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US4016013A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing diffusion layers of carbides, nitrides and/or carbonitrides

Assignee: Berna AG Olten
•
Filing: 1975-02-05
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Granted: 1977-04-05
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Expires: 1995-02-05
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Abstract

Abstract A process for producing diffusion layers of carbides, nitrides and/or carbonitrides on metallic or metalloid substrates, using certain triazines and pyrimidines as sources of carbon and nitrogen, is described. Uniform and well-adhering diffusion layers can be produced in short reaction times by means of this process.

Inventors

  • 👤 Diethelm Bitzer
  • 👤 Dieter Lohmann

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 20:35
CPC Classifications
C; C23; C23C; C23C8/00; C23C8/40; C23C8/06; C23C8/60

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 142 words
A process for producing on a metallic or metalloid substrate, which consists at least partially of one or more of the elements selected from the group consisting of iron, boron, silicon and the transition metals of sub-groups 4 to 6 of the periodic table, a diffusion layer of material selected from the group consisting of said metal carbide, nitride and carbonitride which comprises heating said substrate to a temperature of 500° C. to 1800° C., and contacting said substrate with a gaseous or vaporous reactant stream comprising a carrier gas selected from argon and hydrogen and at least one carbon -- and nitrogen -- releasing compound which readily decomposes at substrate temperature, said compound selected from the group consisting of cyanuric chloride, 2,4-dichloro-6-diisopropylamino-s-triazine, 2-chloro-4,6-bis(diethylamino)-s-triazine, 2,4-bis(diethylamino)-6-dimethylamino-s-triazine, 2,4,5,6-tetrachloropyrimidine, 2,4,6-tris(diethylamino)-s-triazine, 2,4-bis(dimethylamino)-6(1-methylhydrazino)-s-triazine, 2,6-bis(dimethylamino)-5-(cyanopyrimidine and 2,4-dichloro-6-(diallylamino)-s-triazine, permitting reaction thereof to form said diffusion layer on said substrate.
Claim 2
Dependent Claim 142 words
A process for producing on a metallic or metalloid substrate, which consists at least partially of one or more of the elements selected from the group consisting of iron, boron, silicon and the transition metals of sub-groups 4 to 6 of the periodic table, a diffusion layer of material selected from the group consisting of said metal carbide, nitride and carbonitride which comprises heating said substrate to a temperature of 500° C. to 1800° C., and contacting said substrate with a gaseous or vaporous reactant stream comprising a carrier gas selected from argon and hydrogen and at least one carbon -- and nitrogen -- releasing compound which readily decomposes at substrate temperature, said compound selected from the group consisting of cyanuric chloride, 2,4-dichloro-6-diisopropylamino-s-triazine, 2-chloro-4,6-bis(diethylamino)-s-triazine, 2,4-bis(diethylamino)-6-dimethylamino-s-triazine, 2,4,5,6-tetrachloropyrimidine, 2,4,6-tris(diethylamino)-s-triazine, 2,4-bis(dimethylamino)-6(1-methylhydrazino)-s-triazine, 2,6-bis(dimethylamino)-5-(cyanopyrimidine and 2,4-dichloro-6-(diallylamino)-s-triazine, permitting reaction thereof to form said diffusion layer on said substrate.
Claim 3
Dependent Claim 20 words
A process according to claim 1 wherein said substrate is heated to a temperature of 800° C. to 1400° C.
Claim 4
Dependent Claim 17 words
A process according to claim 1 wherein the reaction pressure is from 700 to 800 mm Hg.
Claim 5
Dependent Claim 29 words
A process according to claim 1 wherein said carbon- and nitrogen- releasing compound is present in the gaseous reactant stream at a concentration of up to 3% by volume.
Claim 6
Dependent Claim 15 words
A process as claimed in claim 1 using 2,4,6-tris-(diethylamino)-s-triazine as the compound of formula I.
Claim 7
Dependent Claim 15 words
A process as claimed in claim 1 using 2-chloro-4,6-bis-(diethylamino)-s-triazine as the compound of formula I.
Claim 8
Dependent Claim 15 words
A process as claimed in claim 1 using 2,4-bis-(dimethylamino)-6-(1-methylhydrazino)-s-triazine as the compound of formula I.
Claim 9
Dependent Claim 15 words
A process as claimed in claim 1 using 2,4-dichloro-6-(diallylamino)-s-triazine as the compound of formula I.
Claim 10
Dependent Claim 15 words
A process as claimed in claim 1 using 2-dimethylamino-4,6-bis-(diethylamino)-s-triazine as the compound of formula I.

References Cited (Backward Citations)

FR345642A Cited
US1929252A Cited
US2562065A Cited
US3682789A Cited
GB1251054A Cited
US3637320A Cited
GB1307018A Cited
US3771976A Cited
US3783007A Cited
US3901678A Cited
FR2180463A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-04-04 1980-10-04 1981-04-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-04-04 1984-10-04 1985-04-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-04-04 1988-10-04 1989-04-05 $7700.00 Window Closed / Lapsed

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