Patent US3790435A successfully refreshed from Google Patents.
Patent US6503307B1 successfully refreshed from Google Patents.
US6503307B1
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Ink set, printing method, ink, printed article, printing apparatus, ink cartridge, recording unit, and process of forming polymeric compound films
Assignee: Canon Inc
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Filing: 2000-04-26
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Granted: 2003-01-07
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Expires: 2020-04-26
Abstract
Abstract An ink set is provided which produces a printed article having excellent water resistance and excellent abrasion resistance. The ink set comprises a first liquid composition containing a first water-soluble compound having in the molecule an ethylenically unsaturated double bond having an electron-attractive substituent on the α-position, and a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence, at least one of the first liquid composition and the second liquid composition further containing a coloring material.
Inventors
- 👤 Hiromichi Noguchi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 13:49
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30; C09D11/40; C09D11/54
Claims Analysis
Total Claims: 97
Claim 1
Independent Claim
73 words
A set of liquid compositions, comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, and a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence; at least one of the first liquid composition and the second liquid composition further containing a coloring material.
Claim 2
Dependent Claim
73 words
A set of liquid compositions, comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, and a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence; at least one of the first liquid composition and the second liquid composition further containing a coloring material.
Claim 3
Dependent Claim
26 words
The set of liquid compositions according to claim 1 , wherein the second compound has two or more active hydrogen atoms addable to the first compound.
Claim 4
Dependent Claim
33 words
The set of liquid compositions according to claim 1 , wherein the second compound has two or more amino groups selected from the group consisting of primary amino groups and secondary amino groups.
Claim 5
Dependent Claim
47 words
The set of liquid compositions according to claim 1 , wherein the first liquid composition is a black ink, and the second liquid composition is a liquid having a color tone not substantially affecting the color tone of a printed article obtained with the first liquid composition.
Claim 6
Dependent Claim
44 words
The set of liquid compositions according to claim 1 , wherein the second liquid composition is a black ink, and the first liquid composition has a color tone not substantially affecting the color tone of a printed article obtained with the second liquid composition.
Claim 7
Dependent Claim
25 words
The set of liquid compositions according to claim 1 , wherein the first liquid composition and the second liquid composition are respectively a black ink.
Claim 8
Dependent Claim
33 words
The set of liquid compositions according to claim 1 , wherein one of the first liquid composition and the second liquid composition is a color ink, and the other is a black ink.
Claim 9
Dependent Claim
47 words
The set of liquid compositions according to claim 1 , wherein the first liquid composition is a color ink, and the second liquid composition is a liquid having a color tone not substantially affecting the color tone of a printed article obtained with the first liquid composition.
Claim 10
Dependent Claim
47 words
The set of liquid compositions according to claim 1 , wherein the second liquid composition is a color ink, and the first liquid composition is a liquid having a color tone not substantially affecting the color tone of a printed article obtained with the second liquid composition.
Claim 11
Dependent Claim
36 words
The set of liquid compositions according to any one of claims 6 to 9 , wherein the color ink is at least one selected from the group consisting of yellow inks, cyan inks, and magenta inks.
Claim 12
Dependent Claim
25 words
The set of liquid compositions according to claim 1 , wherein the first liquid composition and the second liquid composition are respectively a color ink.
Claim 13
Dependent Claim
36 words
The set of liquid compositions according to claim 11 , wherein the color of the first liquid composition as the color ink is different from the color of the second liquid composition as the color ink.
Claim 14
Dependent Claim
34 words
The set of liquid compositions according to claim 12 , wherein the color inks are at least two color inks having respectively a color selected from the group consisting of yellow, cyan, and magenta.
Claim 15
Dependent Claim
267 words
The set of liquid compositions according to claim 1 , wherein the first compound is at least one selected from the group consisting of compounds represented by Formulas A-1 to A-12, and the second compound is at least one selected from the group consisting of compounds represented by Formulas B-1 to B-17: where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where x, y and z are respectively an integer in the range of x=10-100, y=3-25, and z=5-25 where x and y are respectively an integer in the range of x=10-25, and y=3-15 where n+m+k is in the range of 0-25 NH 2 —R 1 —OCH 2 CH 2 O n R 1 —NH 2 B-2 where n is in the range of 3-25, and R 1 is an alkyl of 1-3 carbons where n is in the range of 7-1000 where n is in the range of 3-25 where x+y+z is in the range of 1-15 HS—CH 2 CH 2 —SH B-11 HS—CH 2 CH 2 OCH 2 CH 2 —SH B-12 HS—CH 2 CH 2 OCH 2 CH 2 —OCH 2 CH 2 —SH B-13 HSCH 2 CH 2 O n CH 2 CH 2 —SH B-14 where n is in the range of 3-16 HS—CH 2 CH 2 CH 2 CH 2 —SH B-15 HS—CH 2 CH 2 CH 2 CH 2 CH 2 —SH B-16 HS—CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 —SH. B-17
Claim 16
Dependent Claim
64 words
A set of liquid compositions and an ink, comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence, and an ink containing a coloring material.
Claim 17
Dependent Claim
64 words
A set of liquid compositions and an ink, comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence, and an ink containing a coloring material.
Claim 18
Dependent Claim
20 words
The set of liquid compositions and an ink according to claim 15 , wherein the ink is a black ink.
Claim 19
Dependent Claim
20 words
The set of liquid compositions and an ink according to claim 15 , wherein the ink is a color ink.
Claim 20
Dependent Claim
34 words
The set of liquid compositions and an ink according to claim 17 , wherein the color ink is at least one selected from the group consisting of yellow inks, cyan inks, and magenta inks.
Claim 21
Dependent Claim
46 words
The set of liquid compositions and an ink according to any one of claims 15 to 18 wherein the first liquid composition and the second liquid composition respectively have a color tone not substantially affecting the color tone of a printed article obtained with the ink.
Claim 22
Dependent Claim
29 words
The set of liquid compositions and an ink according to claim 15 , wherein the second compound has two or more active hydrogen atoms addable to the first compound.
Claim 23
Dependent Claim
36 words
The set of liquid compositions and an ink according to claim 20 , wherein the second compound has two or more amino groups selected from the group consisting of primary amino groups and secondary amino groups.
Claim 24
Dependent Claim
270 words
The set of liquid compositions and an ink according to claim 15 , wherein the first compound is at least one selected from the group consisting of compounds represented by Formulas A-1 to A-12, and the second compound is at least one selected from the group consisting of compounds represented by Formulas B-1 to B-17: where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where x, y and z are respectively an integer in the range of x=10-100, y=3-25, and z=5-25 where x and y are respectively an integer in the range of x=10-25, and y=3-15 where n+m+k is in the range of 0-25 NH 2 —R 1 —OCH 2 CH 2 O n R 1 —NH 2 B-2 where n is in the range of 3-25, and R 1 is an alkyl of 1-3 carbons where n is in the range of 7-1000 where n is in the range of 3-25 where x+y+z is in the range of 1-15 HS—CH 2 CH 2 —SH B-11 HS—CH 2 CH 2 OCH 2 CH 2 —SH B-12 HS—CH 2 CH 2 OCH 2 CH 2 —OCH 2 CH 2 —SH B-13 HSCH 2 CH 2 O n CH 2 CH 2 —SH B-14 where n is in the range of 3-16 HS—CH 2 CH 2 CH 2 CH 2 —SH B-15 HS—CH 2 CH 2 CH 2 CH 2 CH 2 —SH B-16 HS—CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 —SH. B-17
Claim 25
Dependent Claim
114 words
A printing method comprising the steps of (i) providing a set of liquid compositions comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, and a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence, at least one of the first liquid composition and the second liquid composition further containing a coloring material; and (ii) applying the first liquid composition and the second liquid composition respectively on a recording medium to cause mixing or contact of the first liquid composition and the second liquid composition.
Claim 26
Dependent Claim
114 words
A printing method comprising the steps of (i) providing a set of liquid compositions comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, and a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence, at least one of the first liquid composition and the second liquid composition further containing a coloring material; and (ii) applying the first liquid composition and the second liquid composition respectively on a recording medium to cause mixing or contact of the first liquid composition and the second liquid composition.
Claim 27
Dependent Claim
35 words
The printing method according to claim 23 , wherein, in step (ii), at least one of the first liquid composition and the second liquid composition is applied by an ink-jet system onto a recording medium.
Claim 28
Dependent Claim
45 words
The printing method according to claim 23 , wherein the first liquid composition is a black ink, and the second liquid composition is a liquid having a color tone not substantially affecting the color tone of a printed article obtained with the first liquid composition.
Claim 29
Dependent Claim
45 words
The printing method according to claim 23 , wherein the second liquid composition is a black ink, and the first liquid composition is a liquid having a color tone not substantially affecting the color tone of a printed article obtained with the second liquid composition.
Claim 30
Dependent Claim
21 words
The printing method according to claim 23 , wherein the first liquid composition and the second liquid composition are black inks.
Claim 31
Dependent Claim
26 words
The printing method according to claim 23 , wherein the first liquid composition is a black ink and the second liquid composition is a color ink.
Claim 32
Dependent Claim
26 words
The printing method according to claim 23 , wherein the first liquid composition is a color ink and the second liquid composition is a black ink.
Claim 33
Dependent Claim
45 words
The printing method according to claim 23 , wherein the first liquid composition is a color ink, and the second liquid composition is a liquid having a color tone not substantially affecting the color tone of a printed article obtained with the first liquid composition.
Claim 34
Dependent Claim
45 words
The printing method according to claim 23 , wherein the second liquid composition is a color ink, and the first liquid composition is a liquid having a color tone not substantially affecting the color tone of a printed article obtained with the second liquid composition.
Claim 35
Dependent Claim
33 words
The printing method according to any of claims 28 to 31 , wherein the color ink is at least one selected from the group consisting of yellow inks, cyan inks, and magenta inks.
Claim 36
Dependent Claim
23 words
The printing method according to claim 23 , wherein the first liquid composition and the second liquid composition are respectively a color ink.
Claim 37
Dependent Claim
34 words
The printing method according to claim 33 , wherein the color of the first liquid composition as the color ink is different from the color of the second liquid composition as the color ink.
Claim 38
Dependent Claim
32 words
The printing method according to claim 34 , wherein the color inks are at least two color inks having respectively a color selected from the group consisting of yellow, cyan, and magenta.
Claim 39
Dependent Claim
135 words
A printing method comprising the steps of (i) providing a set of liquid compositions and an ink comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence, and an ink containing a coloring material; (ii) applying the first liquid composition and the second liquid composition respectively on a recording medium to cause mixing or contact of the first liquid composition and the second liquid composition; and (iii) applying the ink onto the recording medium to cause mixing or contact of the ink with at least one of the first liquid composition or the second liquid composition.
Claim 40
Dependent Claim
135 words
A printing method comprising the steps of (i) providing a set of liquid compositions and an ink comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence, and an ink containing a coloring material; (ii) applying the first liquid composition and the second liquid composition respectively on a recording medium to cause mixing or contact of the first liquid composition and the second liquid composition; and (iii) applying the ink onto the recording medium to cause mixing or contact of the ink with at least one of the first liquid composition or the second liquid composition.
Claim 41
Dependent Claim
35 words
The printing method according to claim 36 , wherein, in step (ii), at least one of the first liquid composition and the second liquid composition is applied by an ink-jet system onto a recording medium.
Claim 42
Dependent Claim
24 words
The printing method according to claim 36 , wherein, in step (iii), the ink is applied by an ink-jet system onto a recording medium.
Claim 43
Dependent Claim
15 words
The printing method according to claim 36 , wherein the ink is a black ink.
Claim 44
Dependent Claim
15 words
The printing method according to claim 36 , wherein the ink is a color ink.
Claim 45
Dependent Claim
19 words
The printing method according to claim 36 , wherein the ink includes separate plural inks having different color tones.
Claim 46
Dependent Claim
24 words
The printing method according to claim 41 , wherein the plural inks having different color tones are a black ink and a color ink.
Claim 47
Dependent Claim
19 words
The printing method according to claim 41 , wherein the plural inks having different color tones are color inks.
Claim 48
Dependent Claim
30 words
The printing method according to claim 42 or 43 wherein the color ink is at least one selected from the group consisting of yellow inks, cyan inks, and magenta inks.
Claim 49
Dependent Claim
40 words
The printing method according to claim 36 , wherein the first liquid composition and the second liquid composition are respectively a liquid having a color tone not substantially affecting the color tone of a printed article obtained with the ink.
Claim 50
Dependent Claim
27 words
The printing method according to claim 23 or 36 , wherein the second compound has two or more active hydrogen a toms addable to the first compound.
Claim 51
Dependent Claim
31 words
The printing method according to claim 46 , wherein the second compound has two or more amino groups selected from the group consisting of primary amino groups and secondary amino groups.
Claim 52
Dependent Claim
266 words
The printing method according to claim 23 or 36 , wherein the first compound is at least one selected from the group consisting of compounds represented by Formulas A-1 to A-12, and the second compound is at least one selected from the group consisting of compounds represented by Formulas B-1 to B-17: where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where x, y and z are respectively an integer in the range of x=10-100, y=3-25, and z=5-25 where x and y are respectively an integer in the range of x=10-25, y=3-15 where n+m+k is in the range of 0-25 NH 2 —R 1 —OCH 2 CH 2 O n R 1 —NH 2 B-2 where n is in the range of 3-25, and R 1 is an alkyl of 1-3 carbons where n is in the range of 7-1000 where n is in the range of 3-25 where x+y+z is in the range of 1-15 HS—CH 2 CH 2 —SH B-11 HS—CH 2 CH 2 OCH 2 CH 2 —SH B-12 HS—CH 2 CH 2 OCH 2 CH 2 —OCH 2 CH 2 —SH B-13 HSCH 2 CH 2 O n CH 2 CH 2 —SH B-14 where n is in the range of 3-16 HS—CH 2 CH 2 CH 2 CH 2 —SH B-15 HS—CH 2 CH 2 CH 2 CH 2 CH 2 —SH B-16 HS—CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 —SH. B-17
Claim 53
Dependent Claim
94 words
An ink, containing, in an aqueous medium, at least one compound selected from the group consisting of compounds represented by Formulas A-1 to A-12, and a coloring material: where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C (═O)—O, and X is H or CH 3 where x, y and z are respectively an integer in the range of x=10-100, y=3-25, and z=5-25 where x and y are respectively an integer in the range of x=10-25, and y=3-15
Claim 54
Dependent Claim
94 words
An ink, containing, in an aqueous medium, at least one compound selected from the group consisting of compounds represented by Formulas A-1 to A-12, and a coloring material: where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C (═O)—O, and X is H or CH 3 where x, y and z are respectively an integer in the range of x=10-100, y=3-25, and z=5-25 where x and y are respectively an integer in the range of x=10-25, and y=3-15
Claim 55
Dependent Claim
76 words
An ink, containing, in an aqueous medium, at least one compound selected from the group consisting of compounds represented by Formulas B-1 to B-3, and a coloring material: where n+m+k is in the range of 0-25 NH 2 —R 1 —OCH 2 CH 2 O n R 1 —NH 2 B-2 where n is in the range of 3-25, and R 1 is an alkyl of 1-3 carbons where n is in the range of 7-1000.
Claim 56
Dependent Claim
76 words
An ink, containing, in an aqueous medium, at least one compound selected from the group consisting of compounds represented by Formulas B-1 to B-3, and a coloring material: where n+m+k is in the range of 0-25 NH 2 —R 1 —OCH 2 CH 2 O n R 1 —NH 2 B-2 where n is in the range of 3-25, and R 1 is an alkyl of 1-3 carbons where n is in the range of 7-1000.
Claim 57
Dependent Claim
82 words
A printed article having a colored on containing a coloring material on a recording medium, the colored portion further containing a reaction product of a first liquid composition and a second liquid composition; the first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, and the second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence.
Claim 58
Dependent Claim
82 words
A printed article having a colored on containing a coloring material on a recording medium, the colored portion further containing a reaction product of a first liquid composition and a second liquid composition; the first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, and the second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence.
Claim 59
Dependent Claim
26 words
The printed article according to claim 51 , wherein at least one of the first liquid composition and the second liquid composition contains the coloring material.
Claim 60
Dependent Claim
37 words
The printed article according to claim 52 , wherein the colored portion is formed by applying at least one of the first liquid composition and the second liquid composition by an ink-jet system onto the recording medium.
Claim 61
Dependent Claim
39 words
The printed article according to claim 51 , wherein the colored portion is formed by applying at least one of the first liquid composition, the second liquid composition, and an ink by an ink-jet system onto the recording medium.
Claim 62
Dependent Claim
122 words
A printing apparatus, comprising a set of liquid compositions comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, and a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence, at least one of the first liquid composition and the second liquid composition further containing a coloring material; an ejecting means for ejecting the first liquid composition and the second liquid composition separately onto a recording medium; and a controlling means to bring the first liquid composition and the second liquid composition into contact together in a liquid state on the recording medium.
Claim 63
Dependent Claim
122 words
A printing apparatus, comprising a set of liquid compositions comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, and a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence, at least one of the first liquid composition and the second liquid composition further containing a coloring material; an ejecting means for ejecting the first liquid composition and the second liquid composition separately onto a recording medium; and a controlling means to bring the first liquid composition and the second liquid composition into contact together in a liquid state on the recording medium.
Claim 64
Dependent Claim
118 words
A printing apparatus comprising a set of liquid compositions and an ink comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, a second liquid composition containing a second water soluble compound having an active hydrogen atom addable to the first compound in coexistence, and an ink containing a coloring material; an ejecting means for ejecting the first liquid composition, the second liquid composition, and the ink separately onto a recording medium; and a controlling means to bring the first liquid composition, the second liquid composition, and the ink into contact together in a liquid state on the recording medium.
Claim 65
Dependent Claim
118 words
A printing apparatus comprising a set of liquid compositions and an ink comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, a second liquid composition containing a second water soluble compound having an active hydrogen atom addable to the first compound in coexistence, and an ink containing a coloring material; an ejecting means for ejecting the first liquid composition, the second liquid composition, and the ink separately onto a recording medium; and a controlling means to bring the first liquid composition, the second liquid composition, and the ink into contact together in a liquid state on the recording medium.
Claim 66
Dependent Claim
105 words
A liquid cartridge, comprising a first liquid container holding a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, and a second liquid container holding a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence; at least one of the first liquid composition and the second liquid composition further containing a coloring material; the ink cartridge being mountable to and demountable from an ink-jet head for ejecting the first liquid composition and the second liquid composition separately.
Claim 67
Dependent Claim
105 words
A liquid cartridge, comprising a first liquid container holding a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, and a second liquid container holding a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence; at least one of the first liquid composition and the second liquid composition further containing a coloring material; the ink cartridge being mountable to and demountable from an ink-jet head for ejecting the first liquid composition and the second liquid composition separately.
Claim 68
Dependent Claim
99 words
A liquid cartridge, comprising a first liquid container holding a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, a second liquid container holding a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence, and an ink container holding an ink containing a coloring material; the ink cartridge being mountable to and demountable from an ink-jet head for ejecting the first liquid composition, the second liquid composition, and the ink separately.
Claim 69
Dependent Claim
99 words
A liquid cartridge, comprising a first liquid container holding a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, a second liquid container holding a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence, and an ink container holding an ink containing a coloring material; the ink cartridge being mountable to and demountable from an ink-jet head for ejecting the first liquid composition, the second liquid composition, and the ink separately.
Claim 70
Dependent Claim
113 words
A recording unit, comprising a first liquid container holding a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, a first ink-jet head for ejecting the first liquid composition held in the first liquid container, a second liquid container holding a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence, and a second ink-jet head for ejecting the second liquid composition held in the second liquid container; at least one of the first liquid composition and the second liquid composition further containing a coloring material.
Claim 71
Dependent Claim
113 words
A recording unit, comprising a first liquid container holding a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, a first ink-jet head for ejecting the first liquid composition held in the first liquid container, a second liquid container holding a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence, and a second ink-jet head for ejecting the second liquid composition held in the second liquid container; at least one of the first liquid composition and the second liquid composition further containing a coloring material.
Claim 72
Dependent Claim
117 words
A recording unit, comprising a first liquid container holding a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, a first ink-jet head for ejecting the first liquid composition held in the first liquid container, a second liquid container holding a second liquid composition containing a second compound having an active hydrogen atom addable to the first compound in coexistence, a second ink-jet head for ejecting the second liquid composition held in the second liquid container, an ink container holding an ink containing a coloring material, and a third ink-jet head for ejecting the ink held in the ink container.
Claim 73
Dependent Claim
117 words
A recording unit, comprising a first liquid container holding a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, a first ink-jet head for ejecting the first liquid composition held in the first liquid container, a second liquid container holding a second liquid composition containing a second compound having an active hydrogen atom addable to the first compound in coexistence, a second ink-jet head for ejecting the second liquid composition held in the second liquid container, an ink container holding an ink containing a coloring material, and a third ink-jet head for ejecting the ink held in the ink container.
Claim 74
Dependent Claim
55 words
A set of liquid compositions, comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, and a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence.
Claim 75
Dependent Claim
55 words
A set of liquid compositions, comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, and a second liquid composition containing a second water-soluble compound having an active hydrogen atom addable to the first compound in coexistence.
Claim 76
Dependent Claim
26 words
The set of liquid compositions according to claim 61 , wherein the second compound has two or more active hydrogen atoms addable to the first compound.
Claim 77
Dependent Claim
33 words
The set of liquid compositions according to claim 62 , wherein the second compound has two or more amino groups selected from the group consisting of primary amino groups and secondary amino groups.
Claim 78
Dependent Claim
267 words
The set of liquid compositions according to claim 61 , wherein the first compound is at least one selected from the group consisting of compounds represented by Formulas A-1 to A-12, and the second compound is at least one selected from the group consisting of compounds represented by Formulas B-1 to B-17: where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where x, y and z are respectively an integer in the range of x=10-100, y=3-25, and z=5-25 where x and y are respectively an integer in the range of x=10-25, and y=3-15 where n+m+k is in the range of 0-25 NH 2 —R 1 —OCH 2 CH 2 O n R 1 —NH 2 B-2 where n is in the range of 3-25, and R 1 is an alkyl of 1-3 carbons where n is in the range of 7-1000 where n is in the range of 3-25 where x+y+z is in the range of 1-15 HS—CH 2 CH 2 —SH B-11 HS—CH 2 CH 2 OCH 2 CH 2 —SH B-12 HS—CH 2 CH 2 OCH 2 CH 2 —OCH 2 CH 2 —SH B-13 HSCH 2 CH 2 O n CH 2 CH 2 —SH B-14 where n is in the range of 3-16 HS—CH 2 CH 2 CH 2 CH 2 —SH B-15 HS—CH 2 CH 2 CH 2 CH 2 CH 2 —SH B-16 HS—CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 —SH. B-17
Claim 79
Independent Claim
112 words
A method of forming a polymeric compound film, comprising the steps of (i) providing a set of liquid compositions comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, a second liquid composition containing a second water soluble compound having an active hydrogen atom addable to the first compound in coexistence; and (ii) applying the first liquid composition and the second liquid composition respectively on a recording medium to cause mixing or contact of the first liquid composition and the second liquid composition to cause reaction of the first compound and the second compound.
Claim 80
Independent Claim
112 words
A method of forming a polymeric compound film, comprising the steps of (i) providing a set of liquid compositions comprising a first liquid composition containing a first water-soluble compound having in the molecule two or more ethylenically unsaturated double bonds having an electron-attractive substituent on the α-position, a second liquid composition containing a second water soluble compound having an active hydrogen atom addable to the first compound in coexistence; and (ii) applying the first liquid composition and the second liquid composition respectively on a recording medium to cause mixing or contact of the first liquid composition and the second liquid composition to cause reaction of the first compound and the second compound.
Claim 81
Dependent Claim
34 words
The method according to claim 65 , wherein, in step (ii), at least one of the first liquid composition and the second liquid composition is applied by an ink-jet system onto a recording medium.
Claim 82
Dependent Claim
23 words
The method according to claim 65 , wherein the second compound has two or more active hydrogen atoms addable to the first compound.
Claim 83
Dependent Claim
30 words
The method according to claim 67 , wherein the second compound has two or more amino groups selected from the group consisting of primary amino groups and secondary amino groups.
Claim 84
Dependent Claim
264 words
The method according to claim 65 , wherein the first compound is at least one selected from the group consisting of compounds represented by Formulas A-1 to A-12, and the second compound is at least one selected from the group consisting of compounds represented by Formulas B-1 to B-17: where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where x, y and z are respectively an integer in the range of x=10-100, y=3-25, and z=5-25 where x and y are respectively an integer in the range of x=10-25, and y=3-15 where n+m+k is in the range of 0-25 NH 2 —R 1 —OCH 2 CH 2 O n R 1 —NH 2 B-2 where n is in the range of 3-25, and R 1 is an alkyl of 1-3 carbons where n is in the range of 7-1000 where n is in the range of 3-25 where x+y+z is in the range of 1-15 HS—CH 2 CH 2 —SH B-11 HS—CH 2 CH 2 OCH 2 CH 2 —SH B-12 HS—CH 2 CH 2 OCH 2 CH 2 —OCH 2 CH 2 —SH B-13 HSCH 2 CH 2 O n CH 2 CH 2 —SH B-14 where n is in the range of 3-16 HS—CH 2 CH 2 CH 2 CH 2 —SH B-15 HS—CH 2 CH 2 CH 2 CH 2 CH 2 —SH B-16 HS—CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 —SH. B-17
Claim 85
Dependent Claim
89 words
A liquid composition, containing, in an aqueous medium, at least one compound selected from the group consisting of the compounds represented by Formulas A-1 to A-12 below where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where x, y and z are respectively a range of x=10-100, y=3-25, and z=5-25 where x and y are respectively an integer in the range of x=10-25, and y=3-15
Claim 86
Dependent Claim
89 words
A liquid composition, containing, in an aqueous medium, at least one compound selected from the group consisting of the compounds represented by Formulas A-1 to A-12 below where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where A is CH═C(X)—C(═O)—O, and X is H or CH 3 where x, y and z are respectively a range of x=10-100, y=3-25, and z=5-25 where x and y are respectively an integer in the range of x=10-25, and y=3-15
Claim 87
Dependent Claim
75 words
A liquid composition, containing, in an aqueous medium, at least one compound selected from the group consisting of the compounds represented by Formulas B-1 to B-3 below: where n+m+k is in the range of 0-25 NH 2 —R 1 —OCH 2 CH 2 O n R 1 —NH 2 B-2 where n is in the range of 3-25, and R 1 is an alkyl of 1-3 carbons where n is in the range of 7-1000.
Claim 88
Dependent Claim
75 words
A liquid composition, containing, in an aqueous medium, at least one compound selected from the group consisting of the compounds represented by Formulas B-1 to B-3 below: where n+m+k is in the range of 0-25 NH 2 —R 1 —OCH 2 CH 2 O n R 1 —NH 2 B-2 where n is in the range of 3-25, and R 1 is an alkyl of 1-3 carbons where n is in the range of 7-1000.
Claim 89
Dependent Claim
40 words
The liquid composition according to claim 70 , being used for forming a polymeric compound film together with another liquid composition containing a water-soluble compound having an active hydrogen atom addable to the compound represented by Formulas A-1 to A-12.
Claim 90
Dependent Claim
41 words
The liquid composition according to claim 71 , being used for forming a polymeric compound film together with another liquid composition containing a water-soluble compound having in the molecule an ethylenically unsaturated double bond having an electron-attractive substituent on the α-position.
Claim 91
Dependent Claim
32 words
The set of liquid compositions according to claim 1 , wherein at least one of the first and second liquid compositions is ejected in the form of droplets by applying energy thereto.
Claim 92
Dependent Claim
40 words
The set of liquid compositions and an ink according to claim 15 , wherein at least one of the first liquid composition, the second liquid composition and the ink is ejected in the form of droplets by applying energy thereto.
Claim 93
Dependent Claim
11 words
The ink according to claim 49 , being an ink-jet ink.
Claim 94
Dependent Claim
11 words
The ink according to claim 50 , being an ink-jet ink.
Claim 95
Dependent Claim
32 words
The set of liquid compositions according to claim 61 , wherein at least one of the first and second liquid compositions is ejected in the form of droplets by applying energy thereto.
Claim 96
Dependent Claim
19 words
The liquid composition according to claim 70 , being ejected in the form of droplets by applying energy thereto.
Claim 97
Dependent Claim
19 words
The liquid composition according to claim 71 , being ejected in the form of droplets by applying energy thereto.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 2006-01-06 | 2006-07-08 | 2007-01-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2010-01-06 | 2010-07-08 | 2011-01-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2014-01-06 | 2014-07-08 | 2015-01-07 | $7700.00 | Window Closed / Lapsed |