US3844938A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Reforming of hydrocarbon feed stocks with a catalyst comprising platinum and tin
Assignee: Universal Oil Products Co
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Filing: 1973-02-16
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Granted: 1974-10-29
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Expires: 1993-02-16
Abstract
Abstract A process for reforming a hydrocarbon feed stock which comprises heating said charge stock in contact with a catalytic composite comprising a tin component and a platinum component on a carrier material at reforming conditions including a pressure of from about 0 to about 1000 psig and a temperature of from about 800* to about 1,100* F. The catalytic composite is characterized by a method of preparation. A high surface area porous carrier material is impregnated with a solution comprising a trichlorostannate (II)-chloroplatinate anionic complex and thereafter dried and calcined to yield the catalytic composite.
Inventors
- 👤 F Wilhelm
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 02:48
CPC Classifications
B; B01; B01J; B01J37/00; B01J37/22; B01J37/24; B01J23/00; B01J23/38; B01J23/54; B01J23/56; B01J23/62; B01J23/622; B01J23/626; C; C10; C10G; C10G35/00; C10G35/04; C10G35/06; C10G35/085; C10G35/09; C10G47/00; C10G47/02; C10G47/10; C10G47/12; C10G47/14; C07; C07C; C07C2521/00; C07C2521/02; C07C2521/04; C07C2523/00; C07C2523/14; C07C2523/38; C07C2523/40; C07C2523/42; C07C2523/54; C07C2523/56; C07C2523/62
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
113 words
A PROCESS FOR REFORMING A HYDROCARBON FEED STOCK WHICH COMPRISES HEATING SAID CHARGE STOCK IN CONTACT WITH A CATALYTIC COMPOSITE AT REFORMING CONDITIONS INCLUDING A PRESSURE OF FROM ABOUT 0 TO ABOUT 1000 PSIG AND A TEMPERATURE OF FROM ABOUT 800* TO ABOUT 1100*F., SAID CATALYTIC COMPOSITE CONSISTING ESSENTIALLY OF A TIN COMPONENT IN COMBINATION WITH A PLATINUM COMPONENT ON A CARRIER MATERIAL, AND PREPARED BY THE METHOD WHICH COMPRISES: A. IMPREGNATING A HIGH SURFACE AREA, POROUS CARRIER MATERIAL WITH A SOLUTION OF A COMPLEX CHLOROSTANNATE (II)CHLOROPLATINATE ANIONIC SPECIES, SAID SOLUTION BEING STABILIZED IN CONTACT WITH SAID CARRIER MATERIAL WITH AN AQUEOUS HALOGEN ACID; AND B. DRYING AND CALCINING THE IMPREGNATED CARRIER MATERIAL.
Claim 2
Dependent Claim
113 words
A PROCESS FOR REFORMING A HYDROCARBON FEED STOCK WHICH COMPRISES HEATING SAID CHARGE STOCK IN CONTACT WITH A CATALYTIC COMPOSITE AT REFORMING CONDITIONS INCLUDING A PRESSURE OF FROM ABOUT 0 TO ABOUT 1000 PSIG AND A TEMPERATURE OF FROM ABOUT 800* TO ABOUT 1100*F., SAID CATALYTIC COMPOSITE CONSISTING ESSENTIALLY OF A TIN COMPONENT IN COMBINATION WITH A PLATINUM COMPONENT ON A CARRIER MATERIAL, AND PREPARED BY THE METHOD WHICH COMPRISES: A. IMPREGNATING A HIGH SURFACE AREA, POROUS CARRIER MATERIAL WITH A SOLUTION OF A COMPLEX CHLOROSTANNATE (II)CHLOROPLATINATE ANIONIC SPECIES, SAID SOLUTION BEING STABILIZED IN CONTACT WITH SAID CARRIER MATERIAL WITH AN AQUEOUS HALOGEN ACID; AND B. DRYING AND CALCINING THE IMPREGNATED CARRIER MATERIAL.
Claim 3
Dependent Claim
22 words
The process of claim 1 further characterized with respect to step (a) in that said solution is stabilized with aqueous hydrochloric acid.
Claim 4
Dependent Claim
24 words
The process of claim 1 further characterized with respect to step (a) in that said solution comprises a complex trichlorostannate (II)-chloroplatinate (IV) anionic species.
Claim 5
Dependent Claim
24 words
The process of claim 1 further characterized with respect to step (a) in that said solution comprises a complex trichlorostannate (II)-chloroplatinate (II) anionic species.
Claim 6
Dependent Claim
15 words
The process of claim 1 further characterized in that said carrier material is an alumina.
Claim 7
Dependent Claim
14 words
The process of claim 1 further characterized in that said carrier material is gamma-alumina.
Claim 8
Dependent Claim
30 words
The process of claim 1 further characterized with respect to step (a) in that said solution is stabilized with aqueous hydrochloric acid at a pH of less than about 1.
Claim 9
Dependent Claim
44 words
The process of claim 1 further characterized with respect to step (a) in that said carrier material is impregnated with from about 0.05 to about 1.0 wt. percent platinum and from about 0.05 to about 1.0 wt. percent tin from said complex anionic solution.
Claim 10
Dependent Claim
34 words
The process of claim 1 further characterized in that said reforming conditions include a pressure of from about 50 to about 350 psig and a temperature of from about 800* to about 1050* F.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1977-10-28 | 1978-04-29 | 1978-10-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1981-10-28 | 1982-04-29 | 1982-10-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1985-10-28 | 1986-04-29 | 1986-10-29 | $7700.00 | Window Closed / Lapsed |