Age resisters for oxidizable polymers

Claim 2

Compositions of matter conforming to the structural formula ##EQU1## where n is an integer from 1 to 2, R is selected from the group consisting of tertiary alkyl radicals having from 4 to 8 carbon atoms, R' and R" are selected from the group consisting of hydrogen atom and methyl radical and R'" is selected from the group consisting of the radicals --OH and --OCOR"" where R"" is selected from the group consisting of alkyl radicals having from 1 to 4 carbon atoms.

Claim 3

Compositions according to claim 1 wherein R is tertiarybutyl radical.

Claim 4

Compositions according to claim 1 wherein R'" is the --OH radical.

Claim 5

Compositions according to claim 1 where n is the integer 2.

Claim 6

Compositions according to claim 1 and corresponding to the formula therein selected from the group consisting of 2-(3,5-ditertiarybutyl-4-hydroxybenzyl)-1,3-propanediol; 2-(3,5-ditertiarybutyl-4-hydroxybenzyl)-1,3-butanediol; 3-(3,5-ditertiarybutyl-4-hydroxybenzyl)2,4-pentanediol; 2,2-bis(3,5-ditertiarybutyl-4-hydroxybenzyl)-1,3-propanediol; 2,2-bis(3,5-ditertiarybutyl-4-hydroxybenzyl)-1,3-butanediol and 3,3-bis(3,5-ditertiarybutyl-4-hydroxybenzyl)-2,4-pentanediol.

Claim 7

An oxidizable polymer selected from the group consisting of vulcanized and unvulcanized polymers selected from the group consisting of polychloroprene; homopolymers and copolymers of conjugated 1,3-dienes containing up to 50 percent by weight of at least one copolymerizable monomer; butyl rubber, polyethylene, polypropylene, ethylene/propylene copolymers and terpolymers of a nonconjugated diene and containing an antioxidant amount of an antioxidant composition conforming to the following structural formula: ##STR2## where n is an integer from 1 to 2, R is selected from the group consisting of tertiary alkyl radicals having from 4 to 8 carbon atoms, R' and R" are selected from the group consisting of hydrogen atom and methyl radical and R'" is selected from the group consisting of the radicals --Oh and --OCOR"" where R"" is selected from the group consisting of alkyl radicals having from 1 to 4 carbon atoms.

Claim 8

An oxidizable polymer selected from the group consisting of vulcanized and unvulcanized polymers selected from the group consisting of polychloroprene; homopolymers and copolymers of conjugated 1,3-dienes containing up to 50 percent by weight of at least one copolymerizable monomer; butyl rubber, polyethylene, polypropylene, ethylene/propylene copolymers and terpolymers of a nonconjugated diene and containing an antioxidant amount of an antioxidant composition conforming to the following structural formula: ##STR2## where n is an integer from 1 to 2, R is selected from the group consisting of tertiary alkyl radicals having from 4 to 8 carbon atoms, R' and R" are selected from the group consisting of hydrogen atom and methyl radical and R'" is selected from the group consisting of the radicals --Oh and --OCOR"" where R"" is selected from the group consisting of alkyl radicals having from 1 to 4 carbon atoms.

Claim 9

The polymer according to claim 6 wherein the homopolymers of a conjugated 1,3-diene are polyisoprene and polybutadiene, and wherein the copolymers of a conjugated 1,3-diene contain up to 50 percent by weight of the copolymer of at least one copolymerizable monomer selected from the ground consisting of styrene or acrylonitrile.

Claim 10

The polymer according to claim 6 wherein R of the antioxidant is tertiarybutyl radical.

Claim 11

The polymer according to claim 6 wherein R'" of the antioxidant is the --OH radical.

Claim 12

The polymer according to claim 6 wherein the antioxidant amount ranges from 0.001 to 5.0 percent by weight based on the weight of the polymer.

Claim 13

The polymer according to claim 6 wherein the antioxidant amount ranges from 0.05 to 5.0 percent by weight based on the weight of the polymer.

Claim 14

The polymer according to claim 6 wherein the antioxidant amount ranges from 0.5 to 2.0 percent by weight based on the weight of the polymer.

Claim 15

The polymer according to claim 6 wherein the antioxidant composition is selected from the group consisting of 2-(3,5-ditertiarybutyl-4-hydroxybenzyl)-1,3-propanediol; 2-(3,5-ditertiarybutyl-4-hydroxybenzyl)-1,3-butanediol; 3-(3,5-ditertiarybutyl-4-hydroxybenzyl)-2,4-pentanediol; 2,2-bis(3,5-ditertiarybutl-4-hydroxybenzyl)-1,3-propanediol; 2,2-bis(3,5-ditertiarybutyl-4-hydroxybenzyl)-1,3-butanediol and 3,3-ditertiarybutyl-4-hydroxybenzyl)-2,4-pentanediol.