Abstract A method of making connection between an aluminum or aluminum based material and tungsten. The method includes providing an underlying region containing a layer of tungsten thereover. The underlying region is preferably a layer of titanium over which is a layer of titanium nitride. The layer of tungsten is etched back to the underlying region while exposed tungsten is retained over a portion of the underlying region. The underlying region also may contain a via therein which contains the exposed tungsten. An nitrogen-containing plasma, preferably elemental nitrogen, is then applied to the exposed tungsten and exposed underlying region and a layer of a barrier material is formed by reaction of the nitrogen in the plasma and the tungsten over the exposed tungsten. A further barrier layer, preferably titanium nitride, is optionally then applied followed by a layer of aluminum over the exposed surface, the barrier layer isolating the layer of aluminum from the tungsten. Plasma is preferably an argon/nitrogen plasma.
A method of aluminum crystal orientation control, comprising: (a) providing a surface including a first portion consisting essentially of tungsten and a second portion consisting essentially of titanium nitride; (b) exposing said surface to a nitrogen-containing plasma; (c) forming an aluminum layer over the surface; (d) whereby the exposing of step (b) removes contaminants and thereby controls the crystal orientation of the aluminum over both the tungsten and the titanium nitride.
Claim 2
Independent Claim
71 words
A method of aluminum crystal orientation control, comprising: (a) providing a surface including a first portion consisting essentially of tungsten and a second portion consisting essentially of titanium nitride; (b) exposing said surface to a nitrogen-containing plasma; (c) forming an aluminum layer over the surface; (d) whereby the exposing of step (b) removes contaminants and thereby controls the crystal orientation of the aluminum over both the tungsten and the titanium nitride.
Claim 3
Dependent Claim
46 words
The method of claim 1 , further comprising: (a) forming a barrier layer on the surface after the exposing of step (b) of claim 1 ; and (b) the forming an aluminum layer of step (c) of claim 1 is depositing aluminum on the barrier layer.
Claim 4
Dependent Claim
14 words
The method of claim 2 , wherein: (a) the barrier layer is titanium nitride.