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US6849869B1 Expired / Lapsed US ⏱️ 0.0 years remaining

Long lifetime polymer light-emitting devices with improved luminous efficiency and improved radiance

Assignee: DuPont Displays Inc
•
Filing: 2000-07-17
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Granted: 2005-02-01
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Expires: 2020-07-17
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Abstract

Abstract The luminous efficiency and radiance of light emitting diodes (LEDs) fabricated from organic emissive materials can be increased by using a multilayer cathode including a low work function layer and a high work function high reflectivity layer, in combination with a high work function, high reflectivitity anode material in the device.

Inventors

  • 👤 Marie B. O'Regan
  • 👤 Chi Zhang

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 23:31
CPC Classifications
H; H10; H10K; H10K50/00; H10K50/80; H10K50/85; H10K50/852; H10K50/10; H10K50/17; H10K50/805; H10K50/81; H10K50/82; H10K50/826

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 104 words
A light-emitting device comprising: an anode comprising a semi-transparent layer having a high reflectivity and a high work function, wherein the semi-transparent layer has a reflectivity of at least 86%; and a cathode comprising at least one first cathode layer of a low work function material selected from metal, metal oxide and combinations thereof, and at least one second cathode layer having a high reflectivity and a high work function, at least one emissive layer disposed between the anode and first cathode layer wherein the emissive layer is in contact with the first cathode layer, wherein said device is a metal etalon microcavity structure.
Claim 2
Dependent Claim 104 words
A light-emitting device comprising: an anode comprising a semi-transparent layer having a high reflectivity and a high work function, wherein the semi-transparent layer has a reflectivity of at least 86%; and a cathode comprising at least one first cathode layer of a low work function material selected from metal, metal oxide and combinations thereof, and at least one second cathode layer having a high reflectivity and a high work function, at least one emissive layer disposed between the anode and first cathode layer wherein the emissive layer is in contact with the first cathode layer, wherein said device is a metal etalon microcavity structure.
Claim 3
Dependent Claim 19 words
The device of claim 1 , wherein the semi-transparent layer has a work function of greater than 4 eV.
Claim 4
Dependent Claim 20 words
The device of claim 1 , wherein the semi-transparent layer includes an anode material selected from metals and metal alloys.
Claim 5
Dependent Claim 20 words
The device of claim 1 , wherein the second cathode layer has a work function of greater than 4 eV.
Claim 6
Dependent Claim 21 words
The device of claim 1 , wherein the second cathode layer includes a cathode material selected from metals and metal alloys.
Claim 7
Dependent Claim 21 words
The device of claim 1 wherein the semi-transparent layer has a reflectivity of at least 91.4% at the wavelength of emission.
Claim 8
Dependent Claim 22 words
The device of claim 1 wherein the semi-transparent layer has a reflectivity of more than about 92% at the wavelength of emission.
Claim 9
Dependent Claim 22 words
The device of claim 1 wherein the semi-transparent layer has a reflectivity of from 92 to 96.5% at the wavelength of emission.
Claim 10
Dependent Claim 22 words
The device of claim 1 wherein the semi-transparent layer has a reflectivity of from 94 to 96.5% at the wavelength of emission.
Claim 11
Dependent Claim 22 words
The device of claim 1 wherein the semi-transparent layer has a reflectivity of more than about 96% at the wavelength of emission.
Claim 12
Dependent Claim 11 words
The device of claim 1 wherein the semi-transparent layer comprises silver.
Claim 13
Dependent Claim 15 words
The device of claim 1 wherein the at least one second cathode layer comprises silver.
Claim 14
Dependent Claim 24 words
The device of claim 1 wherein the at least one second cathode layer has reflectivity of at least 91.4% at the wavelength of emission.
Claim 15
Dependent Claim 26 words
The device of claim 1 wherein the at least one second cathode layer has reflectivity of between about 92 and 96.5% at the wavelength of emission.
Claim 16
Dependent Claim 27 words
The device of claim 1 wherein the at least one second cathode layer has reflectivity of between about 94 to 96.5 % at the wavelength of emission.
Claim 17
Dependent Claim 25 words
The device of claim 1 wherein the at least one second cathode layer has reflectivity of greater than about 96% at the wavelength of emission.
Claim 18
Dependent Claim 24 words
The device of claim 1 wherein the at least one second cathode layer includes a layer of air-stable metal coated on a silver layer.
Claim 19
Dependent Claim 50 words
The device of claim 1 wherein: the semi-transparent layer has a first surface adjacent to the cathode and an opposite second surface; the anode further comprising a passivation layer adjacent to the first surface, the passivation layer comprising a passivation material selected from poly(aniline), poly(aniline) blends, polythiophene, and polythiophene blends.
Claim 20
Dependent Claim 20 words
The device of claim 1 wherein the semi-transparent layer has a thickness of from about 100 up to 500 Å.
Claim 21
Dependent Claim 20 words
The device of claim 1 wherein the semi-transparent layer has a thickness of from about 250 up to 400 Å.
Claim 22
Dependent Claim 20 words
The device of claim 1 wherein the semi-transparent layer has a thickness of from about 275 up to 350 Å.
Claim 23
Dependent Claim 20 words
The device of claim 1 wherein the semi-transparent layer has a thickness of from about 275 up to 325 Å.
Claim 24
Dependent Claim 42 words
The device of claim 1 , wherein: the semi-transparent layer has a first surface adjacent to the cathode and an opposite second surface; the anode further comprises a transparent layer of indium/tin oxide adjacent to the second surface of the semi-transparent layer.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2008-02-01 2008-08-02 2009-02-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2012-02-01 2012-08-02 2013-02-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2016-02-01 2016-08-02 2017-02-01 $7700.00 Window Closed / Lapsed

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