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Lactam-polyol-acyl polyactam terpolymers

Assignee: DSM Rim Nylon VOF
•
Filing: 1973-12-10
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Granted: 1975-01-21
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Expires: 1993-12-10
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Abstract

Abstract Lactam-polyol-acyl polylactam terpolymers having both ester linkages and amide linkages between the monomeric segments of the terpolymer are disclosed. Also disclosed is a process for preparing the above terpolymers comprising reacting together a lactam, polyol and acryl polylactam in the presence of a basis lactam polymerization catalyst to form a lactam-polyol-acyl polylactam terpolymer.

Inventors

  • 👤 Ross Melvin Hendrick
  • 👤 James D Gabbert

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 14:37
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/44; C08G63/00; C08G63/91; C08G69/42

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 22 words
A block terpolymer according to claim 1 wherein the lactam portion of the terpolymer is formed from a lactam of the formula
Claim 2
Dependent Claim 13 words
A block terpolymer according to claim 1 wherein the lactam is epsilon -caprolactam.
Claim 3
Dependent Claim 20 words
A block terpolymer according to claim 1 wherein the polyol portion of the terpolymer is formed from an alkylene glycol.
Claim 4
Dependent Claim 24 words
A block terpolymer according to claim 1 wherein said alkylene glycol is a polyalkylene glycol having a molecular weight of at least about 1,000.
Claim 5
Dependent Claim 14 words
A block terpolymer according to claim 1 wherein said polyalkylene glycol is polyethylene glycol.
Claim 6
Dependent Claim 14 words
A block terpolymer according to claim 1 wherein said polyalkyelen glycol is polypropylene glycol.
Claim 7
Dependent Claim 14 words
A block terpolymer according to claim 1 wherein said polyalkylene glycol is polytetramethylene glycol.
Claim 8
Dependent Claim 19 words
A block terpolymer accOrding to claim 1 wherein the polyol portion of the terpolymer is formed from polybutadiene diol.
Claim 9
Dependent Claim 19 words
A block terpolymer according to claim 1 wherein the polyol portion of the terpolymer is formed from a polyester.
Claim 10
Dependent Claim 13 words
A block terpolymer according to claim 1 wherein said polyester is polycaprolactone diol.
Claim 11
Dependent Claim 22 words
A block terpolymer according to claim 1 wherein the acyl groups of all of said ester and amide linkages are carbonyl groups.
Claim 12
Dependent Claim 17 words
A copolymer according to claim 1 wherein said block terpolymer is of the repeating AB block structure.
Claim 13
Dependent Claim 12 words
A process for preparing lactam-polyol acyl polylactam terpolymers having the general formula:
Claim 14
Dependent Claim 24 words
A process according to claim 14 wherein said polyol and said acyl polylactam are reacted before said lactam is added to the polymerization mixture.
Claim 15
Dependent Claim 26 words
A process according to claim 14 wherein said polyol and said acyl polylactam are reacted before said lactam polymerization catalyst is added to the polymerization mixture.
Claim 16
Dependent Claim 26 words
A process according to claim 14 wherein said polymerization catalyst is an alkali metal or alkaline earth metal lactam or a halogenated alkaline earth metal lactam.
Claim 17
Dependent Claim 14 words
A process according to claim 17 wherein said polymerization catalyst is a bromomagnesium lactam.
Claim 18
Dependent Claim 14 words
A process according to claim 14 wherein said acyl polylactam is an acyl bis-lactam.
Claim 19
Dependent Claim 29 words
A process according to claim 14 wherein the polymerization reaction of the lactam, polyol and acyl polylactam is carried out at a temperature from about 90* to about 190*C.
Claim 20
Dependent Claim 35 words
A process according to claim 14 wherein the polymerizing is carried out at an initial temperature of about 70* to about 100*C and is increased to about 150* to about 180*C during the polymerization reaction.

References Cited (Backward Citations)

US3384681A Cited
US3549724A Cited
US3639502A Cited
US3636135A Cited
US3631135A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-01-20 1978-07-22 1979-01-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-01-20 1982-07-22 1983-01-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-01-20 1986-07-22 1987-01-21 $7700.00 Window Closed / Lapsed

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