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Catalyzed process for imide-alcohol condensation

Assignee: Monsanto Co
•
Filing: 1974-07-22
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Granted: 1976-06-22
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Expires: 1994-07-22
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Abstract

Abstract A catalyzed process for the preparation of monomeric and/or polymeric compounds such as esters, polyesters, ester-amides, and polyester-polyamides which result from the reaction of an imide and an alcohol in the presence of an amine or Group IVA, IB, IVB, VB, VIB, and VIII organometal compound, imide-alcohol condensation catalyst.

Inventors

  • 👤 James W. Edwards

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 06:11
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/44

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 87 words
A catalyzed imide-alcohol condensation process for the preparation of polymeric compounds of polyester-polyamides comprising: contacting alcohols having one or more hydroxyl groups attached to an aliphatic carbon and acyl lactams, said contacting being in amounts of from about 10 to about 200 mole percent of the alcohol, in the presence of a catalyst selected from at least one of tertiary amines and a Group IVA, IB, IVB, VB, VIB, VII organometal compound selected from the group consisting of metal alkyls, metal phenols, metal amides, alkoxides, and glycoxides.
Claim 2
Dependent Claim 87 words
A catalyzed imide-alcohol condensation process for the preparation of polymeric compounds of polyester-polyamides comprising: contacting alcohols having one or more hydroxyl groups attached to an aliphatic carbon and acyl lactams, said contacting being in amounts of from about 10 to about 200 mole percent of the alcohol, in the presence of a catalyst selected from at least one of tertiary amines and a Group IVA, IB, IVB, VB, VIB, VII organometal compound selected from the group consisting of metal alkyls, metal phenols, metal amides, alkoxides, and glycoxides.
Claim 3
Dependent Claim 17 words
A process according to claim 1 wherein the catalyst is comprised of a Group IVA organometal compound.
Claim 4
Dependent Claim 13 words
A process according to claim 2 wherein the Group IVA metal is tin.
Claim 5
Dependent Claim 22 words
A process according to claim 1 wherein the amine is selected from the group consisting of triethylenediamine, N-ethylethylenimine, tetramethylguanidine, N-ethylmorpholine, and triethylamine.
Claim 6
Dependent Claim 22 words
A process according to claim 1 wherein the catalyzed imide-alcohol condensation occurs at a temperature of from about -20°C to about 230°C.
Claim 7
Dependent Claim 24 words
A process according to claim 1 wherein the acyl lactam is comprised of isophthaloyl bis-caprolactam and the alcohol is comprised of a polymeric polyol.
Claim 8
Dependent Claim 24 words
A process according to claim 1 wherein the acyl lactam is comprised of terephthaloyl bis-caprolactam and the alcohol is comprised of a polymeric polyol.
Claim 9
Dependent Claim 12 words
A process according to claim 6 wherein the catalyst is stannous octoate.
Claim 10
Dependent Claim 11 words
A process according to claim 6 wherein the catalyst is triethylenediamine.
Claim 11
Dependent Claim 13 words
A process according to claim 6 wherein the catalyst is dibutyl tin dilaurate.

References Cited (Backward Citations)

US2682526A Cited
US3394156A Cited
US3308099A Cited
US3366608A Cited
US3636135A Cited
US3660356A Cited
US3862262A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-06-22 1979-12-22 1980-06-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-06-22 1983-12-22 1984-06-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-06-22 1987-12-22 1988-06-22 $7700.00 Window Closed / Lapsed

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