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US6300407B1 Expired / Lapsed US ⏱️ 0.0 years remaining

Polymeric (meth)acrylate plasticizers and processing aids for elastomers

Assignee: Rohm and Haas Co
•
Filing: 1999-02-04
•
Granted: 2001-10-09
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Expires: 2019-02-04
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Abstract

Abstract An elastomer composition, including: at least one elastomer; a plasticizer which includes at least one polymeric material having a weighted average molecular weight of (Mw) of 500 to 1,000,000, formed from at least one ethylenically unsaturated monomer, and a curing agent, wherein the at least one polymeric material is substantially permanent within the elastomer. The subject elastomer compositions have enhanced plasticity and processability without attendant migration, heat or solvent extraction and compatibility problems.

Inventors

  • 👤 Warren Harvey Machleder
  • 👤 Robert Howard Gore
  • 👤 David Sterett Moorman
  • 👤 Michael Damian Bowe

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 12:29
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/0008; C08K5/0016; C08K5/0025; C08L; C08L101/00; C08L21/00

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 203 words
An elastomer composition, comprising: (A) at least one elastomer, (B) a plasticizer comprising at least one polymeric material having a weight average molecular weight, M w , of 500 to 1,000,000, and (C) a curing agent; wherein the at least one polymeric material is substantially permanent within the elastomer; and wherein the at least one polymeric material consists of: (i) at least one monormer unit selected from the group consisting of (meth)acrylic acid; C 10 -C 50 alkyl (meth)acrylates; and C 1 -C 50 alkyl (meth)acrylates substituted with a halogen, a nitro group, a cyano group, a haloalkyl group, a carboxy group, an amino group, an alkylamino group or a dialkylamino group; and (ii) optionally, at least one monomer unit selected from the group consisting of vinylaromatic monomers; vinylaromatic monomers substituted with a halogen, a nitro group, a cyano group, alkoxy group, a haloalkyl group, carbalkoxy group, a carboxy group, an amino group, an alkylamino group or a dialkylamino group; nitrogen-containing ring compounds and thio analogs thereof; nitrogen-containing ring compounds and thio analogs thereof substituted with a C 1 -C 8 alkyl group; vinyl acetate; vinyl chloride; vinyl fluoride; vinyl bromide; vinylidene chloride; vinylidene fluoride; vinylidenebromide;(meth)acrylonitrile; (meth)acrylamide; and dialkylaminoC 2 -C 6 alkyl(meth)acrylamindes.
Claim 2
Dependent Claim 203 words
An elastomer composition, comprising: (A) at least one elastomer, (B) a plasticizer comprising at least one polymeric material having a weight average molecular weight, M w , of 500 to 1,000,000, and (C) a curing agent; wherein the at least one polymeric material is substantially permanent within the elastomer; and wherein the at least one polymeric material consists of: (i) at least one monormer unit selected from the group consisting of (meth)acrylic acid; C 10 -C 50 alkyl (meth)acrylates; and C 1 -C 50 alkyl (meth)acrylates substituted with a halogen, a nitro group, a cyano group, a haloalkyl group, a carboxy group, an amino group, an alkylamino group or a dialkylamino group; and (ii) optionally, at least one monomer unit selected from the group consisting of vinylaromatic monomers; vinylaromatic monomers substituted with a halogen, a nitro group, a cyano group, alkoxy group, a haloalkyl group, carbalkoxy group, a carboxy group, an amino group, an alkylamino group or a dialkylamino group; nitrogen-containing ring compounds and thio analogs thereof; nitrogen-containing ring compounds and thio analogs thereof substituted with a C 1 -C 8 alkyl group; vinyl acetate; vinyl chloride; vinyl fluoride; vinyl bromide; vinylidene chloride; vinylidene fluoride; vinylidenebromide;(meth)acrylonitrile; (meth)acrylamide; and dialkylaminoC 2 -C 6 alkyl(meth)acrylamindes.
Claim 3
Dependent Claim 68 words
The elastomer composition of claim 1 , wherein the at least one polymeric material consists of at least one monomer unit selected from the group consisting of (meth)acrylic acid; C 10 -C 50 alkyl (meth)acrylates; and C 1 -C 50 alkyl (meth)acrylates substituted with a halogen, a nitro group, a cyano group, a haloalky group, a carboxy group, an amino group, an alkylamino group or a dialkylamino group.
Claim 4
Dependent Claim 66 words
The elastomer composition of claim 1 , wherein the at least one polymeric material consists of at least one monomer unit selected from the group consisting of C 10 -C 20 alkyl (meth)acrylates; and C 1 -C 20 alkyl (meth)acrylates substituted with a halogen, a nitro group, a cyano group, a haloalkyl group, a carboxy group, an amino group, an alkylamino group or a dialkylamino group.
Claim 5
Dependent Claim 65 words
The elastomer composition of claim 1 , wherein the at least one polymeric material consists of at least one monormer unit selected from the group consisting of C 20 -C 50 alkyl (meth)acrylates; and C 20 -C 50 alkyl (meth)acrylates substituted with a halogen, a nitro group, a cyano group, a haloalkyl group, carboxy group, an amino group, an alkylamino group or a dialkylamino group.
Claim 6
Dependent Claim 19 words
The elastomer composition of claim 1 , wherein the at least one polymeric material is a terminally unsaturated oligomer.
Claim 7
Dependent Claim 20 words
The elastomer composition of claim 1 , wherein the at least one polymeric material consists of units of lauryl methacrylate.
Claim 8
Dependent Claim 26 words
The elastomer composition of claim 1 , wherein the at least one polymeric material consists of a mixture of units of lauryl methacrylate and stearyl methacrylate.
Claim 9
Dependent Claim 52 words
The elastomer composition of claim 1 , wherein the at least one elastomer is selected from the group consisting of styrene-butadiene elastomer, chloroprene elastomer, butyl elastomer, polybutadiene elastomer, nitrile elastomer, polyethylene elastomer, ethylene-propylene elastomer, acrylic elastomer, silicone elastomer, fluoroelastomer, epichlorohydrin elastomer, polyalkenamer elastomer, polysulfide elastomer, urethane elastomer, mixtures thereof and blends thereof.
Claim 10
Dependent Claim 11 words
The elastomer composition of claim 1 , further comprising a filler.
Claim 11
Dependent Claim 35 words
The elastomer composition of claim 9 , wherein the filler is selected from the group consisting of carbon black, carbon fiber, calcium carbonate, natural and synthetic silica, talc, mica, wollastonite, glass spheres and glass fiber.
Claim 12
Dependent Claim 12 words
The elastomer composition of claim 1 , further comprising a crosslinking accelerator.
Claim 13
Dependent Claim 34 words
A method of plasticizing an elastomer, comprising: (A) providing an elastomer composition according to claim 1 , wherein the at least one polymeric material is present in an amount effective to plasticize the elastomer.
Claim 14
Dependent Claim 17 words
The method of claim 12 , wherein the polymeric material is present from 2 to 100 PHR.
Claim 15
Dependent Claim 38 words
A method of enhancing processability of an elastomer, comprising: (A) providing an elastomer composition according to claim 1 , wherein the at least one polymeric material is present in an amount effective to enhance processability of the elastomer.
Claim 16
Dependent Claim 17 words
The method of claim 14 , wherein the polymeric material is present from 2 to 30 PHR.

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