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US6251771B1 Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrogen passivation of chemical-mechanically polished copper-containing layers

Assignee: Texas Instruments Inc
•
Filing: 1999-02-22
•
Granted: 2001-06-26
•
Expires: 2019-02-22
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Abstract

Abstract An embodiment of the instant invention is a method of forming an electronic device over a semiconductor substrate and having at least one level of metallic conductors, the method comprising the steps of: forming a dielectric layer over the semiconductor substrate, the dielectric layer having openings (step 102 of FIG. 1 ); forming a layer of the metallic conductor on the dielectric layer (step 104 of FIG. 1 ); removing a portion of the layer of the metallic conductor on the dielectric layer (step 106 of FIG. 1 ); and subjecting the exposed metallic conductor to a plasma which contains hydrogen or deuterium so as to passivate the metallic conductor (step 110 of FIG. 1 ). Preferably, the plasma contains a substance selected from the group consisting of: NH 3 , N 2 H 2 , H 2 S, and CH 4 , and the metallic conductors are comprised of a material selected from the group consisting of: copper, copper doped aluminum, Ag, Sn, Pb, Ti, Cr, Mg, Ta, and any combination thereof. The step of removing a portion of the layer of the metallic conductor is, preferably, performed by sputtering off a portion of the metallic conductor, chemical-mechanical polishing, etching, or a combination thereof.

Inventors

  • 👤 Patricia B. Smith
  • 👤 Girish A. Dixit
  • 👤 Eden Zielinski
  • 👤 Stephen W. Russell

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 17:12
CPC Classifications
H; H10; H10P; H10P52/00; H10P52/40; H10P52/403; H10P95/00

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 142 words
A method of forming an electronic device over a semiconductor substrate and having at least one level of metallic conductors, said method comprising the steps of: forming source and drain regions in the semiconductor substrate; forming a first dielectric layer over the semiconductor substrate and the source and drain regions; forming a second dielectric layer over said first dielectric layer, said second dielectric layer having openings; forming a layer of said metallic conductors on said second dielectric layer and in the openings wherein said metallic conductors do not contact said source and drain regions; removing a portion of said layer of said metallic conductors on said second dielectric layer thereby creating exposed portions of the metallic conductors corresponding to the openings; and subjecting said exposed metallic conductors to a plasma which contains hydrogen or deuterium so as to passivate said metallic conductors.
Claim 2
Independent Claim 142 words
A method of forming an electronic device over a semiconductor substrate and having at least one level of metallic conductors, said method comprising the steps of: forming source and drain regions in the semiconductor substrate; forming a first dielectric layer over the semiconductor substrate and the source and drain regions; forming a second dielectric layer over said first dielectric layer, said second dielectric layer having openings; forming a layer of said metallic conductors on said second dielectric layer and in the openings wherein said metallic conductors do not contact said source and drain regions; removing a portion of said layer of said metallic conductors on said second dielectric layer thereby creating exposed portions of the metallic conductors corresponding to the openings; and subjecting said exposed metallic conductors to a plasma which contains hydrogen or deuterium so as to passivate said metallic conductors.
Claim 3
Dependent Claim 33 words
The method of claim 1 , wherein said plasma contains a substance selected from the group consisting of: NH 3 , N 2 H 2 , H 2 S, and CH 4 .
Claim 4
Dependent Claim 36 words
The method of claim 1 , wherein said metallic conductors are comprised of a material selected from the group consisting of: copper, copper doped aluminum, Ag, Sn, Pb, Ti, Cr, Mg, Ta, and any combination thereof.
Claim 5
Dependent Claim 35 words
The method of claim 1 , wherein said electronic device is selected from the group consisting of: a memory device, a logic device, a DSP, a microprocessor, a transistor, a diode, and any combination thereof.
Claim 6
Dependent Claim 24 words
The method of claim 1 , wherein said step of removing a portion of said layer of said metallic conductors is performed by sputtering.
Claim 7
Dependent Claim 25 words
The method of claim 1 , wherein said step of removing a portion of said layer of said metallic conductors is performed by chemical-mechanical polishing.
Claim 8
Dependent Claim 24 words
The method of claim 1 , wherein said step of removing a portion of said layer of said metallic conductors is performed by etching.
Claim 9
Independent Claim 147 words
A method of forming an electronic device over a semiconductor substrate and having at least one level of metallic conductors, said method comprising the steps of: forming source and drain regions in the semiconductor substrate; forming a first dielectric layer over the semiconductor substrate and the source and drain regions; forming a second dielectric layer over said first dielectric layer, said second dielectric layer having openings; forming a layer of said metallic conductors in said openings in said second dielectric layer and on said second dielectric layer wherein said metallic conductors do not contact said source and drain regions; removing said layer of said metallic conductors on said second dielectric layer using chemical-mechanical polishing thereby creating exposed portions of the metallic conductors corresponding to the openings; and subjecting said exposed metallic conductors to a plasma which contains hydrogen or deuterium so as to passivate said metallic conductors.
Claim 10
Independent Claim 147 words
A method of forming an electronic device over a semiconductor substrate and having at least one level of metallic conductors, said method comprising the steps of: forming source and drain regions in the semiconductor substrate; forming a first dielectric layer over the semiconductor substrate and the source and drain regions; forming a second dielectric layer over said first dielectric layer, said second dielectric layer having openings; forming a layer of said metallic conductors in said openings in said second dielectric layer and on said second dielectric layer wherein said metallic conductors do not contact said source and drain regions; removing said layer of said metallic conductors on said second dielectric layer using chemical-mechanical polishing thereby creating exposed portions of the metallic conductors corresponding to the openings; and subjecting said exposed metallic conductors to a plasma which contains hydrogen or deuterium so as to passivate said metallic conductors.
Claim 11
Dependent Claim 33 words
The method of claim 8 , wherein said plasma contains a substance selected from the group consisting of: NH 3 , N 2 H 2 , H 2 S, and CH 4 .
Claim 12
Dependent Claim 36 words
The method of claim 8 , wherein said metallic conductors are comprised of a material selected from the group consisting of: copper, copper doped aluminum, Ag, Sn, Pb, Ti, Cr, Mg, Ta, and any combination thereof.
Claim 13
Dependent Claim 35 words
The method of claim 8 , wherein said electronic device is selected from the group consisting of: a memory device, a logic device, a DSP, a microprocessor, a transistor, a diode, and any combination thereof.

References Cited (Backward Citations)

US5723383A Cited
US5693961A Cited
US5677244A Cited
US5705435A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2004-06-25 2004-12-25 2005-06-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2008-06-25 2008-12-25 2009-06-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2012-06-25 2012-12-25 2013-06-26 $7700.00 Window Closed / Lapsed

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