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US3893876A Expired / Lapsed US ⏱️ 0.0 years remaining

Method and apparatus of the continuous preparation of epitaxial layers of semiconducting III-V compounds from vapor phase

Assignee: Sumitomo Electric Industries Ltd
•
Filing: 1972-08-31
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Granted: 1975-07-08
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Expires: 1992-08-31
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Abstract

Abstract This invention relates to a method for the continuous preparation of epitaxial layers of semiconducting III-V compounds on suitable substrates of the single crystal from a gas mixture thereof. The plurality of substrates are moved in parallel with the flow of said gas mixture in a reaction furnace which is given a temperature gradient in the same direction as the flow of said gas mixture, the temperature decreasing with distance in the direction of the gas flow. The semiconducting compounds are effectively recovered as epitaxial layers on the substrates, and the composition of the mixed crystal of III-V semiconductors can be changed continuously to result in the graded composition, without timewise changing the composition of said gas mixture. Through the gas mixture entering into the reaction furnace is of constant composition, the composition of the gas mixture is gradually changed downstream of the gas flow in the reaction furnace as a result of effective recovery of the semiconducting compounds on the substrates.

Inventors

  • 👤 Shin-Ichi Akai
  • 👤 Makoto Hayashi
  • 👤 Shin-Ichi Iguchi
  • 👤 Takashi Shimoda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 17:46
CPC Classifications
C; C23; C23C; C23C16/00; C23C16/22; C23C16/30; C23C16/301; Y; Y10; Y10S; Y10S148/00; Y10S148/065; Y10S148/067; Y10S148/072; Y10S438/00; Y10S438/936

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 265 words
A METHOD FOR THE CONTINUOUS PREPARATION OF THE EPITAXIAL LAYERS OF A III-V TERNARY COMPOUND SEMICONDUCTOR REPRESENTED BY GENERAL FORMULA AB1-XCX ON A III-V BINARY COMPOUND SEMICONDUCTOR FROM A GAS MIXRUE, WHEREIN ABI-XCX STANDS FOR BOTH AIIIBV1-X AND BIII1-XCIIIXAV,AIII AND AV BEING III-B ELEMENT AND A V-B ELEMENT, RESPECTIVELY, AND BIII AND CIIIAND BV AND CV BEING TWO DIFFERENT III-B ELEMENTS AND V-B ELEMENTS, RESPECTIVELY, AND THE VALUE OF X BEING BETWEEN 0 AND 1, WHEREIN SAID III-V TERNARY COMPOUND SEMICONDUCTOR WITH A GRADED COMPOSITION IS GROWN WITHOUT CHANGING TIMEWISE THE COMPOSITION OF SAID GAS MIXTURE ENTERING INTO THE REACTION FURNACE, WHICH IS GIVEN A TEMPERATURE GRADIENT DECREASING WITH DISTANCE IN THE DIRECTION OF THE GAS FLOW, AND BY GRADUALLY CHANGING THE TEMPERATURE OF SAID III-V BINARY COMPOUND SEMICONDUCTOR, AND WHICH IS CHARACTERIZED BY CONTINUOUSLY CHANGING THE VALUE OF X TO RESULT IN THE GRADED COMPOSITION BY CONTINUOUSLY MOVING THE PLURALITY OF SAID III-V BINARY COMPOUND SEMICONDUCTOR SUBSTRATES, UPSTREAM OF SAID GAS FLOW IN THE SITUATION WHEN THE SUBSTRATE HAS A LOWER MELTING POINT, AND DOWNSTREAM OF SAID GAS FLOW IN HE SITUATION WHEN THE SUBSTRATE HAS A HIGHER MELTING POINT THAN SAID TERNARY COMPOUND SEMICONDUCTOR, RESPECTIVELY, THUS EFFECTIVELY ROWING SAID EPITAXIAL LAYERS ON SAID SUBSTRATES THEREBY GRADUALLY DECREASING THE CONSITUENT C AND NCREASING THE CONSITUENT B IN THE GAS MIXTURE IN THE REACTION FURNACE DOWNSTREAM OF SAID GAS FLOW IN THE SITUATION WHEN THE COMPOUND AB HAS A LOWER MELTING POINT THAN THE COMPOUND AC AND VICE VERSA IN THE SITUATION WHEN THE COMPOUND AB HAS A HIGHER MELTING POINT THAM THE COMPOUND AC.
Claim 2
Independent Claim 265 words
A METHOD FOR THE CONTINUOUS PREPARATION OF THE EPITAXIAL LAYERS OF A III-V TERNARY COMPOUND SEMICONDUCTOR REPRESENTED BY GENERAL FORMULA AB1-XCX ON A III-V BINARY COMPOUND SEMICONDUCTOR FROM A GAS MIXRUE, WHEREIN ABI-XCX STANDS FOR BOTH AIIIBV1-X AND BIII1-XCIIIXAV,AIII AND AV BEING III-B ELEMENT AND A V-B ELEMENT, RESPECTIVELY, AND BIII AND CIIIAND BV AND CV BEING TWO DIFFERENT III-B ELEMENTS AND V-B ELEMENTS, RESPECTIVELY, AND THE VALUE OF X BEING BETWEEN 0 AND 1, WHEREIN SAID III-V TERNARY COMPOUND SEMICONDUCTOR WITH A GRADED COMPOSITION IS GROWN WITHOUT CHANGING TIMEWISE THE COMPOSITION OF SAID GAS MIXTURE ENTERING INTO THE REACTION FURNACE, WHICH IS GIVEN A TEMPERATURE GRADIENT DECREASING WITH DISTANCE IN THE DIRECTION OF THE GAS FLOW, AND BY GRADUALLY CHANGING THE TEMPERATURE OF SAID III-V BINARY COMPOUND SEMICONDUCTOR, AND WHICH IS CHARACTERIZED BY CONTINUOUSLY CHANGING THE VALUE OF X TO RESULT IN THE GRADED COMPOSITION BY CONTINUOUSLY MOVING THE PLURALITY OF SAID III-V BINARY COMPOUND SEMICONDUCTOR SUBSTRATES, UPSTREAM OF SAID GAS FLOW IN THE SITUATION WHEN THE SUBSTRATE HAS A LOWER MELTING POINT, AND DOWNSTREAM OF SAID GAS FLOW IN HE SITUATION WHEN THE SUBSTRATE HAS A HIGHER MELTING POINT THAN SAID TERNARY COMPOUND SEMICONDUCTOR, RESPECTIVELY, THUS EFFECTIVELY ROWING SAID EPITAXIAL LAYERS ON SAID SUBSTRATES THEREBY GRADUALLY DECREASING THE CONSITUENT C AND NCREASING THE CONSITUENT B IN THE GAS MIXTURE IN THE REACTION FURNACE DOWNSTREAM OF SAID GAS FLOW IN THE SITUATION WHEN THE COMPOUND AB HAS A LOWER MELTING POINT THAN THE COMPOUND AC AND VICE VERSA IN THE SITUATION WHEN THE COMPOUND AB HAS A HIGHER MELTING POINT THAM THE COMPOUND AC.
Claim 3
Dependent Claim 26 words
A method as claimed in claim 1 wherein said III-V ternary compound semiconductor is GaAs1-xPx and GaP is utilized for said III-V binary compound semiconductor substrate.
Claim 4
Dependent Claim 43 words
A method as claimed in claim 2 which is characterized in that said gas mixture is produced from the reaction products of a hydrogen gas saturated with AsC13 with GaAs and the reaction products of a hydrogen gas saturated with PC13 with GaP.
Claim 5
Dependent Claim 38 words
A method as claimed in claim 1 which is characterized in that dummy wafers are placed in the reaction furnace before the movement of said substrates is started, thereby effectively depositing said ternary compound semiconductor on said wafers.

References Cited (Backward Citations)

US2853970A Cited
US2877138A Cited
US3341376A Cited
US3314393A Cited
US3441454A Cited
US3441453A Cited
US3572286A Cited
US3672948A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-07-07 1979-01-06 1979-07-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-07-07 1983-01-06 1983-07-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-07-07 1987-01-06 1987-07-08 $7700.00 Window Closed / Lapsed

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