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US7709588B2 Active / In Force US ⏱️ 1.6 years remaining

Curable composition

Assignee: AGC Inc
•
Filing: 2008-06-26
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Granted: 2010-05-04
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Expires: 2028-06-26
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Abstract

Abstract To provide a hardly colored curable composition having an excellent storage stability while maintaining fast curing properties. A curable composition which comprises a polymer (P) having a polyoxyalkylene chain and a group of the following formula (1) and a compound (S) having a mercapto group and a group of the following formula (2), and which contains from 0.01 to 0.50 part by mass of the compound (S) per 100 parts by mass of the polymer (P): —Si(—X 1 ) 3 (1) —Si(—X 2 ) m (—Y 2 ) 3-m (2) wherein symbols have the following meanings: X 1 and X 2 : each independently a C 1-6 alkoxy group, Y 2 : a C 1-6 alkyl group, and m: 1, 2 or 3.

Inventors

  • 👤 Yuuji Kimura
  • 👤 Tatsuhiro Futami
  • 👤 Hideaki Tanaka
  • 👤 Genichirou Enna

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 12:01
CPC Classifications
C; C08; C08G; C08G65/00; C08G65/02; C08G65/32; C08G65/329; C08G65/336; C08L; C08L71/00; C08L71/02; C08K; C08K5/00; C08K5/54; C08K5/548

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 146 words
A curable composition which comprises a polymer (P) having polyoxyalkylene formed by ring-opening polymerization of a C 2-6 alkylene oxide and a group of the following formula (1), and a compound (S) having the following formula (S1), and which contains from 0.01 to 0.50 part by mass of the compound (S) per 100 parts by mass of the polymer (P): —Si(—X 1 ) 3 (1) Si(—X 2 ) m (—Y 2 ) 3-m (-Q M -SH)  (S1) wherein symbols have the following meanings: X 1 and X 2 : each independently a C 1-6 alkoxy group, Y 2 : a C 1-6 alkyl group, m: 1, 2 or 3, and Q M : a C 1-20 divalent organic group, and wherein the polymer (P) has a number average molecular weight (Mn) of from 5,000 to 30,000 and a molecular weight distribution (Mw/Mn) of at most 3.0.
Claim 2
Dependent Claim 146 words
A curable composition which comprises a polymer (P) having polyoxyalkylene formed by ring-opening polymerization of a C 2-6 alkylene oxide and a group of the following formula (1), and a compound (S) having the following formula (S1), and which contains from 0.01 to 0.50 part by mass of the compound (S) per 100 parts by mass of the polymer (P): —Si(—X 1 ) 3 (1) Si(—X 2 ) m (—Y 2 ) 3-m (-Q M -SH)  (S1) wherein symbols have the following meanings: X 1 and X 2 : each independently a C 1-6 alkoxy group, Y 2 : a C 1-6 alkyl group, m: 1, 2 or 3, and Q M : a C 1-20 divalent organic group, and wherein the polymer (P) has a number average molecular weight (Mn) of from 5,000 to 30,000 and a molecular weight distribution (Mw/Mn) of at most 3.0.
Claim 3
Dependent Claim 102 words
The curable composition according to claim 1 , wherein the polymer (P) is a polymer (P1) obtained by an urethane-forming reaction of a polymer (pP) having a polyoxyalkylene chain and a hydroxy group, with a compound (U) having a group of the following formula (1) and an isocyanate group, and in the urethane-forming reaction, the ratio of the total number of isocyanate groups in the compound (U) to the total number of hydroxy groups in the polymer (pP) is from 0.80 to 1.50: —Si(—X 1 ) 3 (1) wherein symbol has the following meaning: X 1 : a C 1-6 alkoxy group.
Claim 4
Dependent Claim 52 words
The curable composition according to claim 2 , wherein the compound (U) is a compound of the following formula (U1): Si(—X 1 ) 3 (-Q U -NCO)  (U1) wherein symbols have the following meanings: X 1 : a C 1-6 alkoxy group, and Q U : a C 1-20 divalent organic group.
Claim 5
Dependent Claim 56 words
The curable composition according to claim 1 , which further contains a compound of the following formula (V): Si(—X 3 ) n (—Y 3 ) 4-n (V) wherein symbols have the following meanings: X 3 : a C 1-6 alkoxy group, Y 3 : a C 1-6 hydrocarbon group, and n: 1, 2, 3 or 4.
Claim 6
Dependent Claim 15 words
An adhesive or sealing material using the curable composition as defined in claim 1 .
Claim 7
Dependent Claim 22 words
The curable composition according to claim 1 , wherein said ring-opening polymerization is in the presence of a double metal cyanide complex.
Claim 8
Dependent Claim 35 words
The curable composition according to claim 1 , wherein compound (S) is present in a maximum amount of 0.06 part by mass of the compound (S) per 100 parts by mass of the polymer (P).
Claim 9
Dependent Claim 160 words
A curable composition which comprises a polymer (P) having polyoxyalkylene formed by ring-opening polymerization of a C 2-6 alkylene oxide and a group of the following formula (1), a compound (S) having the following formula (S1), and an antioxidant (T), and which contains from 0.01 to 0.50 part by mass of the compound (S) and from 0.01 to 10 parts by mass of the antioxidant (T), per 100 parts by mass of the polymer (P): —Si(—X 1 ) 3 (1) Si(—X 2 ) m (—Y 2 ) 3-m (-Q m -SH)  (S1) wherein symbols have the following meanings: X 1 and X 2 : each independently a C 1-6 alkoxy group, Y 2 : a C 1-6 alkyl group, m:1, 2 or 3, and Q M : a C 1-20 divalent organic group, and wherein the polymer (P) has a number average molecular weight (Mn) of from 5,000 to 30,000 and a molecular weight distribution (Mw/Mn) of at most 3.0.
Claim 10
Dependent Claim 160 words
A curable composition which comprises a polymer (P) having polyoxyalkylene formed by ring-opening polymerization of a C 2-6 alkylene oxide and a group of the following formula (1), a compound (S) having the following formula (S1), and an antioxidant (T), and which contains from 0.01 to 0.50 part by mass of the compound (S) and from 0.01 to 10 parts by mass of the antioxidant (T), per 100 parts by mass of the polymer (P): —Si(—X 1 ) 3 (1) Si(—X 2 ) m (—Y 2 ) 3-m (-Q m -SH)  (S1) wherein symbols have the following meanings: X 1 and X 2 : each independently a C 1-6 alkoxy group, Y 2 : a C 1-6 alkyl group, m:1, 2 or 3, and Q M : a C 1-20 divalent organic group, and wherein the polymer (P) has a number average molecular weight (Mn) of from 5,000 to 30,000 and a molecular weight distribution (Mw/Mn) of at most 3.0.
Claim 11
Dependent Claim 16 words
The curable composition according to claim 8 , which has a chromaticity of less than 100.
Claim 12
Dependent Claim 22 words
The curable composition according to claim 8 , wherein said ring-opening polymerization is in the presence of a double metal cyanide complex.
Claim 13
Dependent Claim 35 words
The curable composition according to claim 8 , wherein compound (S) is present in a maximum amount of 0.06 part by mass of the compound (S) per 100 parts by mass of the polymer (P).
Claim 14
Dependent Claim 175 words
A curable composition which is a curable composition obtained by adding and mixing an antioxidant (T) to a polymer (P) having polyoxyalkylene formed by ring-opening polymerization of a C 2-6 alkylene oxide and the group of the following formula (1), and then adding and mixing a compound (S) having the following formula (S1) thereto, and which contains from 0.01 to 0.50 part by mass of the compound (S) and from 0.01 to 10 parts by mass of the antioxidant (T), per 100 parts by mass of the polymer (P): —Si(—X 1 ) 3 (1) Si(—X 2 ) m (—Y 2 ) 3-m (-Q M -SH)  (S1) wherein symbols have the following meanings: X 1 and X 2 : each independently a C 1-6 alkoxy group, Y 2 : a C 1-6 alkyl group, m: 1, 2 or 3, and Q M : a C 1-20 divalent organic group, and wherein the polymer (P) has a number average molecular weight (Mn) of from 5,000 to 30,000 and a molecular weight distribution (Mw/Mn) of at most 3.0.
Claim 15
Dependent Claim 175 words
A curable composition which is a curable composition obtained by adding and mixing an antioxidant (T) to a polymer (P) having polyoxyalkylene formed by ring-opening polymerization of a C 2-6 alkylene oxide and the group of the following formula (1), and then adding and mixing a compound (S) having the following formula (S1) thereto, and which contains from 0.01 to 0.50 part by mass of the compound (S) and from 0.01 to 10 parts by mass of the antioxidant (T), per 100 parts by mass of the polymer (P): —Si(—X 1 ) 3 (1) Si(—X 2 ) m (—Y 2 ) 3-m (-Q M -SH)  (S1) wherein symbols have the following meanings: X 1 and X 2 : each independently a C 1-6 alkoxy group, Y 2 : a C 1-6 alkyl group, m: 1, 2 or 3, and Q M : a C 1-20 divalent organic group, and wherein the polymer (P) has a number average molecular weight (Mn) of from 5,000 to 30,000 and a molecular weight distribution (Mw/Mn) of at most 3.0.
Claim 16
Dependent Claim 16 words
The curable composition according to claim 12 , which has a chromaticity of less than 100.
Claim 17
Dependent Claim 22 words
The curable composition according to claim 12 , wherein said ring-opening polymerization is in the presence of a double metal cyanide complex.
Claim 18
Dependent Claim 35 words
The curable composition according to claim 12 , wherein compound (S) is present in a maximum amount of 0.06 part by mass of the compound (S) per 100 parts by mass of the polymer (P).

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