groups are attached to the molecule through alkylene radicals.
Claim 7
Dependent Claim
9 words
Polyurethane plastic dyed by the process of claim 4.
Claim 8
Dependent Claim
12 words
The process of claim 4 in which a polyurethane foam is produced.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-05-30 | 1980-11-29 | 1981-05-31 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-05-30 | 1984-11-29 | 1985-05-31 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-05-30 | 1988-11-29 | 1989-05-31 | $7700.00 | Window Closed / Lapsed |