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EP0469470A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Process for producing multilayered printed board

Assignee: Mitsubishi Gas Chemical Co Inc
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Filing: 1991-07-25
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Granted: —
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Expires: 2011-07-25
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Abstract

Abstract A process for producing a multilayered printed circuit board which comprises using, as an intermediate layer, an inner-layer board obtained by chemically oxidizing the surface of a copper foil constituting an outermost layer of an inner-layer board having a printed circuit formed in the copper foil, thereby to form on the surface a finely roughened layer constituted by a copper oxide of a brown to black color, and then reducing the copper oxide constituting the finely roughened layer in an atmosphere in which a reducing gas is present.

Inventors

  • 👤 Ando Kazuhiro
  • 👤 Kawakami Takamasa
  • 👤 Shouji Yasuhiro
  • 👤 Tanaka c/o Mitsubishi Gas Chem. Comp. Inc. Yasuo
  • 👤 Kanaoka c/o Mitsubishi Gas Chem. Co. Inc. Takeo
  • 👤 Sayama c/o Mitsubishi Gas Chem. Comp. Inc. Norio

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 08:47
CPC Classifications
H; H05; H05K; H05K3/00; H05K3/46; H05K3/38; H05K3/382; H05K3/385; H05K2203/00; H05K2203/03; H05K2203/0315; H05K2203/11; H05K2203/1157; H05K3/4611

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 88 words
A process for producing a multilayered printed circuit board which comprises using, as an intermediate layer, an inner-layer board obtained by chemically oxidizing the surface of a copper foil constituting an outermost layer of an inner-layer board having a printed circuit formed in the copper foil, thereby to form on the surface a finely roughened layer constituted by a copper oxide of a brown to black color, and then reducing the copper oxide constituting the finely roughened layer in an atmosphere in which a reducing gas is present.
Claim 2
Dependent Claim 88 words
A process for producing a multilayered printed circuit board which comprises using, as an intermediate layer, an inner-layer board obtained by chemically oxidizing the surface of a copper foil constituting an outermost layer of an inner-layer board having a printed circuit formed in the copper foil, thereby to form on the surface a finely roughened layer constituted by a copper oxide of a brown to black color, and then reducing the copper oxide constituting the finely roughened layer in an atmosphere in which a reducing gas is present.
Claim 3
Dependent Claim 19 words
A process as claimed in claim 1, wherein said reducing gas is hydrogen, carbon monoxide, or a mixture thereof.
Claim 4
Dependent Claim 21 words
A process as claimed in claim 2, wherein the reduction is conducted at a temperature of from 100 to 160° C.
Claim 5
Dependent Claim 14 words
A process as claimed in claim 1, wherein said reducing gas is hydrazine gas.
Claim 6
Dependent Claim 20 words
A process as claimed in claim 4, wherein the pressure of said hydrazine gas is from 0.01 to 15 mmHg.
Claim 7
Dependent Claim 21 words
A process as claimed in claim 5, wherein the reduction is conducted at a temperature of from 60 to 140° C.
Claim 8
Dependent Claim 25 words
A process as claimed in claim 1, wherein a platinum group metal catalyst is fixed on the finely roughened layer constituted by a copper oxide.
Claim 9
Dependent Claim 16 words
A process as claimed in claim 7, wherein said platinum group metal catalyst is palladium (Pd).
Claim 10
Dependent Claim 139 words
A process for producing a multilayered printed circuit board which comprises chemically oxidizing the surface of a copper foil constituting an outermost layer of an inner-layer board having a printed circuit formed in the copper foil, thereby to form on the surface a finely roughened layer constituted by a copper oxide of a brown to black color, laminating the thus-treated inner-layer board as an intermediate layer with other laminating materials thereby to form a multilayered board, subjecting the multilayered board to the formation of through-holes, and thereafter reducing the copper oxide constituting the finely roughened layer on the copper foil in at least those parts of the inner-layer board which are close to the through-holes, said reduction being conducted during the period between said through-hole formation and electroless plating in an atmosphere in which a reducing gas is present.
Claim 11
Dependent Claim 139 words
A process for producing a multilayered printed circuit board which comprises chemically oxidizing the surface of a copper foil constituting an outermost layer of an inner-layer board having a printed circuit formed in the copper foil, thereby to form on the surface a finely roughened layer constituted by a copper oxide of a brown to black color, laminating the thus-treated inner-layer board as an intermediate layer with other laminating materials thereby to form a multilayered board, subjecting the multilayered board to the formation of through-holes, and thereafter reducing the copper oxide constituting the finely roughened layer on the copper foil in at least those parts of the inner-layer board which are close to the through-holes, said reduction being conducted during the period between said through-hole formation and electroless plating in an atmosphere in which a reducing gas is present.
Claim 12
Dependent Claim 31 words
A process as claimed in claim 9, wherein the treatment in an atmosphere in which a reducing gas is present is conducted during the period between desmear treatment and electroless plating.
Claim 13
Dependent Claim 19 words
A process as claimed in claim 9, wherein said reducing gas is hydrogen, carbon monoxide, or a mixture thereof.
Claim 14
Dependent Claim 14 words
A process as claimed in claim 9, wherein said reducing gas is hydrazine gas.

References Cited (Backward Citations)

US4328048A Cited
JPS56153797A Cited
US4643793A Cited
EP0189913A1 Cited
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EP0402966A2 Cited

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