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Production of synthetic lubricants from alpha-olefins through a ternary catalytic system

Assignee: SnamProgetti SpA
•
Filing: 1973-02-15
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Granted: 1975-05-20
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Expires: 1993-02-15
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Abstract

Abstract Synthetic, high quality lubricating oils are produced through the polymerization of a single alpha-olefin or a mixture of alpha-olefins from ''''wax-cracking'''' having the formula R - CH CH2 wherein R is an alkyl radical containing from 2 to 16 C atoms, by the use, in a dry nitrogen atmosphere, of a catalyst system constituted by a compound of a transition metal selected from groups IV to VIII of the periodic system (e.g., TiCl4) and by two coordinate anionic cocatalysts, one of which is an aluminum compound of inorganic nature devoid of any metal-carbon bond and consisting of a polyiminic linear polymer (e.g., a polyimine alane represented by the formula: WHEREIN R is alkyl, aryl or cycloalkyl and n is a whole number from 4 to 25) and the other of which is an aluminum compound of the conventional Ziegler type with a metal-carbon link (e.g., an aluminum alkyl sesquichloride or an aluminum dialkyl monochloride.

Inventors

  • 👤 Pierleone Girotti
  • 👤 Renato Tesei
  • 👤 Telemaco Floris

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 18:50
CPC Classifications
C; C10; C10M; C10M3/00; C08; C08F; C08F10/00; C08F10/14; C10M2205/00

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 105 words
PROCESS FOR THE PREPARATION OF HIGH QUALITY LUBRICATING OILS THROUGH TH POLYMERIZATION OF A MEMBER OF THE GROUP CONSISTING OF PURE NORMAL ALPHA-OLEFINS AND OF MIXTURES OF COMMERCIAL ALPHA-OLEFINS HAVING THE GENERAL FORMULA R - CH = CH2, IN WHICH R IS AN ALKYL RADICAL CONTAINING FROM 2 TO 16 CARBON ATOMS, WHEREIN THE CATALYTIC SYSTEM USED FOR EFFECTING THE POLYMERIZATION IS A CATALYST CONSISTING OF A COMPOUND OF A TRANSITION METAL SELECTED FROM THE GROUP CONSISTING OF TICL4, TICL3, VCL4 AND VOCL3 AND TWO ANIONIC COORDINATE COCATALYSTS, CONSISTING RESPECTIVELY, OF: (A) A LINEAR POLYMER CONSTITUTED BY A POLYIMINIC COMPOUND HAVING THE FOLLOWING GENERAL FORMULA
Claim 2
Dependent Claim 105 words
PROCESS FOR THE PREPARATION OF HIGH QUALITY LUBRICATING OILS THROUGH TH POLYMERIZATION OF A MEMBER OF THE GROUP CONSISTING OF PURE NORMAL ALPHA-OLEFINS AND OF MIXTURES OF COMMERCIAL ALPHA-OLEFINS HAVING THE GENERAL FORMULA R - CH = CH2, IN WHICH R IS AN ALKYL RADICAL CONTAINING FROM 2 TO 16 CARBON ATOMS, WHEREIN THE CATALYTIC SYSTEM USED FOR EFFECTING THE POLYMERIZATION IS A CATALYST CONSISTING OF A COMPOUND OF A TRANSITION METAL SELECTED FROM THE GROUP CONSISTING OF TICL4, TICL3, VCL4 AND VOCL3 AND TWO ANIONIC COORDINATE COCATALYSTS, CONSISTING RESPECTIVELY, OF: (A) A LINEAR POLYMER CONSTITUTED BY A POLYIMINIC COMPOUND HAVING THE FOLLOWING GENERAL FORMULA
Claim 3
Dependent Claim 16 words
Process according to claim 1 wherein the polymerization is carried out in a dry nitrogen atmosphere.
Claim 4
Dependent Claim 23 words
Process according to claim 1, wherein the two cocatalysts which reduce the transition metal compound are in a ratio from 70/30 to 80/20.
Claim 5
Dependent Claim 38 words
Process according to claim 1 wherein the molar ratio between compound (a) and the compound of the transition metal is from 1.2 to 1.3, fixing at 1 the molar ratio between compound (b) and the transition metal compound.
Claim 6
Dependent Claim 12 words
Process according to claim 1, wherein the transition metal compound is TiCl4.
Claim 7
Dependent Claim 19 words
Process according to claim 1, wherein the ratio by weight of olefins/transition metal compound is between 10 and 500.
Claim 8
Dependent Claim 30 words
Process according to claim 1, wherein the reaction is carried out in the presence of a solvent selected from the group consisting of aromatic hydrocarbons, halogenated hydrocarbons and saturated hydrocarbons.
Claim 9
Dependent Claim 14 words
Process according to claim 1, wherein the polymerization temperature is from 0* to 200*C.

References Cited (Backward Citations)

US3156736A Cited
US3259668A Cited
US3467639A Cited
US3489736A Cited
US3798284A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-05-19 1978-11-18 1979-05-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-05-19 1982-11-18 1983-05-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-05-19 1986-11-18 1987-05-20 $7700.00 Window Closed / Lapsed

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