← Back to Patent Explorer
US6491764B2 Expired / Lapsed US ⏱️ 0.0 years remaining

Method and apparatus for removing a liquid from a surface of a rotating substrate

Assignee: Imec
•
Filing: 1998-09-23
•
Granted: 2002-12-10
•
Expires: 2018-09-23
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A method and an apparatus for removing a liquid, i.e a wet processing liquid, from a surface of at least one substrate is disclosed. A liquid is supplied on a surface of substrate. Simultaneously or thereafter besides the liquid also a gaseous substance can be supplied thereby creating at least locally a sharply defined liquid-vapor boundary. The gaseous substance and the liquid can be selected such that the gaseous substance is miscible with the liquid and when mixed with the liquid yields a mixture having a surface tension lower than that of the liquid. According to the invention, the substrate is subjected to a rotary movement at a speed to guide said liquid-vapor boundary over said substrate thereby removing said liquid from said substrate.

Inventors

  • 👤 Paul Mertens
  • 👤 Mark Meuris
  • 👤 Marc Heyns

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 15:36
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/26; G03F7/42; G03F7/422; G03F7/423; H; H10; H10P; H10P50/00; H10P50/20; H10P50/28; H10P50/286; H10P50/287; H10P50/282; H10P50/283; H10P70/00; H10P70/10; H10P70/12; H10P70/15; H10P72/00; H10P72/04; H10P72/0402; H10P72/0406; H10P72/0408; H10P72/0411; H10P72/0414; Y; Y10; Y10S; Y10S134/00; Y10S134/902

Claims Analysis

Total Claims: 54
Claim 1
Independent Claim 141 words
A method of removing a liquid from at least a portion of one surface of a substrate, the method comprising steps of: subjecting said substrate to a rotary movement; supplying a liquid to at least a part of said surface of said substrate; and supplying a gaseous substance to at least a section of said surface of said substrate, the step of supplying a gaseous substance being performed, at least a part of the time, simultaneously with the step of supplying a liquid, said gaseous substance being at least partially miscible with said liquid and when mixed with said liquid yielding a mixture having a surface tension being lower than that of said liquid, wherein the supplying of a liquid and the supplying of a gaseous substance cooperatively remove liquid from at least a portion of one surface of a substrate.
Claim 2
Independent Claim 141 words
A method of removing a liquid from at least a portion of one surface of a substrate, the method comprising steps of: subjecting said substrate to a rotary movement; supplying a liquid to at least a part of said surface of said substrate; and supplying a gaseous substance to at least a section of said surface of said substrate, the step of supplying a gaseous substance being performed, at least a part of the time, simultaneously with the step of supplying a liquid, said gaseous substance being at least partially miscible with said liquid and when mixed with said liquid yielding a mixture having a surface tension being lower than that of said liquid, wherein the supplying of a liquid and the supplying of a gaseous substance cooperatively remove liquid from at least a portion of one surface of a substrate.
Claim 3
Dependent Claim 36 words
A method as recited in claim 1 , wherein, by supplying said liquid and said gaseous substance on said part of said surface of said substrate, at least locally a sharply defined liquid-vapor boundary is created.
Claim 4
Dependent Claim 28 words
A method as recited in claim 1 , wherein said rotary movement is performed at a speed to guide said liquid-vapor boundary over said surface of said substrate.
Claim 5
Dependent Claim 27 words
A method as recited in claim 3 , wherein said rotary movement is on a single substrate applied such that said substrate rotates around its own centre.
Claim 6
Dependent Claim 22 words
A method as in claim 4 , wherein the rotation speed is in the range from 2 to 40 revolutions per second.
Claim 7
Dependent Claim 42 words
A method as recited in claim 1 , wherein said gaseous substance comprises a vaporised substance which is miscible with said liquid and when mixed with said liquid yields a mixture having a surface tension being lower than that of said liquid.
Claim 8
Dependent Claim 31 words
A method as recited in claim 6 , wherein said vaporised substance is selected from a group consisting of isopropyl alcohol (IPA), diacetone, ethyglycol, ethyllactate and methylpyrrolidon or a mixture thereof.
Claim 9
Dependent Claim 52 words
A method as recited in claim 1 , wherein said gaseous substance comprises a mixture of a vaporised substance and a gas, said mixture being at least partially miscible with said liquid and when mixed with said liquid yielding a mixture having a surface tension being lower than that of said liquid.
Claim 10
Dependent Claim 31 words
A method as recited in claim 8 , wherein said vaporised substance is selected from a group consisting of isopropyl alcohol (IPA), diacetone, ethyglycol, ethyllactate and methylpyrrolidon or a mixture thereof.
Claim 11
Dependent Claim 41 words
A method as recited in claim 1 , wherein said gaseous substance comprises a gas which is miscible with said liquid and when mixed with said liquid yields a mixture having a surface tension being lower than that of said liquid.
Claim 12
Dependent Claim 27 words
A method as recited in claim 1 , wherein said liquid is one of a group of an etching liquid, a cleaning liquid or a rinsing liquid.
Claim 13
Dependent Claim 16 words
A method as recited in claim 1 , wherein said liquid is a dilute aqueous solution.
Claim 14
Dependent Claim 53 words
A method as recited in claim 11 , wherein said cleaning liquid comprises a mixture of NH 4 OH, H 2 O 2 and H 2 O; or comprises a mixture of HCl, H 2 O 2 and H 2 O; or comprises diluted HCl; or comprises a mixture comprising O 3 .
Claim 15
Dependent Claim 35 words
A method as recited in claim 11 , wherein said rinsing liquid comprises H 2 O; or a mixture of H 2 O and an acid, said mixture having a pH between 2 and 6.
Claim 16
Dependent Claim 19 words
A method as recited in claim 1 , wherein said liquid and said gaseous substance are supplied substantially simultaneously.
Claim 17
Independent Claim 167 words
A method of removing a liquid from at least a portion of a first side and at least a portion of a second side of a substrate, the method comprising the steps of: subjecting said substrate to a rotary movement; supplying a liquid to at least a part of said first side and at least a part of said second side of said substrate; and supplying a gaseous substance to at least a section of said first side and said second side of said substrate, the step of supplying a gaseous substance being performed, at least a part of the time, simultaneously with the step of supplying a liquid, said gaseous substance being at least partially miscible with said liquid and when mixed with said liquid yielding a mixture having a surface tension being lower than that of said liquid, wherein the supplying of a liquid and the supplying of a gaseous substance cooperatively remove liquid from at least a portion of one surface of a substrate.
Claim 18
Independent Claim 167 words
A method of removing a liquid from at least a portion of a first side and at least a portion of a second side of a substrate, the method comprising the steps of: subjecting said substrate to a rotary movement; supplying a liquid to at least a part of said first side and at least a part of said second side of said substrate; and supplying a gaseous substance to at least a section of said first side and said second side of said substrate, the step of supplying a gaseous substance being performed, at least a part of the time, simultaneously with the step of supplying a liquid, said gaseous substance being at least partially miscible with said liquid and when mixed with said liquid yielding a mixture having a surface tension being lower than that of said liquid, wherein the supplying of a liquid and the supplying of a gaseous substance cooperatively remove liquid from at least a portion of one surface of a substrate.
Claim 19
Dependent Claim 25 words
A method as recited in claim 16 , wherein said first side is the topside and said second side is the bottomside of said substrate.
Claim 20
Dependent Claim 21 words
A method as recited in claim 1 , wherein the supplying of the gaseous substance is performed while supplying the liquid.
Claim 21
Dependent Claim 21 words
A method as recited in claim 16 , wherein the supplying of the gaseous substance is performed while supplying the liquid.
Claim 22
Dependent Claim 31 words
A method as recited in claim 1 , wherein said step of supplying a liquid to at least a part of said surface of said substrate includes supplying the liquid continuously.
Claim 23
Dependent Claim 31 words
A method as recited in claim 16 , wherein said step of supplying a liquid to at least a part of said surface of said substrate includes supplying the liquid continuously.
Claim 24
Dependent Claim 33 words
A method as recited in claim 1 , wherein the simultaneous supplying of a liquid and a gaseous substance cooperatively remove liquid from at least a portion of one surface of a substrate.
Claim 25
Dependent Claim 33 words
A method as recited in claim 16 , wherein the simultaneous supplying of a liquid and a gaseous substance cooperatively remove liquid from at least a portion of one surface of a substrate.
Claim 26
Dependent Claim 16 words
A method as recited in claim 1 , wherein said gaseous substance comprises an organic solvent.
Claim 27
Dependent Claim 16 words
A method as recited in claim 16 , wherein said gaseous substance comprises an organic solvent.
Claim 28
Dependent Claim 43 words
A method as recited in claim 1 , wherein said substrate has a center of rotary movement, and wherein, when beginning the simultaneous supplying of the liquid and the gaseous substance, the gaseous substance is supplied closer to the center than the liquid.
Claim 29
Dependent Claim 18 words
A method as recited in claim 26 , wherein the gaseous substance is supplied adjacent to the liquid.
Claim 30
Dependent Claim 37 words
A method as recited in claim 26 , wherein said substrate has an outer edge, and wherein said gaseous substance and liquid are supplied to the substrate in a direction to said outer edge of the substrate.
Claim 31
Dependent Claim 23 words
A method as recited in claim 28 , wherein said gaseous substance and liquid are supplied from said center to said outer boundary.
Claim 32
Dependent Claim 43 words
A method as recited in claim 1 , wherein said liquid and said gaseous substance are supplied from a first area of the substrate to a second area, and wherein said gaseous substance is supplied closer to said first area than said liquid.
Claim 33
Dependent Claim 28 words
A method as recited in claim 30 , wherein said substrate has a center of rotary movement, and wherein said first area is said center of rotary movement.
Claim 34
Dependent Claim 24 words
A method as recited in claim 31 , wherein said substrate has an outer edge, and wherein said second area is said outer edge.
Claim 35
Dependent Claim 43 words
A method as recited in claim 16 , wherein said substrate has a center of rotary movement, and wherein, when beginning the simultaneous supplying of the liquid and the gaseous substance, the gaseous substance is supplied closer to the center than the liquid.
Claim 36
Dependent Claim 18 words
A method as recited in claim 33 , wherein the gaseous substance is supplied adjacent to the liquid.
Claim 37
Dependent Claim 37 words
A method as recited in claim 33 , wherein said substrate has an outer edge, and wherein said gaseous substance and liquid are supplied to the substrate in a direction to said outer edge of the substrate.
Claim 38
Dependent Claim 23 words
A method as recited in claim 35 , wherein said gaseous substance and liquid are supplied from said center to said outer boundary.
Claim 39
Dependent Claim 43 words
A method as recited in claim 16 , wherein said liquid and said gaseous substance are supplied from a first area of the substrate to a second area, and wherein said gaseous substance is supplied closer to said first area than said liquid.
Claim 40
Dependent Claim 28 words
A method as recited in claim 37 , wherein said substrate has a center of rotary movement, and wherein said first area is said center of rotary movement.
Claim 41
Dependent Claim 24 words
A method as recited in claim 38 , wherein said substrate has an outer edge, and wherein said second area is said outer edge.
Claim 42
Independent Claim 159 words
A method of removing a liquid from at least a portion of one surface of a substrate, the method comprising steps of: subjecting said substrate to a rotary movement; supplying a liquid from a first part of said substrate to a second part of said substrate; and supplying a gaseous substance from said first part of said substrate to said second part of said substrate, the step of supplying a gaseous substance being performed, at least a part of the time, simultaneously with the step of supplying a liquid, said gaseous substance being at least partially miscible with said liquid and when mixed with said liquid yielding a mixture having a surface tension being lower than that of said liquid, wherein the simultaneous supplying of a liquid and a gaseous substance remove liquid from at least a portion of one surface of a substrate, and wherein said gaseous substance is supplied closer to said first part than the liquid.
Claim 43
Independent Claim 159 words
A method of removing a liquid from at least a portion of one surface of a substrate, the method comprising steps of: subjecting said substrate to a rotary movement; supplying a liquid from a first part of said substrate to a second part of said substrate; and supplying a gaseous substance from said first part of said substrate to said second part of said substrate, the step of supplying a gaseous substance being performed, at least a part of the time, simultaneously with the step of supplying a liquid, said gaseous substance being at least partially miscible with said liquid and when mixed with said liquid yielding a mixture having a surface tension being lower than that of said liquid, wherein the simultaneous supplying of a liquid and a gaseous substance remove liquid from at least a portion of one surface of a substrate, and wherein said gaseous substance is supplied closer to said first part than the liquid.
Claim 44
Dependent Claim 28 words
A method as recited in claim 40 , wherein said substrate has a center of rotary movement, and wherein said first part is said center of rotary movement.
Claim 45
Dependent Claim 24 words
A method as recited in claim 41 , wherein said substrate has an outer edge, and wherein said second part is said outer edge.
Claim 46
Dependent Claim 18 words
A method as recited in claim 42 , wherein the gaseous substance is supplied adjacent to the liquid.
Claim 47
Dependent Claim 52 words
A method as recited in claim 1 , wherein the gaseous substance is directed to the section of the surface of the substrate; wherein the liquid is directed to the part of the substrate; and wherein the section of the substrate and the part of the substrate are adjacent to each other.
Claim 48
Dependent Claim 39 words
A method as recited in claim 1 , wherein the supplying a liquid comprises supplying the liquid using at least one nozzle; and wherein the supplying a gaseous substance comprises supplying the gaseous substance using at least one nozzle.
Claim 49
Dependent Claim 56 words
A method as recited in claim 45 , further comprising the step of moving the substrate and nozzles of the liquid supply and gaseous substance supply linearly relative to one another, the step of moving being performed, at least a portion of the time, simultaneously with the step of subjecting said substrate to a rotary movement.
Claim 50
Dependent Claim 41 words
A method as recited in claim 46 , wherein the nozzles move toward an outer edge of the substrate in a direction; and wherein the nozzle of the liquid supply is angled in the direction of the movement of the nozzles.
Claim 51
Dependent Claim 52 words
A method as recited in claim 16 , wherein the gaseous substance is directed to the section of the surface of the substrate; wherein the liquid is directed to the part of the substrate; and wherein the section of the substrate and the part of the substrate are adjacent to each other.
Claim 52
Dependent Claim 39 words
A method as recited in claim 16 , wherein the supplying a liquid comprises supplying the liquid using at least one nozzle; and wherein the supplying a gaseous substance comprises supplying the gaseous substance using at least one nozzle.
Claim 53
Dependent Claim 56 words
A method as recited in claim 49 , further comprising the step of moving the substrate and nozzles of the liquid supply and gaseous substance supply linearly relative to one another, the step of moving being performed, at least a portion of the time, simultaneously with the step of subjecting said substrate to a rotary movement.
Claim 54
Dependent Claim 41 words
A method as recited in claim 50 , wherein the nozzles move toward an outer edge of the substrate in a direction; and wherein the nozzle of the liquid supply is angled in the direction of the movement of the nozzles.

References Cited (Backward Citations)

US4027686A Cited
US5271774A Cited
JPH07211686A Cited
US5873380A Cited
US5964952A Cited
US5660642A Cited
JPH09162159A Cited
US5887605A Cited
US6334902B1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2005-12-09 2006-06-10 2006-12-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2009-12-09 2010-06-10 2010-12-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2013-12-09 2014-06-10 2014-12-10 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag