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US3894233A Expired / Lapsed US ⏱️ 0.0 years remaining

Ion microprobe analyzer

Assignee: Hitachi Ltd
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Filing: 1973-10-29
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Granted: 1975-07-08
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Expires: 1993-10-29
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Abstract

Abstract An ion microprobe analyzer including a detector of secondary particles emitted from a specimen by bombarding a specimen with an ion beam, and means for recording or displaying the relationship between currents of the secondary particles and specific ions. According to this ion microprobe analyzer the influence on the measurement of the work function of a surface of the specimen is eliminated and the measurement of a concentration distribution of an element in a direction toward the depth of the specimen can be measured precisely.

Inventors

  • 👤 Hifumi Tamura
  • 👤 Toshio Kondo
  • 👤 Kazumitsu Nakamura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 10:34
CPC Classifications
H; H01; H01J; H01J49/00; H01J49/02; H01J49/10; H01J49/14; H01J49/142; H01J37/00; H01J37/252

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 164 words
An ion microprobe analyzer comprising: means for generating a primary ion beam; means for bombarding a specimen with said primary ion beam; means for detecting a part of the secondary particles emitted from all elements contained in the specimen as a result of the bombardment thereof by said primary ion beam; means for mass-analyzing a part of the secondary ions in the secondary particles emitted from said specimen; means for detecting ions of an element to be analyzed derived from the secondary ions in the mass-analyzing means; and means for measuring the ratio of the output signals from said means for detecting a part of the secondary particles and said means for detecting ions of an element to be analyzed; whereby the influence of the work function of the bombarded surface of the specimen can be determined so that a measurement of the concentration distribution of an element of the specimen in the direction of the depth of the specimen can be measured precisely.
Claim 2
Dependent Claim 164 words
An ion microprobe analyzer comprising: means for generating a primary ion beam; means for bombarding a specimen with said primary ion beam; means for detecting a part of the secondary particles emitted from all elements contained in the specimen as a result of the bombardment thereof by said primary ion beam; means for mass-analyzing a part of the secondary ions in the secondary particles emitted from said specimen; means for detecting ions of an element to be analyzed derived from the secondary ions in the mass-analyzing means; and means for measuring the ratio of the output signals from said means for detecting a part of the secondary particles and said means for detecting ions of an element to be analyzed; whereby the influence of the work function of the bombarded surface of the specimen can be determined so that a measurement of the concentration distribution of an element of the specimen in the direction of the depth of the specimen can be measured precisely.
Claim 3
Dependent Claim 17 words
An ion microprobe analyzer according to claim 1, which further comprises a shielding electrode surrounding the specimen.
Claim 4
Dependent Claim 27 words
An ion microprobe analyzer according to claim 2, in which said means for detecting a part of the secondary particles is provided outside of the shielding electrode.
Claim 5
Dependent Claim 37 words
An ion microprobe analyzer according to claim 2, in which said shielding electrode is made of a conductor mesh in the shape of a hemisphere and has a common potential for the specimen holder and the specimen.
Claim 6
Dependent Claim 32 words
An ion microprobe analyzer according to claim 1, in which said means for detecting a part of the secondary particles is provided between the specimen and said means for mass-analyzing secondary ions.
Claim 7
Dependent Claim 24 words
An ion microprobe analyzer according to claim 1, in which said means for detecting a part of the secondary particles is a monitoring electrode.
Claim 8
Dependent Claim 25 words
An ion microprobe analyzer according to claim 1, in which said means for detecting a part of the secondary particles is a secondary electron multiplier.
Claim 9
Dependent Claim 61 words
An ion microprobe analyzer according to claim 1, further including a ratio circuit connected to said two detecting means, and in which said means for measuring the ratio comprises means for visually indicating the output from the ratio circuit connected to the respective means for detecting a part of the secondary particles and the ions of an element to be analyzed.
Claim 10
Dependent Claim 49 words
An ion microprobe analyzer according to claim 1, in which said means for measuring the ratio comprises means for visually indicating at the same time the outputs from said means for detecting a part of the secondary particles and said means for detecting a part of the secondary ions.
Claim 11
Dependent Claim 49 words
An ion microprobe analyzer according to claim 1, in which said means for mass-analyzing a part of the secondary ions includes an electrostatic sector and a magnetic sector and said means for detecting a part of the secondary particles is provided between said electrostatic sector and said magnetic sector.
Claim 12
Dependent Claim 16 words
An ion microprobe analyzer according to claim 10, further comprising a shielding electrode surrounding the specimen.
Claim 13
Dependent Claim 37 words
An ion microprobe analyzer according to claim 10, in which said shielding electrode is made of a conductor mesh in the shape of a hemisphere and has a common potential for the specimen holder and the specimen.
Claim 14
Dependent Claim 60 words
An ion microprobe analyzer according to claim 10, in which said means for detecting a part of the secondary particles comprises means for converting an ion input to an electron output having a through hole, a scintillater having an electrode, a mesh electrode disposed between said converting means and said scintillater and photo multiplier for receiving light from said scintillater.
Claim 15
Dependent Claim 17 words
An ion microprobe analyzer according to claim 13, which further comprises a shieLding electrode surrounding the specimen.
Claim 16
Dependent Claim 37 words
An ion microprobe analyzer according to claim 13, in which said shielding electrode is made of a conductor mesh in the shape of a hemisphere and has a common potential for the specimen holder and the specimen.
Claim 17
Independent Claim 186 words
A method of measurement of the concentration distribution of an element in the direction of the depth of a specimen comprising the steps of: a. generating a primary ion beam; b. bombarding a specimen with said primary ion beam; c. detecting a part of the secondary particles emitted from all the elements contained in the specimen as a result of the bombardment thereof by said primary ion beam and generating a signal representative thereof; d. mass-analyzing a part of the secondary ions in the secondary particles emitted from said specimen; e. detecting the ions of an element to be analyzed derived from the secondary ions in the mass-analyzing step (d) and generating a signal representative thereof; and f. measuring the ratio of the output signals from detecting a part of the secondary particles in step (c) and detecting ions of an element to be analyzed in step (e); whereby the influence of the work function of the surface of the specimen is determined and a measurement of the concentration distribution of the element in the direction of the depth of the specimen can be measured precisely.
Claim 18
Independent Claim 186 words
A method of measurement of the concentration distribution of an element in the direction of the depth of a specimen comprising the steps of: a. generating a primary ion beam; b. bombarding a specimen with said primary ion beam; c. detecting a part of the secondary particles emitted from all the elements contained in the specimen as a result of the bombardment thereof by said primary ion beam and generating a signal representative thereof; d. mass-analyzing a part of the secondary ions in the secondary particles emitted from said specimen; e. detecting the ions of an element to be analyzed derived from the secondary ions in the mass-analyzing step (d) and generating a signal representative thereof; and f. measuring the ratio of the output signals from detecting a part of the secondary particles in step (c) and detecting ions of an element to be analyzed in step (e); whereby the influence of the work function of the surface of the specimen is determined and a measurement of the concentration distribution of the element in the direction of the depth of the specimen can be measured precisely.
Claim 19
Dependent Claim 28 words
A method of measurement according to claim 16, which further comprises the step of (g) visually indicating said compared results after said step (f) of measuring the ratio.
Claim 20
Dependent Claim 194 words
An ion microprobe analyzer comprising: first means for generating a primary ion beam; second means for directing said primary ion beam onto a specimen, the concentration distribution of an element in which is to be measured; third means for detecting a portion of each of the types of secondary particles emitted from said specimen as a result of the bombardment of said specimen with said primary ion beam and generating a first signal representative thereof; fourth means for mass-analyzing a portion of the secondary ions included among the secondary particles emitted from said specimen; fifth means for detecting the ions of a selected element from the secondary ions mass-analyzed by said fourth means and generating a second signal representative thereof; and sixth means, coupled to said third means and said fifth means, for measuring the ratio of said first and second signals, whereby the influence of the work function of the surface of said specimen bombarded with said primary ion beam can be determined, so that a measurement of the concentration distribution of an element in said specimen with respect to its depth in said specimen from the surface thereof may be precisely effected.
Claim 21
Dependent Claim 194 words
An ion microprobe analyzer comprising: first means for generating a primary ion beam; second means for directing said primary ion beam onto a specimen, the concentration distribution of an element in which is to be measured; third means for detecting a portion of each of the types of secondary particles emitted from said specimen as a result of the bombardment of said specimen with said primary ion beam and generating a first signal representative thereof; fourth means for mass-analyzing a portion of the secondary ions included among the secondary particles emitted from said specimen; fifth means for detecting the ions of a selected element from the secondary ions mass-analyzed by said fourth means and generating a second signal representative thereof; and sixth means, coupled to said third means and said fifth means, for measuring the ratio of said first and second signals, whereby the influence of the work function of the surface of said specimen bombarded with said primary ion beam can be determined, so that a measurement of the concentration distribution of an element in said specimen with respect to its depth in said specimen from the surface thereof may be precisely effected.

References Cited (Backward Citations)

US3646344A Cited
US3686499A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-07-07 1979-01-06 1979-07-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-07-07 1983-01-06 1983-07-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-07-07 1987-01-06 1987-07-08 $7700.00 Window Closed / Lapsed

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