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US3909482A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of flame-retardant linear polyesters

Assignee: Henkel Corp
•
Filing: 1974-03-11
•
Granted: 1975-09-30
•
Expires: 1994-03-11
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Abstract

Abstract Flame-retardant polyester filaments of excellent whiteness are prepared from dimethyl terephthalate, ethylene glycol and 2,2bis-(4-(2-hydroxyethoxy)-3,5-dibromophenyl) propane by a continuous process as illustrated in the drawing. Conducting the polymerization within a holdup time of 2.5 hours at temperatures from about 273* to about 290* C. is shown to provide flameretardant filaments having excellent whiteness. Addition of 7naphtha-triazinyl-3-phenylcoumarin and a blue toner further improve the whiteness value and the inclusion of antimony oxide provides even greater flame retardance.

Inventors

  • 👤 Gerald Costa Najour
  • 👤 Peter Ray Witt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 12:13
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/68; C08G63/682; C08G63/6824; C08G63/6826

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 167 words
IN THE PRODUCTION OF POLYETHYLENE TEREPHTHALATE FILAMENTS BY A CONTINUOUS PROCESS OF FEEDING DIMETHYL TEREPHTHALATE AND ETHYLENE GLYCOL COMPONENTS WITH CATALYST TO ESTER INERCHARGE MEANS AND REACTING THE COMPONENTS TO FORM DI-B-HYDROXVETHYL TEREPHTHALATE MONOMER, FEEDING THE MONOMER TO A PREPOLYMERIZING AND POLYMERIZING THE MONOMER TO FORM LOW MOLECULAR WEIGHT PREPOLYMER, FEEDING THE PREPOLYMER TO A FINISH POLYMERIZERE AND COMPLETING THE POLYMERIZATION TO FORM FIBER-FORMING POLYMER, AND FEEDING THE POLYMER TO A SPINNING MACHINE AND MELTSPINNING THE POLYMER INTO FILAMENTS, THE IMPROVEMENT FOR PRODUCING FLAME-RETARDANT FILAMENTS OF EXCELLENT WHITENESS, WHEREIN THE IMPROVEMENT COMPRISES CONTINUOUSLY ADDING TO SAID DI-B-HYDROXYETHYL TEREPHTHALATE MONOMER A MOLTEN STREAM OF 2,I-BIS-(4-NI-HYDROXYETHOXY)-3,5-DIBROMOPHENYL) PROPANE IN AN AMOUNT WHICH PROVIDES FROM ABOUT 4 TO ABOUT 5 MOLE PERCENT BASED ON GLYCOL TEREPHTHALATE STRUCTUAL UNITS PERCENT IN THE COPOLYESTER PRODUCED, AND UP TO 400 PARTS PER MILLION OF AN OPTICAL BRIGHTENER, CONDUCTING THE POLYMERIZATION WITHIN A HOLDUP TIME OF 2.5 HOURS TEMPERATURES FROM ABOUT 273* TO ABOUT 290*C. TO FORM FIBER-FORMING COPOLYESTER, AND MELT-SPINNING THE COPOLYESTER INTO FILAMENTS.
Claim 2
Dependent Claim 167 words
IN THE PRODUCTION OF POLYETHYLENE TEREPHTHALATE FILAMENTS BY A CONTINUOUS PROCESS OF FEEDING DIMETHYL TEREPHTHALATE AND ETHYLENE GLYCOL COMPONENTS WITH CATALYST TO ESTER INERCHARGE MEANS AND REACTING THE COMPONENTS TO FORM DI-B-HYDROXVETHYL TEREPHTHALATE MONOMER, FEEDING THE MONOMER TO A PREPOLYMERIZING AND POLYMERIZING THE MONOMER TO FORM LOW MOLECULAR WEIGHT PREPOLYMER, FEEDING THE PREPOLYMER TO A FINISH POLYMERIZERE AND COMPLETING THE POLYMERIZATION TO FORM FIBER-FORMING POLYMER, AND FEEDING THE POLYMER TO A SPINNING MACHINE AND MELTSPINNING THE POLYMER INTO FILAMENTS, THE IMPROVEMENT FOR PRODUCING FLAME-RETARDANT FILAMENTS OF EXCELLENT WHITENESS, WHEREIN THE IMPROVEMENT COMPRISES CONTINUOUSLY ADDING TO SAID DI-B-HYDROXYETHYL TEREPHTHALATE MONOMER A MOLTEN STREAM OF 2,I-BIS-(4-NI-HYDROXYETHOXY)-3,5-DIBROMOPHENYL) PROPANE IN AN AMOUNT WHICH PROVIDES FROM ABOUT 4 TO ABOUT 5 MOLE PERCENT BASED ON GLYCOL TEREPHTHALATE STRUCTUAL UNITS PERCENT IN THE COPOLYESTER PRODUCED, AND UP TO 400 PARTS PER MILLION OF AN OPTICAL BRIGHTENER, CONDUCTING THE POLYMERIZATION WITHIN A HOLDUP TIME OF 2.5 HOURS TEMPERATURES FROM ABOUT 273* TO ABOUT 290*C. TO FORM FIBER-FORMING COPOLYESTER, AND MELT-SPINNING THE COPOLYESTER INTO FILAMENTS.
Claim 3
Dependent Claim 22 words
The process of claim 1 wherein Shepherd Blue No. 3 in an amount of up to 100 parts per million is employed.
Claim 4
Dependent Claim 11 words
The process of claim 2 wherein the optical brightener is 7-naphthatriazinyl-3-phenylcoumarin.
Claim 5
Dependent Claim 30 words
The process of claim 3 wherein the 125-200 parts per million 7-naphthatriazinyl-3-phenylcoumarin and 25-75 parts per million of the blue toner Shepherd Blue No. 3 are added to the monomer.
Claim 6
Dependent Claim 22 words
The process of claim 3 wherein the optical brightener and blue toner are added to the monomer as an ethylene glycol slurry.
Claim 7
Dependent Claim 16 words
The process of claim 3 wherein thE 2,2-bis-(4-(2-hydroxyethoxy)-3,5-dibromophenyl) propane has an APHA color less than 35.
Claim 8
Dependent Claim 28 words
The process of claim 1 wherein 1 to 2 percent by weight of antimony oxide is added to the copolyester to impart increased flame retardancy to the filaments.

References Cited (Backward Citations)

US2902518A Cited
US3400174A Cited
US3651017A Cited
US3712904A Cited
US3749600A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-29 1979-03-31 1979-09-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-29 1983-03-31 1983-09-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-29 1987-03-31 1987-09-30 $7700.00 Window Closed / Lapsed

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