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US3967429A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of grouting using specific mortar composition

Assignee: Tile Council of America Inc
•
Filing: 1974-09-04
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Granted: 1976-07-06
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Expires: 1994-09-04
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Abstract

Abstract Novel aqueous non-hydraulic mortar compositions are disclosed comprising a film-forming, water-dispersible, room temperature cross-linkable polymer and a water-insoluble filler. Setting and grouting of ceramic tile by these compositions are also disclosed.

Inventors

  • 👤 David S. Weiant
  • 👤 Frank E. Bernett
  • 👤 William R. Velivis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 13:17
CPC Classifications
E; E04; E04F; E04F15/00; E04F15/02; E04F15/08; C; C04; C04B; C04B26/00; C04B26/02; C04B26/04; C04B26/06; C08; C08K; C08K3/00; C08K3/40

Claims Analysis

Total Claims: 37
Claim 1
Independent Claim 83 words
A method of setting and grouting tile which comprises employing at room temperature an aqueous non-hydraulic mortar composition having a viscosity of about 120,000 cps comprising about 10% by weight (solids) of a mixture of film-forming, room temperature cross-linkable polymers in the form of an emulsion, suspension, dispersion or partial solution consisting of an acrylic resin having methylol acrylamide and acid cross-linkable groups and about 77% by weight (solids) of a water-insoluble filler consisting of a mixture of silica, glass and alumina trihydrate.
Claim 2
Independent Claim 83 words
A method of setting and grouting tile which comprises employing at room temperature an aqueous non-hydraulic mortar composition having a viscosity of about 120,000 cps comprising about 10% by weight (solids) of a mixture of film-forming, room temperature cross-linkable polymers in the form of an emulsion, suspension, dispersion or partial solution consisting of an acrylic resin having methylol acrylamide and acid cross-linkable groups and about 77% by weight (solids) of a water-insoluble filler consisting of a mixture of silica, glass and alumina trihydrate.
Claim 3
Independent Claim 91 words
A method of setting and grouting tile which comprises employing at room temperature an aqueous non-hydraulic mortar composition having a viscosity of about 16,000 cps comprising about 5% by weight (solids) of a mixture of film-forming, room temperature, cross-linkable polymers in the form of an emulsion, suspension, dispersion or partial solution consisting of an acrylic resin having methylol acrylamide and acid cross-linkable groups and an acrylic polymer having acid cross-linkable groups and about 77% by weight (solids) of a water-insoluble filler consisting of a mixture of silica, glass and alumina trihydrate.
Claim 4
Independent Claim 91 words
A method of setting and grouting tile which comprises employing at room temperature an aqueous non-hydraulic mortar composition having a viscosity of about 16,000 cps comprising about 5% by weight (solids) of a mixture of film-forming, room temperature, cross-linkable polymers in the form of an emulsion, suspension, dispersion or partial solution consisting of an acrylic resin having methylol acrylamide and acid cross-linkable groups and an acrylic polymer having acid cross-linkable groups and about 77% by weight (solids) of a water-insoluble filler consisting of a mixture of silica, glass and alumina trihydrate.
Claim 5
Independent Claim 84 words
A method of setting and grouting tile which comprises employing at room temperature an aqueous non-hydraulic mortar composition comprising about 2.5% by weight (solids) of a mixture of film-forming, room temperature, cross-linkable polymers in the form of an emulsion, suspension, dispersion or partial solution consisting of an acrylic resin having methylol acrylamide and acid cross-linkable groups and an acrylic polymer having acid cross-linkable groups and about 77% by weight (solids) of a water-insoluble filler consisting of a mixture of silica, glass and alumina trihydrate.
Claim 6
Independent Claim 84 words
A method of setting and grouting tile which comprises employing at room temperature an aqueous non-hydraulic mortar composition comprising about 2.5% by weight (solids) of a mixture of film-forming, room temperature, cross-linkable polymers in the form of an emulsion, suspension, dispersion or partial solution consisting of an acrylic resin having methylol acrylamide and acid cross-linkable groups and an acrylic polymer having acid cross-linkable groups and about 77% by weight (solids) of a water-insoluble filler consisting of a mixture of silica, glass and alumina trihydrate.
Claim 7
Independent Claim 80 words
A method of setting and grouting tile which comprises employing at room temperature an aqueous non-hydraulic mortar composition having a viscosity of about 740,000 cps comprising about 7% by weight (solids) of a film-forming, room temperature, cross-linkable polymer in the form of an emulsion, suspension, dispersion or partial solution, said polymer being an acrylic resin having methylol acrylamide and acid cross-linkable groups and about 80% by weight (solids) of a water-insoluble filler consisting of silica, sand, limestone and alumina trihydrate.
Claim 8
Independent Claim 80 words
A method of setting and grouting tile which comprises employing at room temperature an aqueous non-hydraulic mortar composition having a viscosity of about 740,000 cps comprising about 7% by weight (solids) of a film-forming, room temperature, cross-linkable polymer in the form of an emulsion, suspension, dispersion or partial solution, said polymer being an acrylic resin having methylol acrylamide and acid cross-linkable groups and about 80% by weight (solids) of a water-insoluble filler consisting of silica, sand, limestone and alumina trihydrate.
Claim 9
Independent Claim 164 words
A method of setting and grouting tile which comprises employing at room temperature an aqueous non-hydraulic mortar composition having a viscosity in the range of 10,000 to 1,200,000 cps comprising a film-forming, room temperature cross-linkable polymer in the form of an emulsion, suspension, dispersion or partial solution, having reactive substituents on the polymer chain selected from the group consisting of epoxy, hydroxy, methylol, carboxy, ester, α-olefin, isocyanate, methylol acrylamide, amino, N-methylol amide, internal double bond and combinations thereof wherein said reactive substituents are capable of reacting at room temperature to cross-link said polymers, a water-insoluble filler selected from the group consisting of glass, quartz, silica, limestone, barytes, wollastonite, mica, flint powder, kryolite, alumina trihydrate, talc, pyrophyllite, zinc oxide and mixtures thereof, and an acid catalyst cross-linking aid which is ammonium chloride, said polymer comprising from 2% to 16% by weight, and said filler from 50% to 90% by weight, and said cross-linking aid from 0.03% to 2.0% by weight of the total aqueous composition.
Claim 10
Independent Claim 164 words
A method of setting and grouting tile which comprises employing at room temperature an aqueous non-hydraulic mortar composition having a viscosity in the range of 10,000 to 1,200,000 cps comprising a film-forming, room temperature cross-linkable polymer in the form of an emulsion, suspension, dispersion or partial solution, having reactive substituents on the polymer chain selected from the group consisting of epoxy, hydroxy, methylol, carboxy, ester, α-olefin, isocyanate, methylol acrylamide, amino, N-methylol amide, internal double bond and combinations thereof wherein said reactive substituents are capable of reacting at room temperature to cross-link said polymers, a water-insoluble filler selected from the group consisting of glass, quartz, silica, limestone, barytes, wollastonite, mica, flint powder, kryolite, alumina trihydrate, talc, pyrophyllite, zinc oxide and mixtures thereof, and an acid catalyst cross-linking aid which is ammonium chloride, said polymer comprising from 2% to 16% by weight, and said filler from 50% to 90% by weight, and said cross-linking aid from 0.03% to 2.0% by weight of the total aqueous composition.
Claim 11
Dependent Claim 18 words
The method of setting and grouting tile according to claim 5 wherein the reactive substituents include hydroxy groups.
Claim 12
Dependent Claim 18 words
The method of setting and grouting tile according to claim 5 wherein the reactive substituents include methylol groups.
Claim 13
Dependent Claim 18 words
The method of setting and grouting tile according to claim 5 wherein the reactive substituents include carboxy groups.
Claim 14
Dependent Claim 19 words
The method of setting and grouting tile according to claim 5 wherein the reactive substituents include methylol acrylamide groups.
Claim 15
Dependent Claim 18 words
The method of setting and grouting tile according to claim 5 wherein the reactive substituents include amino groups.
Claim 16
Dependent Claim 18 words
The method of setting and grouting tile according to claim 5 wherein the reactive substituents include N-methylol amide.
Claim 17
Independent Claim 173 words
A method of setting and grouting tile which comprises employing at room temperature an aqueous mortar composition having a viscosity in the range of 10,000 to 1,200,000 cps comprising a film-forming, room temperature cross-linkable polymer in the form of an emulsion, suspension, dispersion or partial solution, having reactive substituents on the polymer chain selected from the group consisting of epoxy, hydroxy, methylol, carboxy, ester, α-olefin, isocyanate, methylol acrylamide, amino, N-methylol amide, internal double bond and combinations thereof wherein said reactive substituents are capable of reacting at room temperature to cross-link said polymers, a water-insoluble filler selected from the group consisting of glass, quartz, silica, limestone, barytes, wollastonite, mica, flint powder, kryolite, alumina trihydrate, talc, pyrophyllite, zinc oxide and mixtures thereof, and an acid catalyst cross-linking aid selected from the group consisting of inorganic and organic salts, organic acids, and amine acid-addition salts, said polymer comprising from 2% to 16% by weight, and said filler from 50% to 90% by weight of the total aqueous composition and wherein said composition is a non-hydraulic mortar.
Claim 18
Independent Claim 173 words
A method of setting and grouting tile which comprises employing at room temperature an aqueous mortar composition having a viscosity in the range of 10,000 to 1,200,000 cps comprising a film-forming, room temperature cross-linkable polymer in the form of an emulsion, suspension, dispersion or partial solution, having reactive substituents on the polymer chain selected from the group consisting of epoxy, hydroxy, methylol, carboxy, ester, α-olefin, isocyanate, methylol acrylamide, amino, N-methylol amide, internal double bond and combinations thereof wherein said reactive substituents are capable of reacting at room temperature to cross-link said polymers, a water-insoluble filler selected from the group consisting of glass, quartz, silica, limestone, barytes, wollastonite, mica, flint powder, kryolite, alumina trihydrate, talc, pyrophyllite, zinc oxide and mixtures thereof, and an acid catalyst cross-linking aid selected from the group consisting of inorganic and organic salts, organic acids, and amine acid-addition salts, said polymer comprising from 2% to 16% by weight, and said filler from 50% to 90% by weight of the total aqueous composition and wherein said composition is a non-hydraulic mortar.
Claim 19
Dependent Claim 21 words
A method for setting and grouting tile according to claim 12 wherein said polymer is substantially emulsified in the aqueous composition.
Claim 20
Dependent Claim 11 words
A method according to claim 13 wherein said filler is glass.
Claim 21
Dependent Claim 11 words
A method according to claim 14 wherein said filler is quartz.
Claim 22
Dependent Claim 11 words
A method according to claim 14 wherein said filler is silica.
Claim 23
Dependent Claim 12 words
A method according to claim 14 wherein said filler is alumina trihydrate.
Claim 24
Dependent Claim 18 words
A method according to claim 14 wherein said filler is a mixture of glass, alumina trihydrate and silica.
Claim 25
Dependent Claim 33 words
A method for setting and grouting tile according to claim 12 wherein a water-soluble, water-retentive agent selected from the group consisting of methyl cellulose and hydroxyethyl cellulose is added to the aqueous composition.
Claim 26
Dependent Claim 29 words
The method according to claim 12 wherein said catalyst is an acidic catalyst present in an amount to provide from 0.03% to 2.0% by weight of the total composition.
Claim 27
Dependent Claim 16 words
The method according to claim 12 wherein an activating agent is included in the mortar composition.
Claim 28
Dependent Claim 12 words
The method according to claim 21 wherein said activating agent is formaldehyde.
Claim 29
Dependent Claim 53 words
A new article of construction which is resistant to attack by water and/or chemicals produced according to the method of claim 12, said article comprising tiles bonded to a support, said tiles being arranged in edge-to-edge relationship with open spaces between said tiles, the spaces between said tiles comprising the cured mortar composition.
Claim 30
Dependent Claim 23 words
A new article of construction as claimed in claim 23 wherein said cured mortar composition is additionally located between said tiles and support.
Claim 31
Dependent Claim 19 words
The method for setting and grouting tile according to claim 12 wherein said acid catalyst is an inorganic salt.
Claim 32
Dependent Claim 20 words
The method for setting and grouting tile according to claim 12 wherein said acid catalyst is an amine acid-addition salt.
Claim 33
Dependent Claim 23 words
The method for setting and grouting tile according to claim 12 wherein said acid catalyst is selected from organic acids and organic salts.
Claim 34
Independent Claim 170 words
A method of grouting tile which comprises: assembling on a substrate a plurality of ceramic tiles in edge-to-edge relationship with spaces between the tiles; and filling the spaces between the tiles with an aqueous grouting composition having a viscosity in the range of 10,000 to 1,200,000 cps comprising 1. a film-forming, room temperature cross-linkable polymer in the form of an emulsion, suspension, dispersion or partial solution, having reactive substituents on the polymer chain selected from the group consisting of epoxy, hydroxy, methylol, carboxy, ester, α-olefin, isocyanate, methylol acrylamide, amino, N-methylol amide, internal double bond and combinations thereof wherein said reactive substituents are capable of reacting at room temperature to cross-link said polymer, 2. a water-insoluble filler, and 3. an acid catalyst cross-linking aid selected from the group consisting of inorganic and organic salts, organic acid, and amine-acid addition salts, said polymer comprising from 2% to 16% by weight, and said filler from 50% to 90% by weight of the total aqueous composition and wherein said composition is a non-hydraulic mortar.
Claim 35
Independent Claim 170 words
A method of grouting tile which comprises: assembling on a substrate a plurality of ceramic tiles in edge-to-edge relationship with spaces between the tiles; and filling the spaces between the tiles with an aqueous grouting composition having a viscosity in the range of 10,000 to 1,200,000 cps comprising 1. a film-forming, room temperature cross-linkable polymer in the form of an emulsion, suspension, dispersion or partial solution, having reactive substituents on the polymer chain selected from the group consisting of epoxy, hydroxy, methylol, carboxy, ester, α-olefin, isocyanate, methylol acrylamide, amino, N-methylol amide, internal double bond and combinations thereof wherein said reactive substituents are capable of reacting at room temperature to cross-link said polymer, 2. a water-insoluble filler, and 3. an acid catalyst cross-linking aid selected from the group consisting of inorganic and organic salts, organic acid, and amine-acid addition salts, said polymer comprising from 2% to 16% by weight, and said filler from 50% to 90% by weight of the total aqueous composition and wherein said composition is a non-hydraulic mortar.
Claim 36
Independent Claim 170 words
A method of setting ceramic tile which comprises applying to a substrate and/or the backs of ceramic tiles a mortar composition having a viscosity in the range of 10,000 to 1,200,000 cps comprising 1. a film-forming, room temperature cross-linkable polymer in the form of an emulsion, suspension, dispersion or partial solution, having reactive substituents on the polymer chain selected from the group consisting of epoxy, hydroxy, methylol, carboxy, ester, α-olefin, isocyanate, methylol acrylamide, amino, N-methylol amide, internal double bond and combinations thereof wherein said reactive substituents are capable of reacting at room temperature to cross-link said polymers, 2. a water-insoluble filler, and 3. an acid catalyst cross-linking aid selected from the group consisting of inorganic and organic salts, organic acid, and amine acid-addition salts, said polymer comprising from 2% to 16% by weight, and said filler from 50% to 90% by weight of the total aqueous composition and wherein said composition is a non-hydraulic mortar; and placing a plurality of said ceramic tiles in an edge-to-edge relationship over said substrate.
Claim 37
Independent Claim 170 words
A method of setting ceramic tile which comprises applying to a substrate and/or the backs of ceramic tiles a mortar composition having a viscosity in the range of 10,000 to 1,200,000 cps comprising 1. a film-forming, room temperature cross-linkable polymer in the form of an emulsion, suspension, dispersion or partial solution, having reactive substituents on the polymer chain selected from the group consisting of epoxy, hydroxy, methylol, carboxy, ester, α-olefin, isocyanate, methylol acrylamide, amino, N-methylol amide, internal double bond and combinations thereof wherein said reactive substituents are capable of reacting at room temperature to cross-link said polymers, 2. a water-insoluble filler, and 3. an acid catalyst cross-linking aid selected from the group consisting of inorganic and organic salts, organic acid, and amine acid-addition salts, said polymer comprising from 2% to 16% by weight, and said filler from 50% to 90% by weight of the total aqueous composition and wherein said composition is a non-hydraulic mortar; and placing a plurality of said ceramic tiles in an edge-to-edge relationship over said substrate.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-07-06 1980-01-05 1980-07-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-07-06 1984-01-05 1984-07-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-07-06 1988-01-05 1988-07-06 $7700.00 Window Closed / Lapsed

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