Patent US3978152A successfully refreshed from Google Patents.
← Back to Patent Explorer
US3978152A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat-resistant resins derived from a bis-imide, an epoxy resin and a polyamine

Assignee: Novartis Corp
•
Filing: 1975-01-31
•
Granted: 1976-08-31
•
Expires: 1995-01-31
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Polymers possessing imide groups are disclosed. These polymers display good impact strength and are obtained by reacting: A. a bis-imide of the formula ##EQU1## in which Y represents a divalent hydrocarbon radical with 2 to 20 carbon atoms which is free from unsaturated bonds other than aromatic bonds, a divalent mono- or bis-heterocyclic radical with 2 to 10 carbon atoms, or a divalent organic radical with 4 to 20 carbon atoms consisting of several of the hydrocarbon radicals defined above connected to one another by --O--, --S--, --CO-- or --SO 2 --, and B. either an adduct (A) obtained by reacting an epoxy resin and a polyamine of the general formula: Z(-- NH.sub.2 ).sub.v (II) in which Z represents an organic radical of valency v and v represents an integer at least equal to 2, or a mixture comprising the adduct (A) and an amine of the formula: X NH.sub.2 ).sub.m (III) in which X represents an organic radical of valency m and m represents an integer at least equal to 1, the proportions of the reagents being such that if n 1 denotes the number of --NH 2 groups of the polyamine of formula (II) and n 2 denotes the number of epoxy groups of the epoxy resin, n 3 denotes the number of carbon-carbon double bonds in the bis-imide of formula (I) and n 4 denotes the total number of --NH 2 groups in component b), the ratio n 1 /n.sub. 2 is greater than 1 and the ratio n 3 /n.sub. 4 is between 1 and 10. The polymers are particularly useful in the preparation of moulded and laminated articles.

Inventors

  • 👤 Max Gruffaz
  • 👤 Gerard Lefebvre

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 15:23
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/12

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 292 words
Process for preparing a polymer possessing imide groups, which comprises reacting at a temperature of at least 50°C.: a. a bis-imide of the formula: ##EQU2## in which Y represents a divalent hydrocarbon radical with 2 to 20 carbon atoms which is free from unsaturated bonds other than aromatic bonds, a divalent mono- or bis-heterocyclic radical with 2 to 10 carbon atoms, or a divalent organic radical with 4 to 20 carbon atoms consisting of several of the hydrocarbon radicals defined above connected to one another by --O--, --S--, --CO-- or --SO 2 --, and b. either an adduct (A) obtained by reacting at a temperature from 50° to 200°C. a resin containing more than one 1,2-epoxy group and a polyamine of the general formula: Z ( -- NH.sub.2 ).sub.v (II) in which Z represents an organic radical of valency v and v represents an integer at least equal to 2, or a mixture comprising the adduct (A) and an amine of the formula: X ( -- NH.sub.2 ).sub.m (III) in which X represents an organic radical of valency m and m represents an integer at least equal to 1, the proportions of the reagents being such that if on the one hand, with regard to the adduct (A) n 1 denotes the number of --NH 2 groups of the polyamine of formula (II) and n 2 denotes the number of epoxy groups of the epoxy resin, and, on the other hand n 3 denotes the number of carbon-carbon double bonds in the bis-imide of formula (I) and n 4 denotes the total number of --NH 2 groups in component (b) the ratio n 1 /n 2 is greater than 1 and the ratio n 3 /n 4 is between 1 and 10.
Claim 2
Dependent Claim 292 words
Process for preparing a polymer possessing imide groups, which comprises reacting at a temperature of at least 50°C.: a. a bis-imide of the formula: ##EQU2## in which Y represents a divalent hydrocarbon radical with 2 to 20 carbon atoms which is free from unsaturated bonds other than aromatic bonds, a divalent mono- or bis-heterocyclic radical with 2 to 10 carbon atoms, or a divalent organic radical with 4 to 20 carbon atoms consisting of several of the hydrocarbon radicals defined above connected to one another by --O--, --S--, --CO-- or --SO 2 --, and b. either an adduct (A) obtained by reacting at a temperature from 50° to 200°C. a resin containing more than one 1,2-epoxy group and a polyamine of the general formula: Z ( -- NH.sub.2 ).sub.v (II) in which Z represents an organic radical of valency v and v represents an integer at least equal to 2, or a mixture comprising the adduct (A) and an amine of the formula: X ( -- NH.sub.2 ).sub.m (III) in which X represents an organic radical of valency m and m represents an integer at least equal to 1, the proportions of the reagents being such that if on the one hand, with regard to the adduct (A) n 1 denotes the number of --NH 2 groups of the polyamine of formula (II) and n 2 denotes the number of epoxy groups of the epoxy resin, and, on the other hand n 3 denotes the number of carbon-carbon double bonds in the bis-imide of formula (I) and n 4 denotes the total number of --NH 2 groups in component (b) the ratio n 1 /n 2 is greater than 1 and the ratio n 3 /n 4 is between 1 and 10.
Claim 3
Dependent Claim 41 words
Process according to claim 1 for preparing a polymer possessing a softening point of 50° to 200°C which comprises heating the bis-imide and component (b) at a temperature of from 50° to 220°C until a liquid or paste-like mass is obtained.
Claim 4
Dependent Claim 36 words
Process according to claim 1 for preparing a polymer possessing a softening point of 50° to 200°C which comprises heating the bis-imide and component (b) at from 50° to 220°C in the presence of a solvent.
Claim 5
Dependent Claim 50 words
Process according to claim 1 for preparing a polymer which is substantially insoluble in conventional solvents and does not undergo significant softening below the temperature at which it begins to degrade which comprises heating a mixture comprising the bis-imide and component (b) at a temperature of from 150° to 350°C.
Claim 6
Dependent Claim 29 words
Process according to claim 1 in which the adduct (A) is derived from an aromatic or cycloaliphatic epoxy resin and from a polyamine containing at least 5 carbon atoms.
Claim 7
Dependent Claim 23 words
Process according to claim 5 in which the epoxy resin is a novolac epoxy resin or an epoxy resin derived from bisphenol A.
Claim 8
Dependent Claim 35 words
Process according to claim 1 in which the bis-imide is used as a reaction mixture from the dehydration of a bis maleamic acid with acetic anhydride and triethylamine in the presence of a nickel catalyst.
Claim 9
Dependent Claim 11 words
Process according to claim 1 in which the bis-imide is N,N'-4,4'-diphenylmethane-bis-maleimide.
Claim 10
Dependent Claim 19 words
A polymer possessing a softening point of 50° to 200°C prepared by a process as defined in claim 2.
Claim 11
Dependent Claim 19 words
A polymer possessing a softening point of 50° to 200°C prepared by a process as defined in claim 3.
Claim 12
Dependent Claim 33 words
A polymer which is substantially insoluble in conventional solvents and does not undergo significant softening below the temperature at which it begins to degrade prepared by a process as defined in claim 4.
Claim 13
Dependent Claim 41 words
Process for preparing a polymer which is substantially insoluble in conventional solvents and does not undergo significant softening below the temperature at which it begins to degrade which comprises heating a polymer as claimed in claim 9 at 150° to 350°C.

References Cited (Backward Citations)

US2909448A Cited
US3637901A Cited
US3763087A Cited
US3875113A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-08-31 1980-03-01 1980-08-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-08-31 1984-03-01 1984-08-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-08-31 1988-03-01 1988-08-31 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag