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US6727592B1 Expired / Lapsed US ⏱️ 0.0 years remaining

Copper interconnect with improved barrier layer

Assignee: Advanced Micro Devices Inc
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Filing: 2002-02-22
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Granted: 2004-04-27
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Expires: 2022-02-22
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Abstract

Abstract A Cu interconnect, e.g.; a dual damascene structure, is formed with improved electromigration resistance and increased via chain yield by depositing a barrier layer in an opening by CVD, depositing a flash layer of α-Ta by PVD, at a thickness less than 30 Å, on the bottom of the barrier layer, depositing a seedlayer and then filling the opening with Cu. Embodiments include depositing a thin α-Ta layer, as at a thickness less than 10 Å, and/or as discontinuous regions of clusters of atoms on sides of the opening.

Inventors

  • 👤 Christy Mei-Chu Woo
  • 👤 John E. Sanchez
  • 👤 Darrell M. Erb
  • 👤 Amit P. Marathe

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 02:24
CPC Classifications
H; H10; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/032; H10W20/033; H10W20/035; H10W20/041; H10W20/042; H10W20/40; H10W20/41; H10W20/425

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 100 words
A semiconductor device comprising: an opening formed in a dielectric layer; a barrier layer lining the opening, the barrier layer comprising a bottom portion and side portions; a layer of tantalum (Ta), deposited by physical vapor deposition and having a thickness less than 30 Å, on the bottom portion of the barrier layer; discontinuous regions of clusters of Ta atoms on the side portions of the barrier layer; a seedlayer on the layer of Ta and over the side portions of the barrier layer and the clusters of Ta atoms; and copper (Cu) or a Cu alloy filling the opening.
Claim 2
Dependent Claim 100 words
A semiconductor device comprising: an opening formed in a dielectric layer; a barrier layer lining the opening, the barrier layer comprising a bottom portion and side portions; a layer of tantalum (Ta), deposited by physical vapor deposition and having a thickness less than 30 Å, on the bottom portion of the barrier layer; discontinuous regions of clusters of Ta atoms on the side portions of the barrier layer; a seedlayer on the layer of Ta and over the side portions of the barrier layer and the clusters of Ta atoms; and copper (Cu) or a Cu alloy filling the opening.
Claim 3
Dependent Claim 50 words
The semiconductor device according to claim 1 , wherein the barrier layer comprises a material selected from the group consisting of tantalum nitride, titanium silicon nitride, tungsten nitride, titanium, titanium-tungsten, tungsten, titanium-titanium nitride, tungsten silicon nitride, tantalum silicon nitride silicon nitride and titanium nitride with a layer of silicon thereon.
Claim 4
Dependent Claim 16 words
The semiconductor device according to claim 1 , wherein the layer of Ta comprises alpha (2)-Ta.
Claim 5
Dependent Claim 37 words
The semiconductor device according to claim 1 , wherein the opening is a dual damascene opening and the filled opening comprises an upper Cu or Cu alloy line connected to a lower Cu or Cu alloy via.
Claim 6
Dependent Claim 25 words
The semiconductor device according to claim 1 , wherein the layer of Ta layer has a thickness of about 5 Å to about 30 Å.
Claim 7
Dependent Claim 24 words
The semiconductor device according to claim 5 , wherein the layer of Ta has a thickness of about 8 Å to about 24 Å.
Claim 8
Dependent Claim 101 words
A semiconductor device comprising: an opening formed in a dielectric layer; a barrier layer lining the opening, the barrier layer comprising a bottom portion and side portions; a first layer of tantalum (Ta) deposited by physical vapor deposition and having a thickness less than 30 Å, on the bottom portion of the barrier layer; a discontinuous second layer of Ta, having a thickness less than 10 Å, on the side portions of the barrier layer; a seedlayer on the first layer of Ta and in direct contact with the barrier layer; and copper (Cu) or a Cu alloy filling the opening.
Claim 9
Dependent Claim 101 words
A semiconductor device comprising: an opening formed in a dielectric layer; a barrier layer lining the opening, the barrier layer comprising a bottom portion and side portions; a first layer of tantalum (Ta) deposited by physical vapor deposition and having a thickness less than 30 Å, on the bottom portion of the barrier layer; a discontinuous second layer of Ta, having a thickness less than 10 Å, on the side portions of the barrier layer; a seedlayer on the first layer of Ta and in direct contact with the barrier layer; and copper (Cu) or a Cu alloy filling the opening.
Claim 10
Dependent Claim 31 words
The semiconductor device according to claim 7 , wherein the discontinuous second layer of Ta on the side portions of the barrier layer has a thickness less than about 3 Å.
Claim 11
Independent Claim 114 words
A method of manufacturing a semiconductor device, the method comprising: forming an opening in a dielectric layer; depositing a barrier layer by chemical vapor deposition or atomic layer deposition lining the opening, the barrier layer comprising a bottom portion and side portions; depositing a layer of tantalum (Ta) by physical vapor deposition, at a thickness less than 30 Å, on the bottom portion of the barrier layer; depositing discontinuous regions of clusters of Ta atoms by physical vapor deposition on side portions of the barrier layer; depositing a seedlayer on the layer of Ta and over the side portions of the barrier layer; and filling the opening with copper (Cu) or a Cu alloy.
Claim 12
Independent Claim 114 words
A method of manufacturing a semiconductor device, the method comprising: forming an opening in a dielectric layer; depositing a barrier layer by chemical vapor deposition or atomic layer deposition lining the opening, the barrier layer comprising a bottom portion and side portions; depositing a layer of tantalum (Ta) by physical vapor deposition, at a thickness less than 30 Å, on the bottom portion of the barrier layer; depositing discontinuous regions of clusters of Ta atoms by physical vapor deposition on side portions of the barrier layer; depositing a seedlayer on the layer of Ta and over the side portions of the barrier layer; and filling the opening with copper (Cu) or a Cu alloy.
Claim 13
Dependent Claim 44 words
The method according to claim 9 , comprising depositing the barrier layer of a material selected from a group consisting of tantalum nitride, titanium nitride, titanium, titanium-tungsten, tungsten, tungsten nitride, titanium-titanium nitride, titanium silicon nitride, tungsten silicon nitride, tantalum silicon nitride and silicon nitride.
Claim 14
Dependent Claim 24 words
The method according to claim 9 , comprising a depositing a layer of alpha (2)-Ta as the layer of Ta by physical vapor deposition.
Claim 15
Dependent Claim 42 words
The method according to claim 9 , comprising: forming the opening as a dual damascene opening; and filling the opening with the Cu or Cu alloy to form a Cu or Cu alloy line connected to a Cu or Cu alloy via.
Claim 16
Dependent Claim 24 words
The method according to claim 9 , comprising depositing the layer of Ta at a thickness of about 5 Å to about 30 Å.
Claim 17
Dependent Claim 24 words
The method according to claim 13 , comprising depositing the layer of Ta at a thickness of about 8 Å to about 24 Å.
Claim 18
Independent Claim 119 words
A method of manufacturing a semiconductor device, the method comprising: forming an opening in a dielectric layer: depositing a barrier layer by chemical vapor deposition or atomic layer deposition lining the opening, the barrier layer comprising a bottom portion and side portions; depositing a first layer of tantalum (Ta) by physical vapor deposition at a thickness less than 30 Å, on the bottom portion of the barrier layer; depositing a discontinuous second layer of Ta on the side portions of the barrier layer at a thickness less than about 10 Å; depositing a seedlayer on the first layer of Ta and in direct contact with the barrier layer; and filling the opening with copper (Cu) or a Cu alloy.
Claim 19
Independent Claim 119 words
A method of manufacturing a semiconductor device, the method comprising: forming an opening in a dielectric layer: depositing a barrier layer by chemical vapor deposition or atomic layer deposition lining the opening, the barrier layer comprising a bottom portion and side portions; depositing a first layer of tantalum (Ta) by physical vapor deposition at a thickness less than 30 Å, on the bottom portion of the barrier layer; depositing a discontinuous second layer of Ta on the side portions of the barrier layer at a thickness less than about 10 Å; depositing a seedlayer on the first layer of Ta and in direct contact with the barrier layer; and filling the opening with copper (Cu) or a Cu alloy.
Claim 20
Dependent Claim 30 words
The method according to claim 15 , comprising depositing the discontinuous second layer of Ta on side portions of the barrier layer at a thickness less than about 3 Å.

References Cited (Backward Citations)

US6291885B1 Cited
US6221757B1 Cited
US6342448B1 Cited
US6562715B1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2007-04-27 2007-10-27 2008-04-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2011-04-27 2011-10-27 2012-04-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2015-04-27 2015-10-27 2016-04-27 $7700.00 Window Closed / Lapsed

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