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US6454844B1 Expired / Lapsed US ⏱️ 0.0 years remaining

Ink set

Assignee: Seiko Epson Corp
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Filing: 2000-04-07
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Granted: 2002-09-24
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Expires: 2020-04-07
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Abstract

Abstract An ink set is provided which can bring good lightfastness and can realize images having excellent color reproduction. The ink set comprises a yellow ink composition, two magenta ink compositions different from each other in color density, and two cyan ink compositions different from each other in color density. The ink compositions contain respective specific compounds as colorants.

Inventors

  • 👤 Miharu Kanaya

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 07:43
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30; C09D11/40

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 418 words
An ink set comprising: a yellow ink composition; first and second magenta ink compositions different from each other in color density, wherein the first magenta ink composition has a higher color density and the second magenta ink composition has a lower color density; and first and second cyan ink compositions different from each other in color density, wherein the first cyan ink composition has a higher color density and the second cyan ink composition has a lower color density, said yellow ink composition containing as a colorant a compound represented by formula (I) or (II): wherein R 1 , R 1 ′, R 2 , and R 2 ′ each independently represent CH 3 or OCH 3 ; and A and A′ each independently represent a group having a structure selected from the group consisting of wherein M represents a hydrogen atom, lithium, sodium, potassium, ammonium, or an organic amine; and n is an integer of 1 or 2, said first magenta ink composition with higher color density containing as a colorant a compound represented by formula (III): wherein B and B′ each independently represent a hydrogen atom or a group represented by formula wherein R 2 represents OH, COOM, or NHR 5 wherein R 5 represents an SO 3 M— or COOH-substituted C 1 -C 4 alkyl group; R 3 represents a hydrogen atom or an OH— or COOH-substituted C 1 -C 4 alkyl group; and R 4 represents an OH—, OCH 3 —, OC 2 H 5 —, SO 3 M—, or COOM-substituted C 1 -C 4 alkyl or phenyl group, provided that B and B′ do not simultaneously represent a hydrogen atom; R 1 represents a C 1 -C 4 alkyl or alkoxy group, OH, SO 3 M, or COOH; and M represents a hydrogen atom, lithium, sodium, potassium, ammonium, or an organic amine, said second magenta ink composition with lower color density containing as a colorant the compound represented by formula (III) or a compound represented by formula (V): wherein X represents an anilino group substituted by at least one SO 3 M; Y represents OH, Cl, or a morpholino group; and M represents a hydrogen atom, lithium, sodium, potassium, ammonium, or an organic amine, said first cyan ink composition with higher color density and said second cyan ink composition with lower color density each containing as a colorant a compound represented by formula (IV): wherein R 6 represents OH or COOM; and p, m, and n are each 0 to 4 with (p+m+n)=4.
Claim 2
Dependent Claim 418 words
An ink set comprising: a yellow ink composition; first and second magenta ink compositions different from each other in color density, wherein the first magenta ink composition has a higher color density and the second magenta ink composition has a lower color density; and first and second cyan ink compositions different from each other in color density, wherein the first cyan ink composition has a higher color density and the second cyan ink composition has a lower color density, said yellow ink composition containing as a colorant a compound represented by formula (I) or (II): wherein R 1 , R 1 ′, R 2 , and R 2 ′ each independently represent CH 3 or OCH 3 ; and A and A′ each independently represent a group having a structure selected from the group consisting of wherein M represents a hydrogen atom, lithium, sodium, potassium, ammonium, or an organic amine; and n is an integer of 1 or 2, said first magenta ink composition with higher color density containing as a colorant a compound represented by formula (III): wherein B and B′ each independently represent a hydrogen atom or a group represented by formula wherein R 2 represents OH, COOM, or NHR 5 wherein R 5 represents an SO 3 M— or COOH-substituted C 1 -C 4 alkyl group; R 3 represents a hydrogen atom or an OH— or COOH-substituted C 1 -C 4 alkyl group; and R 4 represents an OH—, OCH 3 —, OC 2 H 5 —, SO 3 M—, or COOM-substituted C 1 -C 4 alkyl or phenyl group, provided that B and B′ do not simultaneously represent a hydrogen atom; R 1 represents a C 1 -C 4 alkyl or alkoxy group, OH, SO 3 M, or COOH; and M represents a hydrogen atom, lithium, sodium, potassium, ammonium, or an organic amine, said second magenta ink composition with lower color density containing as a colorant the compound represented by formula (III) or a compound represented by formula (V): wherein X represents an anilino group substituted by at least one SO 3 M; Y represents OH, Cl, or a morpholino group; and M represents a hydrogen atom, lithium, sodium, potassium, ammonium, or an organic amine, said first cyan ink composition with higher color density and said second cyan ink composition with lower color density each containing as a colorant a compound represented by formula (IV): wherein R 6 represents OH or COOM; and p, m, and n are each 0 to 4 with (p+m+n)=4.
Claim 3
Dependent Claim 31 words
The ink set according to claim 1 , wherein the content of the compound represented by formula (I) or (II) in the yellow ink composition is 1.5 to 4% by weight.
Claim 4
Dependent Claim 54 words
The ink set according to claim 1 , wherein the first magenta ink composition with higher color density contains 1.5 to 3.5% by weight of the compound represented by formula (III) and the second magenta ink composition with lower color density contains 0.2 to 0.9% by weight of the compound represented by formula (III).
Claim 5
Dependent Claim 54 words
The ink set according to claim 1 , wherein the first magenta ink composition with higher color density contains 0.5 to 4% by weight of the compound represented by formula (III) and the second magenta ink composition with lower color density contains 1 to 3% by weight of the compound represented by formula (V).
Claim 6
Dependent Claim 54 words
The ink set according to claim 1 , wherein the first cyan ink composition with higher color density contains 2.5 to 4.5% by weight of the compound represented by formula (IV) and the second cyan ink composition with lower color density contains 0.4 to 1.5% by weight of the compound represented by formula (IV).
Claim 7
Dependent Claim 16 words
The ink set according to any claim 1 , which further comprises a black ink composition.
Claim 8
Dependent Claim 28 words
The ink set according to claim 1 , wherein each of the yellow, first and second magenta, and first and second cyan ink compositions further contains a surfactant.
Claim 9
Dependent Claim 242 words
An ink set comprising first and second magenta ink compositions different from each other in color density, wherein the first magenta ink composition has a higher color density and the second magenta ink composition has a lower color density, the first magenta ink composition with higher color density containing as a colorant the compound represented by formula (III) wherein B and B′ each independently represent a hydrogen atom or a group represented by formula wherein R 2 represents OH, COOM, or NHR 5 wherein R 5 represents an SO 3 M— or COOH-substituted C 1 -C 4 alkyl group; R 3 represents a hydrogen atom or an OH— or COOH-substituted C 1 -C 4 alkyl group; and R 4 represents an OH—, OCH 3 —, OC 2 H 5 —, SO 3 M—, or COOM-substituted C 1 -C 4 alkyl or phenyl group, provided that B and B′ do not simultaneously represent a hydrogen atom; R 1 represents a C 1 -C 4 alkyl or alkoxy group, OH, SO 3 M, or COOH; and M represents a hydrogen atom, lithium, sodium, potassium, ammonium, or an organic amine, the second magenta ink composition with lower color density containing as a colorant the compound represented by formula (V) wherein X represents an anilino group substituted by at least one SO 3 M; Y represents OH, Cl, or a morpholino group; and M represents a hydrogen atom, lithium, sodium, potassium, ammonium, or an organic amine.
Claim 10
Dependent Claim 242 words
An ink set comprising first and second magenta ink compositions different from each other in color density, wherein the first magenta ink composition has a higher color density and the second magenta ink composition has a lower color density, the first magenta ink composition with higher color density containing as a colorant the compound represented by formula (III) wherein B and B′ each independently represent a hydrogen atom or a group represented by formula wherein R 2 represents OH, COOM, or NHR 5 wherein R 5 represents an SO 3 M— or COOH-substituted C 1 -C 4 alkyl group; R 3 represents a hydrogen atom or an OH— or COOH-substituted C 1 -C 4 alkyl group; and R 4 represents an OH—, OCH 3 —, OC 2 H 5 —, SO 3 M—, or COOM-substituted C 1 -C 4 alkyl or phenyl group, provided that B and B′ do not simultaneously represent a hydrogen atom; R 1 represents a C 1 -C 4 alkyl or alkoxy group, OH, SO 3 M, or COOH; and M represents a hydrogen atom, lithium, sodium, potassium, ammonium, or an organic amine, the second magenta ink composition with lower color density containing as a colorant the compound represented by formula (V) wherein X represents an anilino group substituted by at least one SO 3 M; Y represents OH, Cl, or a morpholino group; and M represents a hydrogen atom, lithium, sodium, potassium, ammonium, or an organic amine.
Claim 11
Dependent Claim 52 words
The ink set according to claim 8 , wherein the first magenta ink composition with higher color density contains 0.5 to 4% by weight of the compound represented by formula (III) and the second magenta ink composition with lower color density contains 1 to 3% of the compound represented by formula (V).
Claim 12
Dependent Claim 20 words
The ink set according to claim 8 , which further comprises a yellow ink composition and a cyan ink composition.
Claim 13
Dependent Claim 15 words
The ink set according to claim 8 , which further comprises a black ink composition.
Claim 14
Dependent Claim 22 words
The ink set according to claim 8 , wherein each of the first and second magenta ink compositions further contains a surfactant.
Claim 15
Dependent Claim 40 words
A method for recording comprising: (a) providing the ink set according to claim 1 ; and (b) depositing onto a recording medium to perform printing each of the yellow, first magenta, second magenta, first cyan and second cyan ink compositions.
Claim 16
Dependent Claim 48 words
A method for ink ret recording comprising: (a) providing the ink set according to claim 1 ; and (b) ejecting droplets of each of the yellow, first magenta, second magenta, first cyan and second cyan ink compositions and depositing the droplets onto a recording medium to perform printing.
Claim 17
Dependent Claim 11 words
A record produced by the recording method of claim 13 .
Claim 18
Dependent Claim 40 words
A method for recording comprising: (a) providing the ink set according to claim 8 ; and (b) depositing onto a recording medium to perform printing each of the yellow, first magenta, second magenta, first cyan and second cyan ink compositions.
Claim 19
Dependent Claim 48 words
A method for ink ret recording comprising: (a) providing the ink set according to claim 8 ; and (b) ejecting droplets of each of the yellow, first magenta, second magenta, first cyan and second cyan ink compositions and depositing the droplets onto a recording medium to perform printing.
Claim 20
Dependent Claim 11 words
A record produced by the recording method of claim 16 .

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2005-09-23 2006-03-25 2006-09-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2009-09-23 2010-03-25 2010-09-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2013-09-23 2014-03-25 2014-09-24 $7700.00 Window Closed / Lapsed

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