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US3899355A Expired / Lapsed US ⏱️ 0.0 years remaining

Battery assembly

Assignee: Polaroid Corp
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Filing: 1974-02-14
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Granted: 1975-08-12
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Expires: 1994-02-14
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Abstract

Abstract A relatively thin, flat or planar battery is disclosed which includes one or more cells in series relationship each comprising a planar anode in superposed relationship with a planar cathode and a separator disposed intermediate and extending substantially coextensive the facing surfaces of the anode and cathode possessing marginal portions and an aqueous electrolyte permeable central portion. Each cell includes an aqueous electrolyte disposed in the central portion of the separator and in contact with the facing surfaces of both the anode and the cathode and an electrically nonconducting, water-vapor impervious, heatactivated thermosetting adhesive which is the product of the reaction between a thermally dissociated phenol-, alkyl or aryl thiol-, or 1,3-dicarbonyl compound- polyisocyanate or polyisothiocyanate adduct and a polymer containing active hydrogen atoms extending intermediate and providing adhesive contact between the marginal portions of the separator and next adjacent facing surfaces.

Inventors

  • 👤 Charles K Chiklis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 21:46
CPC Classifications
H; H01; H01M; H01M10/00; H01M10/04; H01M10/0413; H01M10/0468; H01M6/00; H01M6/42; H01M6/46; Y; Y02; Y02E; Y02E60/00; Y02E60/10; Y02P; Y02P70/00; Y02P70/50

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 180 words
A PLANAR BATTEY WHICH COMPRISES, IN COMBINADTION AND IN SUPERPOSED RELATIONSHIP, ELECTRICAL ENERGY GENERATING COMPONENTS INCLUDING: A. A PLANAR ANODE, B. A PLANAR CATHODE SUPERPOSED SUBSTANTIALLY XOEXTENSIVE THE ANODE, C. A PLANAR SEPARATOR POSITIONED INTERMEDIATE AND EXTENDING SUBSTANTIALLY COEXTENSIVE THE FACING SURFACES OF THE ANODE AND THE CATHODE INCLUDING MARGINAL PORTIONS AND AN AQUEOUS ELECTROLYTE PERMEABLE CENTRAL POSITION, D. AN AQUEOUS ELECTROLYTE DISPOSED IN THE CENTRAL PORTION OF THE SEPARATOR AND IN CONTACT WITH THE FACING SURFACES OF THE ANODE AND THE CATHODE, AND E. AN ELECTRICALLY NONCONDUCTING, WATER VAPOR IMPERVIOUS HEAT-ACTIVATED THERMOSETTING ADHESIVE EXTENDING COEXTENSIVE THE MARGINAL SURFACES OF THE SEPARATOR AND SECURING THE SEPARATOR TO THE CONTIGUOUS FACING SURFACES OF THE ANODE AND THE CATHODE. SAID ADHESIVE BEING THE PRODUCT OF THE REACTION BETWEEN A POLYMER CONTAINING ACTIVE HYDROGEN ATOMS AND A THEMALLY DISSOCIATED ADDUCT OF A COMPOUND CONTAINING AT LEAST TWO -N=C"X GROUPS WHEREIN X IS SELCTED FROM THE GROUP CONSISTING OF OXYGEN AND SULFUR AND THE ADDUCT IS BASED ON A COMPOUND SELECTED FROM THE GROUP CONSISTING OF PHENOLS, ALKYL AND ARYL THIOLS AND 1,3-DICARBONYL COMPOUNDS.
Claim 2
Dependent Claim 180 words
A PLANAR BATTEY WHICH COMPRISES, IN COMBINADTION AND IN SUPERPOSED RELATIONSHIP, ELECTRICAL ENERGY GENERATING COMPONENTS INCLUDING: A. A PLANAR ANODE, B. A PLANAR CATHODE SUPERPOSED SUBSTANTIALLY XOEXTENSIVE THE ANODE, C. A PLANAR SEPARATOR POSITIONED INTERMEDIATE AND EXTENDING SUBSTANTIALLY COEXTENSIVE THE FACING SURFACES OF THE ANODE AND THE CATHODE INCLUDING MARGINAL PORTIONS AND AN AQUEOUS ELECTROLYTE PERMEABLE CENTRAL POSITION, D. AN AQUEOUS ELECTROLYTE DISPOSED IN THE CENTRAL PORTION OF THE SEPARATOR AND IN CONTACT WITH THE FACING SURFACES OF THE ANODE AND THE CATHODE, AND E. AN ELECTRICALLY NONCONDUCTING, WATER VAPOR IMPERVIOUS HEAT-ACTIVATED THERMOSETTING ADHESIVE EXTENDING COEXTENSIVE THE MARGINAL SURFACES OF THE SEPARATOR AND SECURING THE SEPARATOR TO THE CONTIGUOUS FACING SURFACES OF THE ANODE AND THE CATHODE. SAID ADHESIVE BEING THE PRODUCT OF THE REACTION BETWEEN A POLYMER CONTAINING ACTIVE HYDROGEN ATOMS AND A THEMALLY DISSOCIATED ADDUCT OF A COMPOUND CONTAINING AT LEAST TWO -N=C"X GROUPS WHEREIN X IS SELCTED FROM THE GROUP CONSISTING OF OXYGEN AND SULFUR AND THE ADDUCT IS BASED ON A COMPOUND SELECTED FROM THE GROUP CONSISTING OF PHENOLS, ALKYL AND ARYL THIOLS AND 1,3-DICARBONYL COMPOUNDS.
Claim 3
Dependent Claim 13 words
A planar battery as defined in claim 1 wherein the anode comprises zinc.
Claim 4
Dependent Claim 31 words
A planar battery as defined in claim 2 wherein the zinc is secured to the surface of an electrically conductive, gas permeable and water-vapor impermeable polymeric sheet positioned distal the separator.
Claim 5
Dependent Claim 26 words
A planar battery as defined in claim 3 wherein the conductive metallic sheet is secured to the surface of the conductive polymeric sheet opposite the zinc.
Claim 6
Dependent Claim 15 words
A planar battery as defined in claim 4 wherein the conductive metallic sheet comprises steel.
Claim 7
Dependent Claim 13 words
A planar battery as defined in claim 2 wherein the cathode comprises carbon.
Claim 8
Dependent Claim 14 words
A planar battery as defined in claim 6 wherein the cathode includes manganese dioxide.
Claim 9
Dependent Claim 24 words
A planar battery as defined in claim 7 wherein the carbon and manganese dioxide are disposed in an electrically conductive ionically permeable polymeric matrix.
Claim 10
Dependent Claim 29 words
A planar battery as defined in claim 8 wherein the carbon/manganese dioxide mixture is secured to the surface of a conductive carbon retaining polymeric sheet positioned distal the separator.
Claim 11
Dependent Claim 29 words
A planar battery as defined in claim 9 wherein a conductive metallic sheet is secured to the surface of the exterior conductive carbon retaining sheet opposite the carbon/manganese mixture.
Claim 12
Dependent Claim 17 words
A planar battery as defined in claim 6 wherein the electrolyte comprises zinc chloride and/or ammonium chloride.
Claim 13
Dependent Claim 19 words
A planar battery as defined in claim 11 wherein the electrolyte is disposed in an ionically permeable polymeric matrix.
Claim 14
Dependent Claim 16 words
A planar battery as defined in claim 12 wherein the separator comprises electrolyte permeable fibrous sheet.
Claim 15
Dependent Claim 46 words
A planar battery as defined in claim 1 wherein the marginal portions of the separator comprise electrolyte permeable separator sheet impregnated with said electrically nonconductive, water-vapor impermeable heat-activated thermosetting adhesive in a concentration effective to prevent electrolyte permeation of the marginal portions of the separator sheet.
Claim 16
Dependent Claim 20 words
A planar battery as defined in claim 1 wherein said thermally dissociated adduct is the phenol derivative of toluene diisocyanate.
Claim 17
Dependent Claim 39 words
A planar battery as defined in claim 1 wherein said polymer containing active hydrogen atoms is selected from a group consisting of polyurethanes, suitably derivatized acrylics, poly-hydroxy ethers, polyesters, polyamides, polyureas, polyamineamides, and water insensitive organo soluble cellulosic derivatives.
Claim 18
Dependent Claim 21 words
A planar battery as defined in claim 1 wherein said polymer containing active hydrogen atoms is a bisphenol A type polyhydroxyether.
Claim 19
Dependent Claim 209 words
A planar battery comprising a plurality of cells as defined in claim 1 in stacked and series relationship, each cell comprising, in combination: a. a planar anode; b. a planar cathode superposed substantially coextensive the anode; c. a planar separator including marginal portions and an aqueous electrolyte permeable central portion positioned intermediate and extending substantially coextensive the facing surfaces of the anode and the cathode; d. aqueous electrolyte disposed in the central portion of the separator and in contact with the facing surfaces of the anode and the cathode; e. an electrolyte impermeable electrically conducting intercell connector positioned intermediate and in coextensive contact with the facing surfaces of each superposed cell; and f. an electrically nonconducting, water-vapor impermeable heat-activated thermosetting polymeric adhesive extending coextensive the marginal surfaces of each separator and securing the marginal portions of the separators and each next adjacent facing surface, which adhesive is the product of the reaction between a polymer containing active hydrogen atoms, and a thermally dissociated adduct of a compound containing at least two -N C X groups wherein X is selected from the group consisting of oxygen and sulfur and tHe adduct is based on a compound selected from the group consisting of phenols, alkyl and aryl thiols and 1,3-dicarbonyl compounds.
Claim 20
Dependent Claim 21 words
A planar battery as defined in claim 18 wherein the intercell connector comprises an electrolyte impermeable electrically conducting polymeric sheet material.
Claim 21
Dependent Claim 48 words
A planar battery as defined in claim 19 wherein the anode of the first of two superposed cells is adhesively secured to one surface of the intercell connector and the cathode of the second of the superposed cells is adhesively secured to the opposite surface of the connector.

References Cited (Backward Citations)

US2880259A Cited
US3004094A Cited
US3563805A Cited
US3617387A Cited
US3770504A Cited
US3734780A Cited
US3784414A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-08-11 1979-02-10 1979-08-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-08-11 1983-02-10 1983-08-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-08-11 1987-02-10 1987-08-12 $7700.00 Window Closed / Lapsed

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