Patent US3909482A successfully refreshed from Google Patents.
US3909482A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Production of flame-retardant linear polyesters
Assignee: Henkel Corp
•
Filing: 1974-03-11
•
Granted: 1975-09-30
•
Expires: 1994-03-11
Abstract
Abstract Flame-retardant polyester filaments of excellent whiteness are prepared from dimethyl terephthalate, ethylene glycol and 2,2bis-(4-(2-hydroxyethoxy)-3,5-dibromophenyl) propane by a continuous process as illustrated in the drawing. Conducting the polymerization within a holdup time of 2.5 hours at temperatures from about 273* to about 290* C. is shown to provide flameretardant filaments having excellent whiteness. Addition of 7naphtha-triazinyl-3-phenylcoumarin and a blue toner further improve the whiteness value and the inclusion of antimony oxide provides even greater flame retardance.
Inventors
- 👤 Gerald Costa Najour
- 👤 Peter Ray Witt
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 12:14
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/68; C08G63/682; C08G63/6824; C08G63/6826
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
167 words
IN THE PRODUCTION OF POLYETHYLENE TEREPHTHALATE FILAMENTS BY A CONTINUOUS PROCESS OF FEEDING DIMETHYL TEREPHTHALATE AND ETHYLENE GLYCOL COMPONENTS WITH CATALYST TO ESTER INERCHARGE MEANS AND REACTING THE COMPONENTS TO FORM DI-B-HYDROXVETHYL TEREPHTHALATE MONOMER, FEEDING THE MONOMER TO A PREPOLYMERIZING AND POLYMERIZING THE MONOMER TO FORM LOW MOLECULAR WEIGHT PREPOLYMER, FEEDING THE PREPOLYMER TO A FINISH POLYMERIZERE AND COMPLETING THE POLYMERIZATION TO FORM FIBER-FORMING POLYMER, AND FEEDING THE POLYMER TO A SPINNING MACHINE AND MELTSPINNING THE POLYMER INTO FILAMENTS, THE IMPROVEMENT FOR PRODUCING FLAME-RETARDANT FILAMENTS OF EXCELLENT WHITENESS, WHEREIN THE IMPROVEMENT COMPRISES CONTINUOUSLY ADDING TO SAID DI-B-HYDROXYETHYL TEREPHTHALATE MONOMER A MOLTEN STREAM OF 2,I-BIS-(4-NI-HYDROXYETHOXY)-3,5-DIBROMOPHENYL) PROPANE IN AN AMOUNT WHICH PROVIDES FROM ABOUT 4 TO ABOUT 5 MOLE PERCENT BASED ON GLYCOL TEREPHTHALATE STRUCTUAL UNITS PERCENT IN THE COPOLYESTER PRODUCED, AND UP TO 400 PARTS PER MILLION OF AN OPTICAL BRIGHTENER, CONDUCTING THE POLYMERIZATION WITHIN A HOLDUP TIME OF 2.5 HOURS TEMPERATURES FROM ABOUT 273* TO ABOUT 290*C. TO FORM FIBER-FORMING COPOLYESTER, AND MELT-SPINNING THE COPOLYESTER INTO FILAMENTS.
Claim 2
Dependent Claim
167 words
IN THE PRODUCTION OF POLYETHYLENE TEREPHTHALATE FILAMENTS BY A CONTINUOUS PROCESS OF FEEDING DIMETHYL TEREPHTHALATE AND ETHYLENE GLYCOL COMPONENTS WITH CATALYST TO ESTER INERCHARGE MEANS AND REACTING THE COMPONENTS TO FORM DI-B-HYDROXVETHYL TEREPHTHALATE MONOMER, FEEDING THE MONOMER TO A PREPOLYMERIZING AND POLYMERIZING THE MONOMER TO FORM LOW MOLECULAR WEIGHT PREPOLYMER, FEEDING THE PREPOLYMER TO A FINISH POLYMERIZERE AND COMPLETING THE POLYMERIZATION TO FORM FIBER-FORMING POLYMER, AND FEEDING THE POLYMER TO A SPINNING MACHINE AND MELTSPINNING THE POLYMER INTO FILAMENTS, THE IMPROVEMENT FOR PRODUCING FLAME-RETARDANT FILAMENTS OF EXCELLENT WHITENESS, WHEREIN THE IMPROVEMENT COMPRISES CONTINUOUSLY ADDING TO SAID DI-B-HYDROXYETHYL TEREPHTHALATE MONOMER A MOLTEN STREAM OF 2,I-BIS-(4-NI-HYDROXYETHOXY)-3,5-DIBROMOPHENYL) PROPANE IN AN AMOUNT WHICH PROVIDES FROM ABOUT 4 TO ABOUT 5 MOLE PERCENT BASED ON GLYCOL TEREPHTHALATE STRUCTUAL UNITS PERCENT IN THE COPOLYESTER PRODUCED, AND UP TO 400 PARTS PER MILLION OF AN OPTICAL BRIGHTENER, CONDUCTING THE POLYMERIZATION WITHIN A HOLDUP TIME OF 2.5 HOURS TEMPERATURES FROM ABOUT 273* TO ABOUT 290*C. TO FORM FIBER-FORMING COPOLYESTER, AND MELT-SPINNING THE COPOLYESTER INTO FILAMENTS.
Claim 3
Dependent Claim
22 words
The process of claim 1 wherein Shepherd Blue No. 3 in an amount of up to 100 parts per million is employed.
Claim 4
Dependent Claim
11 words
The process of claim 2 wherein the optical brightener is 7-naphthatriazinyl-3-phenylcoumarin.
Claim 5
Dependent Claim
30 words
The process of claim 3 wherein the 125-200 parts per million 7-naphthatriazinyl-3-phenylcoumarin and 25-75 parts per million of the blue toner Shepherd Blue No. 3 are added to the monomer.
Claim 6
Dependent Claim
22 words
The process of claim 3 wherein the optical brightener and blue toner are added to the monomer as an ethylene glycol slurry.
Claim 7
Dependent Claim
16 words
The process of claim 3 wherein thE 2,2-bis-(4-(2-hydroxyethoxy)-3,5-dibromophenyl) propane has an APHA color less than 35.
Claim 8
Dependent Claim
28 words
The process of claim 1 wherein 1 to 2 percent by weight of antimony oxide is added to the copolyester to impart increased flame retardancy to the filaments.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1978-09-29 | 1979-03-31 | 1979-09-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1982-09-29 | 1983-03-31 | 1983-09-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1986-09-29 | 1987-03-31 | 1987-09-30 | $7700.00 | Window Closed / Lapsed |