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US3896112A Expired / Lapsed US ⏱️ 0.0 years remaining

Bisbenzopyran and bisbenzopyrylium adducts

Assignee: Ricoh Co Ltd
•
Filing: 1972-10-20
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Granted: 1975-07-22
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Expires: 1992-10-20
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Abstract

Abstract A sensitizer for use in electrophotography comprising a bisbenzopyran or bisbenzopyrylium adduct of a member selected from the group consisting of bisbenzopyrylium salts represented by the general formula I: wherein R1 represents hydrogen, iso- or normal-alkyl radical having 1 to 10 carbon atoms or the phenyl radical; R2 represents phenyl, naphthyl styryl or any of these radicals having 1 to 3 substituents selected from methyl radical, alkoxy containing 1 to 4 carbon atoms such as methoxy, ethoxy and butoxy; and X represents an anionic functional radical; and benzopyrylium salts represented by the general formula II: wherein R3 represents methyl, phenyl or wherein R6 represents hydrogen or a lower alkyl radical having 1 to 3 carbon atoms; R7 represents phenyl, naphthyl or either of these radicals having 1 to 3 substituents selected from methyl, methoxy, nitro, nitrile, halogen, carboxyl, amino and hydroxy; R4 represents hydrogen, methyl or phenyl; R5 represents hydrogen, lower alkyl containing 1 to 2 carbon atoms, alkoxy containing 1 to 2 carbon atoms, halogen, nitro or nitrile; and Y represents an anionic functional radical; AND A MEMBER SELECTED FROM THE GROUP CONSISTING OF BISBENZOPYRAN DERIVATIVES HAVING THE FOLLOWING GENERAL FORMULA I'': wherein R1 and R2 are identical with R1 and R2 in the general formula I respectively: AND BENZOPYRAN DERIVATIVES HAVING THE FOLLOWING GENERAL FORMULA II'': wherein R3, R4 and R5 are identical with R3, R4 and R5 in the general formula II respectively.

Inventors

  • 👤 Tomio Kubota
  • 👤 Katsue Kojima
  • 👤 Masafumi Ohta

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 23:07
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0664; G03G5/0666; G03G5/0672; G03G5/0674; C; C07; C07D; C07D311/00; C07D311/02; C07D311/04; C07D311/58

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 26 words
A COMPOUND WHICH IS A BISBENZOPYRAN OR BISBENZOPYRYLIUM ADDUCT OF A MEMBER SELECTED FROM THE GROUP CONSISTING OF BISBENZOPYRYLIUM SALTS REPRESENTED BY THE GENERAL FORMULA 1:
Claim 2
Dependent Claim 26 words
A COMPOUND WHICH IS A BISBENZOPYRAN OR BISBENZOPYRYLIUM ADDUCT OF A MEMBER SELECTED FROM THE GROUP CONSISTING OF BISBENZOPYRYLIUM SALTS REPRESENTED BY THE GENERAL FORMULA 1:
Claim 3
Dependent Claim 25 words
An adduct as in claim 1 wherein the benzopyran compound is 6, 6''-methylene bis-(2-(4''-methoxy naphthoethenyl)-3-phenyl-4-methoxy) benzopyran and the benzopyrylium compound is 6,6''-methylenebis-(2-(4''-methoxy naphthoethenyl)-3-phenyl) benzopyrylium perchlorate.
Claim 4
Dependent Claim 25 words
An adduct as in claim 1 wherein the benzopyran compound is 6, 6''-methylene bis-(2-(4''-methoxy naphthoethenyl)-3-phenyl-4-methoxy) benzopyran and the benzopyrylium compound is 2-(P-methoxy styryl)-3-phenyl-6-methoxy benzopyrylium perchlorate.
Claim 5
Dependent Claim 24 words
An adduct as in claim 1 wherein the benzopyran compound is 6, 6''-methylenebis-(2-(2'',3'',4''-trimethoxy styryl)-3-phenyl-4-methoxy) benzopyran and the benzopyrylium compound is 2-(P-methoxy styryl)-3-phenyl-6-methoxy benzopyrylium perchlorate.
Claim 6
Dependent Claim 23 words
An adduct as in claim 1 wherein the benzopyran compound is 6, 6''-methylenebis-(2-(2'',3'',4''-trimethoxy styryl)-3-phenyl-4-methoxy) benzopyran and the benzopyrylium compound is 6,6''-methylenebis-(2-(2'',3'',4''-trimethoxystyryl)-3-phenyl) benzopyrylium perchlorate.
Claim 7
Dependent Claim 23 words
An adduct as in claim 1 wherein the beyzopyran compound is 6, 6''-methylenebis-(2-(2'',3'',4''-trimethoxy styryl)-3-phenyl-4-methoxy) benzopyran and the benzopyrylium compound is 2-phenyl benzopyrylium perchlorate.

References Cited (Backward Citations)

US3526502A Cited
US3586500A Cited
US3617268A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-07-21 1979-01-20 1979-07-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-07-21 1983-01-20 1983-07-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-07-21 1987-01-20 1987-07-22 $7700.00 Window Closed / Lapsed

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